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We study the ground state of 1D Holstein single polaron with next nearest neighbour electron hopping (NNN), employing a variational approximation based on exact diagonalization. Our investigation reveals that, depending upon the sign and…

Strongly Correlated Electrons · Physics 2017-09-19 Monodeep Chakraborty , A. Taraphder , Mona Berciu

A geometrical model which captures the main ingredients governing atom-diatom collinear chemical reactions is proposed. This model is neither near-integrable nor hyperbolic, yet it is amenable to analysis using a combination of the recently…

Chaotic Dynamics · Physics 2018-04-10 L. Lerman , V. Rom-Kedar

The one-dimensional Holstein model and its generalizations have been studied extensively to understand the effects of electron-phonon interaction. The half-filled case is of particular interest, as it describes a transition from a metallic…

Strongly Correlated Electrons · Physics 2015-12-29 J. Greitemann , S. Hesselmann , S. Wessel , F. F. Assaad , M. Hohenadler

Non-classical features like interference is already being harnessed to control the output of chemical reactions. However quantum entanglement which is an equally enigmatic many-body quantum correlation can also be used as a powerful…

Quantum Physics · Physics 2021-07-20 Junxu Li , Manas Sajjan , Sumit Suresh Kale , Sabre Kais

The eigenstate thermalization hypothesis (ETH) posits how isolated quantum many-body systems thermalize, assuming that individual eigenstates at the same energy density have identical expectation values of local observables in the limit of…

Statistical Mechanics · Physics 2026-01-14 Maksym Serbyn , Alexander Avdoshkin , Oriana K. Diessel , David A. Huse

The standard quantum mechanical expressions for the singlet and triplet survival probabilities and product yields of a radical pair recombination reaction involve a trace over the states in a combined electronic and nuclear spin Hilbert…

Chemical Physics · Physics 2017-01-02 Alan M. Lewis , Thomas P. Fay , David E. Manolopoulos

The interplay between electron-electron correlations and disorder has been a central theme of condensed matter physics over the last several decades, with particular interest in the possibility that interactions might cause delocalization…

Strongly Correlated Electrons · Physics 2021-03-12 Bo Xiao , Natanael C. Costa , Ehsan Khatami , George G. Batrouni , Richard T. Scalettar

Clustered quantum materials provide a new platform for the experimental study of many-body entanglement. Here we address a simple model of a single-molecule nano-magnet featuring N interacting spins in a transverse field. The field can…

Strongly Correlated Electrons · Physics 2017-12-14 Hannah R. Irons , Jorge Quintanilla , Toby G. Perring , Luigi Amico , Gabriel Aeppli

Relativistic correction to the Coulomb interaction is considered for strongly correlated electron orbitals. The atomic representation of the Coulomb-Breit interaction and its physical origin are clarified, to generalize a concept of the…

Strongly Correlated Electrons · Physics 2023-11-10 Shintaro Hoshino

We show that the parallel magnetic field-induced increase in the critical electron density for the Anderson transition in a strongly interacting two-dimensional electron system is caused by the effects of exchange and correlations. If the…

Strongly Correlated Electrons · Physics 2017-08-21 V. T. Dolgopolov , A. A. Shashkin , S. V. Kravchenko

We study the combined effects of electron-phonon coupling and dot-lead repulsion in the transport properties of the Anderson-Holstein model. We employ a recently proposed nonperturbative method to calculate the transient response of the…

Mesoscale and Nanoscale Physics · Physics 2015-03-12 E. Perfetto , G. Stefanucci

In the paper a possibility of metallic ferromagnetic state realization in a generalized Hubbard model with more complete accounting of electron-electron interactions, in particular, the correlated hopping and exchange interaction integrals…

Strongly Correlated Electrons · Physics 2007-05-23 L. Didukh , O. Kramar

We consider an exchange model of itinerant electrons in a Heisenberg ferromagnet and we assume that the ferromagnet is in a fully polarized state. Using the Holstein-Primakoff transformation we are able to obtain a boson-fermion Hamiltonian…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Marco Frasca

The radical-pair-based chemical reaction could be used by birds for the navigation via the geomagnetic direction. An inherent physical mechanism is that the quantum coherent transition from a singlet state to triplet states of the radical…

Quantum Physics · Physics 2012-02-23 C. Y. Cai , Qing Ai , H. T. Quan , C. P. Sun

Radiation-reaction in the interaction of ultra-relativistic electrons with a strong external electromagnetic field is investigated using a kinetic approach in the weakly quantum regime ($\chi \lesssim 1$, with $\chi$ the electron quantum…

Plasma Physics · Physics 2018-05-02 F. Niel , C. Riconda , F. Amiranoff , R. Duclous , M. Grech

We develop a numerical model that reproduces the thermal equilibrium and the spin transfer mechanisms in magnetic nanomaterials. We analyze the coherent two-particle spin exchange interaction and the electron-electron collisions. Our study…

Mesoscale and Nanoscale Physics · Physics 2021-04-01 O. Morandi

Spin-crossover compounds, which are characterized by magnetic ions showing low-spin and high-spin states at thermally accessible energies, are ubiquitous in nature. We here focus on the effect of an exchange interaction on the collective…

Statistical Mechanics · Physics 2009-11-13 Carsten Timm , Charles J. Pye

We examine theoretically a new idea for spatial and temporal control of chemical reactions. When chemical reactions take place in a mixture of solvents, an external electric field can alter the local mixture composition thereby accelerating…

Soft Condensed Matter · Physics 2017-01-19 Shivaraj D. Deshmukh , Yoav Tsori

For triatomic chemical reactions under single-collision conditions, we propose a new quasi-classical trajectory (QCT) approach to rotational-state distributions of particular interest in the quantum regime where only a few rotational states…

Chemical Physics · Physics 2014-05-02 L. Bonnet , P. Larrégaray , Ph. Halvick , J. -C. Rayez

Purpose: The paper introduces a classical model to describe the dynamics of large spin-1/2 ensembles associated with nuclei bound in large molecule structures, commonly referred to as the semi-solid spin pool, and their magnetization…

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