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We experimentally demonstrate that critical Casimir forces in colloidal systems can be continuously tuned by the choice of boundary conditions. The interaction potential of a colloidal particle in a mixture of water and 2,6-lutidine has…

Soft Condensed Matter · Physics 2009-10-23 Ursula Nellen , Laurent Helden , Clemens Bechinger

Colloids immersed in a critical or near-critical binary liquid mixture and close to a chemically patterned substrate are subject to normal and lateral critical Casimir forces of dominating strength. For a single colloid we calculate these…

Soft Condensed Matter · Physics 2010-08-18 M. Tröndle , S. Kondrat , A. Gambassi , L. Harnau , S. Dietrich

We argue that in a fluid, or magnet, confined by adsorbing walls which favour liquid, or (+) phase, the solvation (Casimir) force in the vicinity of the critical point is strongly influenced by capillary condensation which occurs below the…

Statistical Mechanics · Physics 2009-10-31 A. Drzewinski , A. Maciolek , R. Evans

We examine the solvent-mediated interaction between two neutral colloidal particles due to preferential adsorption in a near-critical binary mixture. We take into account the renormalization effect due to the critical fluctuations using the…

Soft Condensed Matter · Physics 2013-08-21 Ryuichi Okamoto , Akira Onuki

We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…

Soft Condensed Matter · Physics 2015-06-03 T. F. Mohry , A. Maciołek , S. Dietrich

We report the observation of a temperature-controlled synchronization of two Brownian-particles in a binary mixture close to the critical point of the demixing transition. The two beads are trapped by two optical tweezers whose distance is…

Statistical Mechanics · Physics 2017-03-06 Ignacio A. Martínez , Clemence Devailly , Artyom Petrosyan , Sergio Ciliberto

We investigate bridging and aggregation of two colloidal particles in a near-critical binary mixture when the fluid far from the particles is outside the coexistence (CX) curve and is rich in the component disfavored by the colloid…

Soft Condensed Matter · Physics 2015-05-26 Shunsuke Yabunaka , Ryuichi Okamoto , Akira Onuki

Among the various kinds of effective forces in soft matter, the spatial range and the direction of the so-called critical Casimir force - which is generated by the enhanced thermal fluctuations close to a continuous phase transition - can…

Soft Condensed Matter · Physics 2011-02-14 Andrea Gambassi , S. Dietrich

Critical Casimir interactions represent a perfect example of bath-induced forces at mesoscales. These forces may have a relevant role in the living systems as well as a role in the design of nanomachines fueled by environmental…

Mesoscale and Nanoscale Physics · Physics 2023-12-20 Ignacio A. Martinez , Artyom Petrosyan , Sergio Ciliberto

We study the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance $L$ from each other confining a non-polar simple fluid or a binary liquid mixture.…

Statistical Mechanics · Physics 2015-07-20 Galin Valchev , Daniel Dantchev

We review recent advances in the theoretical, numerical, and experimental studies of critical Casimir forces in soft matter, with particular emphasis on their relevance for the structures of colloidal suspensions and on their dynamics.…

Soft Condensed Matter · Physics 2023-12-27 Andrea Gambassi , S. Dietrich

Understanding the phase behaviour of mixtures continues to pose challenges, even for systems that might be considered "simple". Here we consider a very simple mixture of two colloidal and one non-adsorbing polymer species which can be…

If two ore more bodies are immersed in a critical fluid critical fluctuations of the order parameter generate long ranged forces between these bodies. Due to the underlying mechanism these forces are close analogues of the well known…

Soft Condensed Matter · Physics 2009-10-30 M. Krech

We study the critical Casimir interaction between two spherical colloids immersed in a binary liquid mixture close to its critical demixing point. The surface of each colloid prefers one species of the mixture with the exception of a…

Statistical Mechanics · Physics 2020-04-22 Nima Farahmand Bafi , Piotr Nowakowski , Siegfried Dietrich

Some time ago, Fisher and de Gennes pointed out that long-ranged correlations in a fluid close to its critical point Tc cause distinct forces between immersed colloidal particles which can even lead to flocculation [C. R. Acad. Sc. Paris B…

Statistical Mechanics · Physics 2007-05-23 F. Schlesener , A. Hanke , S. Dietrich

We study the fluctuation-induced Casimir interactions in colloidal suspensions, especially between colloids immersed in a binary liquid close to its critical demixing point. To simulate these systems, we present a highly efficient cluster…

Soft Condensed Matter · Physics 2017-06-09 Hendrik Hobrecht , Alfred Hucht

Percolation and critical phenomena show common features such as scaling and universality. Colloidal particles, immersed in a solvent close to criticality, experience long-range effective forces, named critical Casimir forces. %These…

Soft Condensed Matter · Physics 2014-07-16 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

Critical fluctuations are known to induce a collapse of polymer chains in a mixed solvent upon approaching its liquid-liquid critical point, as originally predicted by Brochard and de Gennes. Recently, we have found that closer to the…

Soft Condensed Matter · Physics 2020-01-08 Jan V. Sengers , Mikhail A. Anisimov , Xiong Zheng

Mesoscopic particles immersed in a critical fluid experience long-range Casimir forces due to critical fluctuations. Using field theoretical methods, we investigate the Casimir interaction between two spherical particles and between a…

Condensed Matter · Physics 2009-10-28 E. Eisenriegler , U. Ritschel

We study the non-equilibrium coarsening dynamics of a binary liquid solvent around a colloidal particle in a presence of a time-dependent temperature gradient that emerges after temperature quench of a suitably coated colloid surface. The…

Soft Condensed Matter · Physics 2018-11-30 Sutapa Roy , Anna Maciolek