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Stochastic pumps are models of artificial molecular machines which are driven by periodic time variation of parameters, such as site and barrier energies. The no-pumping theorem states that no directed motion is generated by variation of…

Statistical Mechanics · Physics 2014-07-29 Shahaf Asban , Saar Rahav

From molecular machines to quantum dots, a wide range of mesoscopic systems can be modeled by periodically driven Markov processes, or stochastic pumps. Currents in the stochastic pumps are delimited by an exact no-go condition called the…

Statistical Mechanics · Physics 2014-12-10 Dibyendu Mandal

The control of chemical dynamics requires understanding the effect of time-dependent transition rates between states of chemo-mechanical molecular configurations. Pumping refers to generating a net current, e.g. per period in the…

Statistical Mechanics · Physics 2015-05-18 C. Maes , K. Netocny , S. R. Thomas

The no-pumping theorem states that seemingly natural driving cycles of stochastic machines fail to generate directed motion. Initially derived for single particle systems, the no-pumping theorem was recently extended to many-particle…

Statistical Mechanics · Physics 2017-02-02 Saar Rahav

The no-pumping theorem refers to a Markov system that holds the detailed balance, but is subject to a time-periodic external field. It states that the time-averaged probability currents nullify in the steady periodic (Floquet) state,…

Statistical Mechanics · Physics 2017-04-26 Narek H. Martirosyan

We show that a reversible pumping mechanism operating between two states of a kinetic network can give rise to Poisson transitions between these two states. An external observer, for whom the pumping mechanism is not accessible, will…

Statistical Mechanics · Physics 2015-05-06 Massimiliano Esposito , Juan MR Parrondo

Synthetic nanoscale complexes capable of mechanical movement are often studied theoretically using discrete-state models that involve instantaneous transitions between metastable states. A number of general results have been derived within…

Statistical Mechanics · Physics 2012-12-21 Dibyendu Mandal , Christopher Jarzynski

We analyze the operation of a molecular machine driven by the non-adiabatic variation of external parameters. We derive a formula for the integrated flow from one configuration to another, obtain a "no-pumping theorem" for cyclic processes…

Statistical Mechanics · Physics 2008-10-08 Saar Rahav , Jordan Horowitz , Christopher Jarzynski

We formulate an exact result, which we refer to as the pumping restriction theorem (PRT). It imposes strong restrictions on the currents generated by periodic driving in a generic dissipative system with detailed balance. Our theorem…

Statistical Mechanics · Physics 2009-11-13 V. Y. Chernyak , N. A. Sinitsyn

We analyze a generic model of mesoscopic machines driven by the nonadiabatic variation of external parameters. We derive a formula for the probability current; as a consequence we obtain a no-pumping theorem for cyclic processes satisfying…

Statistical Mechanics · Physics 2009-10-02 Jordan M. Horowitz , Christopher Jarzynski

We calculate a pump current in a classical two-state stochastic chemical kinetics by means of the non-adiabatic geometrical phase interpretation. The two-state system is attached to two particle reservoirs, and under a periodic perturbation…

Biological Physics · Physics 2009-11-13 Jun Ohkubo

We show that current fluctuations in a stochastic pump can be robustly mapped to fluctuations in a corresponding time-independent nonequilibrium steady state. We thus refine a recently proposed mapping so that it ensures equivalence of not…

Statistical Mechanics · Physics 2017-03-22 Grant M. Rotskoff

We establish a correspondence between two very general paradigms for systems that persist away from thermal equilibrium. In the first paradigm, a nonequilibrium steady state (NESS) is maintained by applying fixed thermodynamic forces that…

Statistical Mechanics · Physics 2016-05-25 Oren Raz , Yigit Subasi , Christopher Jarzynski

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito

We study a model of synthetic molecular motor - a [3]-catenane consisting of two small macrocycles mechanically interlocked with a bigger one - subjected to a time-dependent driving using stochastic thermodynamics. The model presents…

Statistical Mechanics · Physics 2023-06-28 Massimo Bilancioni , Massimiliano Esposito , Emanuele Penocchio

Stochastic Thermodynamics uses Markovian jump processes to model random transitions between observable mesoscopic states. Physical currents are obtained from anti-symmetric jump observables defined on the edges of the graph representing the…

Statistical Mechanics · Physics 2015-10-19 Artur Wachtel , Jürgen Vollmer , Bernhard Altaner

The problem of estimating entropy production from incomplete information in stochastic thermodynamics is essential for theory and experiments. Whereas a considerable amount of work has been done on this topic, arguably, most of it is…

Statistical Mechanics · Physics 2024-12-17 Pedro E. Harunari , Carlos E. Fiore , Andre C. Barato

Periodic driving is used to operate machines that go from standard macroscopic engines to small non-equilibrium micro-sized systems. Two classes of such systems are small heat engines driven by periodic temperature variations and molecular…

Statistical Mechanics · Physics 2017-11-16 Somrita Ray , Andre C. Barato

A periodically modulated N-state model whose dynamics is governed by a time-convoluted generalized master equation is theoretically analyzed. It is shown that this non-Markovian master equation can be converted to a Markovian master…

Statistical Mechanics · Physics 2021-06-30 Ville Matias Mikael Paasonen , Hisao Hayakawa

The stochastic theory of non-relativistic quantum mechanics presented here relies heavily upon the theory of stochastic processes, with its definitions, theorems and specific vocabulary as well. Its main hypothesis states indeed that the…

Quantum Physics · Physics 2014-04-01 Maurice J. M. L. O. Godart
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