Related papers: Heat capacity in nonequilibrium steady states
We explore two- and three-state Markov models driven out of thermal equilibrium by non-potential forces to demonstrate basic properties of the steady heat capacity based on the concept of quasistatic excess heat. It is shown that large…
We define the heat capacity for steady periodically driven systems and as an example we compute it for dissipative two-level systems where the energy gap is time-modulated. There, as a function of ambient temperature, the Schottky peak…
This thesis is devoted to the theoretical study of slow thermodynamic processes in non-equilibrium stochastic systems. Its main result is a physically and mathematically consistent construction of relevant thermodynamic quantities in the…
Steady nonequilibria dissipate energy and, when changing external parameters, an extra or excess heat accompanies the relaxation to the new nonequilibrium condition. For nonequilibrium systems in contact with a thermal bath, the heat…
We consider stationary driven systems in contact with a thermal equilibrium bath. There is a constant (Joule) heat dissipated from the steady system to the environment as long as all parameters are unchanged. As a natural generalization…
The extended Third Law of thermodynamics for nonequilibrium jump processes is studied in previous collaborative papers (Kh et al.,2023) [1,2], where the nonequilibrium heat capacity and the excess heat with the corresponding quasipotential…
The notion of a nonequilibrium heat capacity is important for bio-energetics and for calorimetry of active materials more generally. It centers around the notion of excess heat or excess work dissipated during a quasistatic relaxation…
Development of steady state thermodynamics and statistical mechanics depends crucially on our ability to develop notions of equilibrium thermodynamics for nonequilibrium steady states (NESS). The present paper considers the development of…
We discuss via general arguments and examples when and why the steady nonequilibrium heat capacity vanishes with temperature. The framework is the one of Markov jump processes on finite connected graphs where the condition of local detailed…
Using information entropy formalism, we consider a one-dimensional system with heat flux and extend the meaning of equilibrium variables to non equilibrium scenarios when classical local equilibrium approach is not applicable; this is…
The thermal response of nonequilibrium systems requires the knowledge of concepts that go beyond entropy production. This is showed for systems obeying overdamped Langevin dynamics, either in steady states or going through a relaxation…
Close to equilibrium, the excess heat governs the static fluctuations. We study the heat capacity in that McLennan regime, i.e., in linear order around equilibrium, using an expression in terms of the average energy that extends the…
Systems out of equilibrium, in stationary as well as in nonstationary regimes, display a linear response to energy impulses simply expressed as the sum of two specific temporal correlation functions. There is a natural interpretation of…
We study a class of non-equilibrium quasi-stationary states for a Markov system interacting with two different thermal baths. We show that the work done under a slow, external change of parameters admits a potential, i.e., the free energy.…
We present the mathematical ingredients for an extension of the Third Law of Thermodynamics (Nernst heat postulate) to nonequilibrium processes. The central quantity is the excess heat which measures the quasistatic addition to the steady…
Physical systems driven away from equilibrium by an external controller dissipate heat to the environment; the excess entropy production in the thermal reservoir can be interpreted as a "cost" to transform the system in a finite time. The…
Non-equilibrium systems under temperature modulation are investigated in the light of the stochastic thermodynamics. We show that, for small amplitudes of the temperature oscillations, the heat flux behaves sinusoidally with time, a result…
Heat capacities of model systems with finite numbers of effective degrees of freedom are evaluated using canonical and microcanonical thermodynamics. Discrepancies between both approaches, which are observed even in the infinite-size limit,…
For students familiar with equilibrium statistical mechanics, the notion of a positive specific heat, being intimately related to the idea of stability, is both intuitively reasonable and mathematically provable. However, for system in…
We numerically determine the entropy for heat-conducting states, which is connected to the so-called excess heat considered as a basic quantity for steady-state thermodynamics in nonequilibrium. We adopt an efficient method to estimate the…