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Specific heat, resistivity, magnetic susceptibility, linear thermal expansion (LTE), and high-resolution synchrotron X-ray powder diffraction investigations of single crystals Fe1+yTe (0.06 < y < 0.15) reveal a splitting of a single,…

We used low-temperature synchrotron x-ray diffraction to investigate the structural phase transitions of Fe1+yTe in the vicinity of a tricitical point in the phase diagram. Detailed analysis of the powder diffraction patterns and…

Superconductivity · Physics 2013-10-03 Cevriye Koz , Sahana Rößler , Alexander A. Tsirlin , Steffen Wirth , Ulrich Schwarz

The low-temperature magnetic phase diagram of the multiferroic system FeTe$_2$O$_5$Br down to 300 mK and up to 9 T is presented. Short-range magnetic correlations within the crystal layers start to develop already at $\sim$50 K, i.e., far…

Strongly Correlated Electrons · Physics 2015-05-19 M. Pregelj , A. Zorko , O. Zaharko , Z. Kutnjak , M. Jagodič , Z. Jagličić , H. Berger , M. de Souza , C. Balz , M. Lang , D. Arčon

We use bulk magnetic susceptibility, electronic specific heat, and neutron scattering to study structural and magnetic phase transitions in Fe$_{1+y}$Se% $_x$Te$_{1-x}$. Fe$_{1.068}$Te exhibits a first order phase transition near 67 K with…

We investigated the evolution of the temperature-composition phase diagram of Fe$_{1+y}$Te upon Se substitution. In particular, the effect of Se substitution on the two-step, coupled magneto-structural transition in Fe$_{1+y}$Te single…

Superconductivity · Physics 2015-05-12 Dona Cherian , S. Rößler , S. Wirth , Suja Elizabeth

We study the effects of Cu substitution in Fe1.1Te, the non-superconducting parent compound of the iron-based superconductor, Fe1+yTe1-xSex, utilizing neutron scattering techniques. It is found that the structural and magnetic transitions,…

We construct a phase diagram of the parent compound Fe1+xTe as a function of interstitial iron x in terms of the electronic, structural, and magnetic properties. For a concentration of x < 10%, Fe1+xTe undergoes a "semimetal" to metal…

Strongly Correlated Electrons · Physics 2015-06-17 E. E. Rodriguez , D. A. Sokolov , C. Stock , M. A. Green , O. Sobolev , J. A. Rodriguez-Rivera , H. Cao , A. Daoud-Aladine

The evolution of the nuclear and magnetic structures of TlFe$_{1.6}$Se$_2$ was determined in the temperature range of 5-450\,K using single crystal neutron diffraction. The Fe layers in these materials develop a corrugation in the…

At 300 K, Y$_{0.9}$Gd$_{0.1}$Fe$_{2}$H$_{x}$ hydrides crystallize sequentially with increasing H concentration in various structures related to a lowering of the cubic MgCu$_{2}$ type structure of the parent alloy: cubic C1, monoclinic M1,…

Materials Science · Physics 2022-10-06 V. Paul-Boncour , K. Provost , T. Mazet , A. N Diaye , E. Alleno , F. Couturas

Structural, magnetic, electrical transport, and heat capacity data are reported for single crystals of TlFe1.6Se2. This compound crystallizes in a tetragonal structure similar to the ThCr2Si2 structure, but with vacancies in the Fe layer.…

The low-temperature crystal structure of Fe1.13Te, which exhibits an anomalous two-step magnetic transition, was clarified by the systematic x-ray diffraction measurements. It was found that two-step structural phase transition,…

Neutron diffraction measurements of a high quality single crystal of CaFe2As2 are reported. A sharp transition was observed between the high temperature tetragonal and low temperature orthorhombic structures at TS = 172.5K (on cooling) and…

Layered transition metal dichalcogenides (TMDCs) host a plethora of interesting physical phenomena ranging from charge order to superconductivity. By introducing magnetic ions into 2H-NbS$_2$, the material forms a family of magnetic…

The first order magneto-structural transition ($T_t\simeq95$ K) and magnetocaloric effect in MnNiGe$_{0.9}$Ga$_{0.1}$ are studied via powder x-ray diffraction and magnetization measurements. Temperature dependent x-ray diffraction…

Materials Science · Physics 2018-01-17 Pallab Bag , R. Nath

The pressure-temperature phase diagram of an intermediate-valence compound YbPd was revealed via simultaneous ac-calorimetry and electrical resistivity measurements. Two successive structural phase transition temperatures, $T_1$ = 125 K and…

We report the effects of hydrostatic pressure on the temperature-induced phase transitions in Fe1.08Te in the pressure range 0-3 GPa using synchrotron powder x-ray diffraction (XRD). The results reveal a plethora of phase transitions. At…

Superconductivity · Physics 2012-09-07 C. Koz , S. Rößler , A. A. Tsirlin , D. Kasinathan , C. Börrnert , M. Hanfland , H. Rosner , S. Wirth , U. Schwarz

Alloys with a first-order magnetic transition are central to solid-state refrigeration technology, sensors and actuators, or spintronic devices. The discontinuous nature of the transition in these materials is a consequence of the coupling…

Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2-xO4(0.0<=x<=1.0). The temperature versus Fe…

This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

Superconductivity · Physics 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

The nuclear and magnetic structure of Fe1+y(Te1-x,Sex) (0 < x < 0.20) compounds was analyzed between 2 K and 300 K by means of Rietveld refinement of neutron powder diffraction data. Samples with x < 0.075 undergo a tetragonal to monoclinic…

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