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In this work we present a detailed computational study of structural and elastic properties of cubic AlGaInN alloys in the framework of Keating valence force field model, for which we perform accurate parametrization based on state of the…

Materials Science · Physics 2015-05-18 Michal Lopuszynski , Jacek A. Majewski

UV emitters based on the semiconductor alloy aluminium gallium nitride, (Al,Ga)N, have attracted significant interest in recent years due to their potential for optoelectronic devices. To guide the design of such devices with improved…

Materials Science · Physics 2025-05-27 Amit Kumar Singh , Alvaro Gomez-Iglesias , Stefan Schulz

We present theoretical studies for the third-order elastic constants $C_{ijk}$ in zinc-blende nitrides AlN, GaN, and InN. Our predictions for these compounds are based on detailed ab initio calculations of strain-energy and strain-stress…

Materials Science · Physics 2009-11-13 Michal Lopuszynski , Jacek A. Majewski

The wurtzite III-Nitrides family of semiconductors, which include the compounds GaN, InN, and AlN, along with their derivative ternary alloys, is highly priced for its wide range of bandgaps, lattice constant tunability, high breakdown…

Applied Physics · Physics 2020-05-19 Ahmad Al Sulami , Feras Alqatari , Xiaohang Li

The alchemical mixing approximation which is the ab initio pseudopotential specific implementation of the virtual crystal approximation (VCA), offered in the ABINIT package, has been employed to study the wurtzite (WZ) and zinc blende (ZB)…

Materials Science · Physics 2014-08-04 P. Scharoch , M. J. Winiarski , M. P. Polak

A combined experimental and theoretical study is presented of the band gap of AlInN, confirming the breakdown of the virtual crystal approximation (VCA) for the conduction and valence band edges. Composition dependent bowing parameters for…

Materials Science · Physics 2013-11-26 S. Schulz , M. A. Caro , L. -T. Tan , P. J. Parbrook , R. W. Martin , E. P. O'Reilly

Machine learning is changing how we design and interpret experiments in materials science. In this work, we show how unsupervised learning, combined with ab initio modeling, improves our understanding of structural metastability in…

We present Fourier-space based methods to calculate the electronic structure of wurtzite quantum dot systems with continuous alloy profiles. We incorporate spatially varying elastic and dielectric constants in strain and piezoelectric…

Mesoscale and Nanoscale Physics · Physics 2021-01-06 Luc Robichaud , Jacob J. Krich

We report the calculated fundamental band gaps of \emph{wurtzite} ternary alloys Zn$_{1-x}$M$_x$O (M=Mg, Cd) and the band offsets of the ZnO/Zn$_{1-x}$M$_x$O heterojunctions, these II-VI materials are important for electronics and…

Materials Science · Physics 2017-01-26 Haitao Yin , Junli Chen , Yin Wang , Jian Wang , Hong Guo

Multicomponent nitrides are a hot research topic in the search of hard coatings. The effect of substitutions on the phase stabilities, magnetic, and elastic properties of $Al_{1-x-y}Cr_{x}Ti_{y}N$ $(0\leq x,y\leq1)$ was studied using first…

The elastic properties of paramagnetic cubic B1 (c-) Cr1-xAlxN ternary alloys are studied using stress-strain and energy-strain methods within the framework of Density Functional Theory (DFT). A strong compositional dependence of the…

Materials Science · Physics 2014-07-10 Liangcai Zhou , David Holec , Paul H. Mayrhofer

Controlling the crystal phase and lattice mismatch of semiconductors offers a powerful route to engineer electronic and optical properties of heterostructures. As a consequence, semiconductors in the wurtzite phase are increasingly sought…

Materials Science · Physics 2025-12-16 Aisling Power , Cara-Lena Nies , Stefan Schulz

Based on a successful description of II-VI ternary alloys, which introduces an empirical bowing parameter to the widely used virtual crystal approximation, we set up a tight-binding Hamiltonian to describe the Zn_{1-y}Cd_ySe_{1-x}Te_x and…

Materials Science · Physics 2019-08-15 A. E. Garcia , A. Zepeda-Navratil , A. Camacho , D. Olguin , R. Baquero

Using the density functional theory (DFT) with the generalized gradient approximation (GGA), the structural and electronic properties of wurtzite AlN, GaN, InN, and their related alloys, Al$_x$Ga$_{1-x}$N and In$_x$Ga$_{1-x}$N, were…

Materials Science · Physics 2008-11-04 E. Lopez-Apreza , J. Arriaga , D. Olguin

Using a valence force field model based on that introduced by Martin, we present three related methods through which we analytically determine valence force field parameters. The methods introduced allow easy derivation of valence force…

Materials Science · Physics 2019-10-09 Daniel S. P. Tanner , Miguel A. Caro , Stefan Schulz , Eoin P. O'Reilly

We study the electroacoustic properties of aluminum scandium nitride crystals Al$_{1-x}$Sc$_x$N with the metastable wurtzite structure by means of first-principles calculations based on density functional theory. We extract the material…

Materials Science · Physics 2021-03-17 Daniel F. Urban , Oliver Ambacher , Christian Elsässer

We investigate the elastic properties of selected zincblende III-V semiconductors. Using hybrid functional density functional theory we calculate the second and third order elastic constants, and first and second-order internal strain…

Computational Physics · Physics 2018-12-12 Daniel S. P. Tanner , Miguel A. Caro , Stefan Schulz , Eoin P. O'Reilly

A lattice dynamical formalism based on nonaffine response theory is derived for non-centrosymmetric crystals, accounting for long-range interatomic interactions using the Ewald method. The framework takes equilibrated static configurations…

Materials Science · Physics 2020-01-08 Bingyu Cui , Alessio Zaccone , David Rodney

Motivated by frequently reported deviations from stoichiometry in cubic transition metal nitride (TMNx) thin films, the effect of N-vacancy concentration on the elastic properties of cubic TiNx, ZrNx, VNx, NbNx, and MoNx (0.72<x<1.00) is…

The magnetic properties tuning and volume dependence in the series of quaternary full Heusler alloys with formula Co2Cr1-xYGa (Y = Ti, V, Mn, Fe, Co, Ni) were studied with a detailed first-principles exploration. We employ the density…

Materials Science · Physics 2016-12-22 J. N. Gonçalves , N. M. Fortunato , J. S. Amaral , V. S. Amaral
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