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It has been well known that flexoelectricity can be exploited to generate an analogous piezoelectric response in non-piezoelectric materials. For the direct flexoelectric effect, the induced electric polarization is linearly proportional to…

Materials Science · Physics 2013-11-21 Sivapalan Baskaran , Xiangtong He , John Y. Fu

The relationship between elastic fatigue and electrical cyclic loading in alpha-phase poly(vinylidene fluoride) films has been investigated. Our experimental studies have shown that the electric-field-induced fatigue behavior can be…

Materials Science · Physics 2017-04-04 Xiangtong He , Shaopeng Pei , Robert E. Baier , John Y. Fu

The coupling between strain gradients and polarization, known as flexoelectricity, offers a new mechanism to control the functionality of dielectric materials. However, for the effect to be practically attractive, dynamic control of the…

Flexoelectricity - polarization induced by strain gradients - offers a route to polar functionality in centrosymmetric dielectrics, where traditional piezoelectric effects are absent. This study investigates the flexoelectric effect in…

Pressure-induced polarization switching in ferroelectric thin films has emerged as a powerful method for domain patterning, allowing to create predefined domain patterns on free surfaces and under thin conductive top electrodes. However,…

Materials Science · Physics 2017-12-06 Ye Cao , Anna Morozovska , Sergei V. Kalinin

Flexoelectricity phenomenon is the response of electric polarization to an applied strain gradient and is developed as a consequence of crystal symmetry in all materials. In this study, we show that the presence of strain gradient in…

Computational Physics · Physics 2017-03-03 S. I. Kundalwal , S. A. Meguid , G. J. Weng

X-ray analysis of ferroelectric thin layers of Ba1/2Sr1/2TiO3 with different thickness reveals the presence of internal strain gradients across the film thickness and allows us to propose a functional form for the internal strain profile.…

Materials Science · Physics 2009-11-10 G. Catalan , B. Noheda , J. McAneney , L. Sinnamon , J. M. Gregg

Polyvinylidenefluoride (PVDF) a semicrystalline pieozoelectric polymer was synthesized with varying process conditions and its ferroelectric domain orientations were studied using piezoresponse force microscope (PFM). PVDF thin films…

Flexoelectricity, a coupling between strain gradients and electric polarization, has attracted significant interest due to its critical role in enhanced effects at small scales and its applicability across a diverse range of materials.…

Computational Physics · Physics 2025-02-28 Arash Kazemi , Kshiteej J Deshmukh , Susan Trolier-McKinstry , Shad Roundy

The polarization response of a material to a strain gradient, known as flexoelectricity, holds great promise for novel electromechanical applications. Despite considerable recent progress, however, the effect remains poorly understood. From…

Materials Science · Physics 2014-12-03 Massimiliano Stengel

Recent observations of unusual ferroelectricity in thin films of HfO_2 and related materials have attracted broad interest to the materials and led to the emergence of a number of competing models for observed behaviors. Here we develop the…

Materials Science · Physics 2018-11-27 Maya D. Glinchuk , Anna N. Morozovska , Yunseok Kim , Sergei V. Kalinin

Flexoelectricity induced by strain gradient in dielectrics is highly desirable for electromechanical actuating and sensing systems. It is broadly adopted that flexoelectric polarization responds linearly to strain gradient without…

Materials Science · Physics 2025-04-03 Yingzhuo Lun , Yida Yang , Tingjun Wang , Qi Ren , Sang-Wook Cheong , Xueyun Wang , Jiawang Hong

Polyvinylidene difluoride (PVDF) is a ferroelectric polymer characterized by negative strain along the direction of the applied electric field. However, the electromechanical response mechanism of PVDF remains unclear due to the complexity…

Soft Condensed Matter · Physics 2021-03-17 V. Egorov , O. Maksimova , H. Koibuchi , C. Bernard , J-M. Chenal , O. Lame , G. Diguet , G. Sebald , J-Y. Cavaille , T. Takagi

The conductivity of $\alpha$-polyvinylidene fluoride ($\alpha$-PVDF) is obtained from dielectric measurements performed in the frequency domain at several temperatures. At temperatures above the glass-transition, the conductivity can be…

Materials Science · Physics 2016-08-16 Enis Tuncer , Michael Wegener , Peter Frübing , Reimund Gerhard-Multhaupt

Because of the flexoelectric effect, dielectric materials usually polarize in response to a strain gradient. Soft materials are good candidates for developing large strain gradient because of their good deformability. However, they always…

Soft Condensed Matter · Physics 2019-04-17 Xin Wen , Dongfan Li , Kai Tan , Qian Deng , Shengping Shen

Flexible ferroelectrics possess significant potential for wearable electronics and bio-inspired devices, yet their electromechanical coupling mechanisms under dynamic bending remain elusive. This study employs phase-field simulations to…

Materials Science · Physics 2025-12-16 Changqing Guo , Letao Yang , Jing Wang , Houbing Huang

Phonon engineering focuses on heat transport modulation on atomic-scale. Different from reported methods, it is shown that electric field can also modulate heat transport in ferroelectric polymers, poly(vinylidene fluoride), by both…

Mesoscale and Nanoscale Physics · Physics 2020-11-26 Shichen Deng , Jiale Yuan , Yuli Lin , Xiaoxiang Yu , Dengke Ma , Yuwen Huang , Rencai Ji , Guangzu Zhang , Nuo Yang

Flexoelectricity is a universal effect that generates electric polarization due to broken inversion symmetry caused by local strain gradient. The large strain gradient at nanoscale makes flexo-electric effects, especially in nanoscopic…

Materials Science · Physics 2025-05-30 Xin Li , Guodong Ren , Yu Yun , Arashdeep Singh Thind , Amit Kumar Shah , Abbey Bowers , Rohan Mishra , Xiaoshan Xu

Flexoelectricity describes the coupling between polarization and strain/stress gradients in insulating crystals. In this paper, using the Landau-Ginsburg-Devonshire phenomenological approach, we found that flexoelectricity could increase…

Materials Science · Physics 2015-06-04 Hao Zhou , Jiawang Hong , Yihui Zhang , Faxin Li , Yongmao Pei , Daining Fang

Surface alignment of a recently discovered ferroelectric nematic liquid crystal (NF) is usually achieved by buffed polymer films, which produce a unidirectional polar alignment of the spontaneous electric polarization. We demonstrate that…

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