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The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…

Statistical Mechanics · Physics 2013-05-29 Hiroki Majima , Akira Suzuki

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers , Susan B. Rempe

We introduce an algorithmic model of heat conduction, the thermodynamic graph. The thermodynamic graph is analogous to meshes in the finite difference method in the sense that the calculation of temperature is carried out at the vertices of…

Computational Engineering, Finance, and Science · Computer Science 2018-02-02 O. Kurganskyy , A. J. Maksimova

Thermodynamics is based on the notions of energy and entropy. While energy is the elementary quantity governing physical dynamics, entropy is the fundamental concept in information theory. In this work, starting from first principles, we…

Statistical Mechanics · Physics 2017-10-25 Bernhard Altaner

We analyze underdamped Brownian motion in non-isothermal media with quadratic, linear, and piecewise-constant temperature profiles. Exact identities for entropy production and entropy extraction are derived, addressing whether a vanishing…

Statistical Mechanics · Physics 2025-09-10 Mesfin Taye

We brief{}ly review the connection between statistical mechanics and thermodynamics. We show that, in order to satisfy thermodynamics and its Legendre transformation mathematical frame, the celebrated Boltzmann-Gibbs~(BG) statistical…

Statistical Mechanics · Physics 2014-11-03 Constantino Tsallis , Leonardo J. L. Cirto

The fact that a temperature and an entropy may be associated with horizons in semi-classical general relativity has led many to suspect that spacetime has microstructure. If this is indeed the case then its description via Riemannian…

Statistical Mechanics · Physics 2011-10-28 Cenalo Vaz

We show that systems driven by an external force and described by Nose-Hoover dynamics allow for a consistent nonequilibrium thermodynamics description when the thermostatted variable is initially assumed in a state of canonical…

Statistical Mechanics · Physics 2011-08-11 Massimiliano Esposito , Takaaki Monnai

Irreversible processes accomplished in a fixed time involve nonlinearly coupled flows of matter, energy, and information. Here, using entropy production as an example, we show how thermodynamic uncertainty relations and speed limits on…

Statistical Mechanics · Physics 2021-05-12 Schuyler B. Nicholson , Jason R. Green

The limit of small entropy production is reached in relaxing systems long after preparation, and in stationary driven systems in the limit of small driving power. Surprisingly, for extended systems this limit is not in general the…

Condensed Matter · Physics 2009-10-31 Leticia F. Cugliandolo , Jorge Kurchan

We formulate thermodynamics of economic systems in terms of an arbitrary probability distribution for a conserved economic quantity. As in statistical physics, thermodynamic macroeconomic variables emerge as the mean value of microeconomic…

Statistical Finance · Quantitative Finance 2011-05-26 H. Quevedo , M. N. Quevedo

The total entropy production of stochastic systems can be divided into three quantities. The first corresponds to the excess heat, whilst the second two comprise the house-keeping heat. We denote these two components the transient and…

Statistical Mechanics · Physics 2015-06-03 Richard E. Spinney , Ian J. Ford

The statistical mechanics of Gibbs is a juxtaposition of subjective, probabilistic ideas on the one hand and objective, mechanical ideas on the other. In this paper, we follow the path set out by Jaynes, including elements added…

Statistical Mechanics · Physics 2015-11-24 David M. Rogers , Thomas L. Beck , Susan B. Rempe

The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , S. Martinez , F. Pennini , A. Plastino

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

Based on the property of extensivity (mathematically, homogeneity of first degree), we derive in a mathematically consistent manner the explicit expressions of the chemical potential $\mu$ and the Clausius entropy $S$ for the case of…

Statistical Mechanics · Physics 2013-01-15 Thomas Oikonomou , G. Baris Bagci

We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how…

Statistical Mechanics · Physics 2015-03-02 J. P. Badiali

The backbone of nonequilibrium thermodynamics is the stability structure, where entropy is related to a Lyapunov function of thermodynamic equilibrium. Stability is the background of natural selection: unstable systems are temporary, and…

Physics and Society · Physics 2024-10-01 Peter Ván