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Using pair potentials fitted to an ab--initio database, combined with replica--exchange simulated annealing, we show the complex, quasicrystal-related Al$_{11}$Ir$_4$ compound contains a new version of the "pseudo-Mackay" icosahedral…

Materials Science · Physics 2012-06-26 Marek Mihalkovič , C. L. Henley

Phase equilibria in the Al-Ti-Nb-Zr-Ta refractory complex concentrated alloy system were investigated using a high throughput experimental approach. A pseudo-ternary section of the quinary compositional space was prepared by a honeycomb…

Classical molecular dynamics simulation with embedded atom method potential had been performed to investigate the surface structure and solidification morphology of aluminum nanoclusters Aln (n = 256, 604, 1220 and 2048). It is found that…

Materials Science · Physics 2015-05-13 F. L. Tang , W. J. Lu , G. B. Chen , Y. Xie , W. Y. Yu

We resolve issues that have plagued reliable prediction of relative phase stability for solid-solutions and compounds. Due to its commercially important phase diagram, we showcase Al-Li system because historically density-functional theory…

Materials Science · Physics 2013-12-25 Aftab Alam , D. D. Johnson

The intermetallic $\tau_{11}$ Al$_4$Fe$_{1.7}$Si phase is of interest for high-temperature structural application due to its combination of low density and high strength. We determine the crystal structure of the $\tau_{11}$ phase through a…

Alumina ultrathin films obtained by high temperature oxidation of a Ni$_3$Al (111) surface are a good template to grow regular arrays of metal clusters. Up to now two hexagonal organizations called 'dot' and 'network' structures have been…

Chemical Physics · Physics 2020-10-26 Georges Sitja , Aude Bailly , Maurizio de Santis , Vasile Heresanu , Claude Henry

Icosahedral quasicrystals spontaneously form from the melt in simulations of Al--Cu--Fe alloys. We model the interatomic interactions using oscillating pair potentials tuned to the specific alloy system based on a database of density…

Materials Science · Physics 2020-03-04 Marek Mihalkovic , Michael Widom

An archetypical spin-glass metallic alloy, Cu0.83Mn0.17, is studied by means of an ab-initio based approach. First-principles calculations are employed to obtain effective chemical, strain-induced and magnetic exchange interactions, as well…

Materials Science · Physics 2009-06-16 O. E. Peil , A. V. Ruban , B. Johansson

Body-centered cubic (bcc) Fe-Mn systems are known to exhibit a complex and atypical magnetic behaviour from both experiments and 0 K electronic-structure calculations, which is due to the half-filled 3d-band of Mn. We propose effective…

Materials Science · Physics 2021-01-20 Anton Schneider , Chu-Chun Fu , Osamu Waseda , Cyrille Barreteau , Tilmann Hickel

The dodecagonal quasicrystal classified into the five-dimensional space group P126/mmc, recently discovered in a Mn-Cr-Ni-Si alloy, has been analyzed using atomic-resolution spherical aberration-corrected electron microscopy, i.e.…

Materials Science · Physics 2016-02-17 Tsutomu Ishimasa , Shuhei Iwami , Norihito Sakaguchi , Ryo Oota , Marek Mihalkovic

Pd-Zn intermetallic catalysts show encouraging combinations of activity and selectivity on well-defined active site ensembles. Thermodynamic description of the Pd-Zn system, delineating phase boundaries, and enumerating site occupancies…

Materials Science · Physics 2024-02-21 Rushi Gong , Shun-Li Shang , Hui Sun , Michael J. Janik , Zi-Kui Liu

Alloying offers a way to tune many of the properties of the transition metal dichalcogenide (TMD) monolayers. While these systems in many cases have been thoroughly investigated previously, the fundamental understanding of critical…

Materials Science · Physics 2023-04-17 Christopher Linderälv , J. Magnus Rahm , Paul Erhart

Extensive first-principle calculations on embedded clusters containing few O, Y, Ti, and Cr atoms as well as vacancies are performed to obtain interaction parameters to be applied in Metropolis Monte Carlo simulations, within the framework…

Materials Science · Physics 2014-11-05 M. Posselt , D. Murali , B. K. Panigrahi

This study explores Ti-containing complex concentrated alloys (CCAs) within the AlMoNbTiZr system, focusing on compositions located in regions of the Bo-Md diagram characterized by low bond order (Bo) and d-orbital energy level (Md). Four…

Materials Science · Physics 2025-10-10 Mariano Casas-Luna , Dalibor Preisler , Jiří Kozlík , Josef Stráský

We use molecular dynamics as a tool to understand the structure and phase transitions [Osman et. al. J. Phys. Chem. B 2000, 104, 4433; 2002, 106, 653] in alkylammonium micas. The consistent force field 91 is extended for accurate simulation…

Materials Science · Physics 2007-05-23 Hendrik Heinz , Hein J. Castelijns , Ulrich W. Suter

A first-principles approach to the construction of concentration-temperature magnetic phase diagrams of metallic alloys is presented. The method employs self-consistent total energy calculations based on the coherent potential approximation…

Materials Science · Physics 2015-07-29 B. S. Pujari , P. Larson , V. P. Antropov , K. D. Belashchenko

We present structure calculations of neutral and singly ionized Mg clusters of up to 30 atoms, as well as Na clusters of up to 10 atoms. The calculations have been performed using density functional theory (DFT) within the local…

Atomic and Molecular Clusters · Physics 2015-03-19 Stefan Janecek , Eckard Krotscheck , Michael Liebrecht , Roman Wahl

The composition and site occupancy of Mg within ordered {\delta} precipitates in a model Al Mg Li alloy have been characterized by atom probe microscopy and first-principles simulations. The concentration in the precipitates is found to be…

We present total energy and force calculations on the (GaN)$_{1-x}$(ZnO)$_{x}$ alloy. Site-occupancy configurations are generated by Monte Carlo (MC) simulations, based on a cluster expansion (CE) model proposed in a previous study.…

Materials Science · Physics 2015-12-11 Jian Liu , Luana S. Pedroza , Carissa Misch , Maria V. Fernández-Serra , Philip B. Allen

We employ the Monte-Carlo Basin-Hopping (MC-BH) global optimisation technique with inter- atomic pair potentials to generate low-energy candidates of stoichiometric alumina octomers ((Al$_2$O$_3$)$_8$). The candidate structures are…

Materials Science · Physics 2018-10-05 David Gobrecht , Leen Decin , Sergio Cristallo , Stefan T. Bromley