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This is the second in a series of papers in which we derive a $\Gamma$-expansion for the two-dimensional non-local Ginzburg-Landau energy with Coulomb repulsion known as the Ohta-Kawasaki model in connection with diblock copolymer systems.…
We consider a non local isoperimetric problem arising as the sharp interface limit of the Ohta-Kawasaki free energy introduced to model microphase separation of diblock copolymers. We perform a second order variational analysis that allows…
This is the first in a series of two papers in which we derive a $\Gamma$-expansion for a two-dimensional non-local Ginzburg-Landau energy with Coulomb repulsion, also known as the Ohta-Kawasaki model in connection with diblock copolymer…
In this paper we collect some new observations about periodic critical points and local minimizers of a nonlocal isoperimetric problem, arising in the modeling of diblock copolymers. In the main result, by means of a purely variational…
We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove…
This paper is concerned with the macroscopic behavior of global energy minimizers in the three-dimensional sharp interface unscreened Ohta-Kawasaki model of diblock copolymer melts. This model is also referred to as the nuclear liquid drop…
We consider a version of Gamow's liquid drop model with a short range attractive perimeter-penalizing potential and a long-range Coulomb interaction of a uniformly charged mass in $\R^3$. Here we constrain ourselves to minimizing among the…
We study a two-dimensional ternary inhibitory system derived as a sharp-interface limit of the Nakazawa-Ohta density functional theory of triblock copolymers. This free energy functional combines an interface energy favoring micro-domain…
We discuss the local minimality of certain configurations for a nonlocal isoperimetric problem used to model microphase separation in diblock copolymer melts. We show that critical configurations with positive second variation are local…
Using area-preserving curve shortening flow, and a new inequality relating the potential generated by a set to its curvature, we study a non-local isoperimetric problem which arises in the study of di-block copolymer melts, also referred to…
We study the ternary Ohta-Kawasaki free energy that has been used to model triblock copolymer systems. Its one-dimensional global minimizers are conjectured to have cyclic patterns. However, some physical experiments and computer…
The Ohta-Kawasaki model for diblock-copolymers is well known to the scientific community of diffuse-interface methods. To accurately capture the long-time evolution of the moving interfaces, we present a derivation of the corresponding…
We address small volume-fraction asymptotic properties of a nonlocal isoperimetric functional with a confinement term, derived as the sharp interface limit of a variational model for self-assembly of diblock copolymers under confinement by…
We introduce a rigorous approach to the study of the symmetry breaking and pattern formation phenomenon for isotropic functionals with local/nonlocal interactions in competition. We consider a general class of nonlocal variational problems…
We study a non-local Cahn-Hilliard energy arising in the study of di-block copolymer melts, often referred to as the Ohta-Kawasaki energy in that context. In this model, two phases appear, which interact via a Coulombic energy. As in our…
We obtain a sharp quantitative isoperimetric inequality for nonlocal $s$-perimeters, uniform with respect to $s$ bounded away from $0$. This allows us to address local and global minimality properties of balls with respect to the…
Using an interface displacement model we calculate the shapes of nanometer-size liquid droplets on homogeneous cylindrical surfaces. We determine effective contact angles and line tensions, the latter defined as excess free energies per…
We investigate the shape of critical points for a free energy consisting of a nonlocal perimeter plus a nonlocal repulsive term. In particular, we prove that a volume-constrained critical point is necessarily a ball if its volume is…
We propose a fast and robust scheme for the direct minimization of the Ohta-Kawasaki energy that characterizes the microphase separation of diblock copolymer melts. The scheme employs a globally convergent modified Newton method with line…
In this paper we study a new model for patterns in two dimensions, inspired by diblock copolymer melts with a dominant phase. The model is simple enough to be amenable not only to numerics but also to analysis, yet sophisticated enough to…