Related papers: Theory of Sorption Hysteresis in Nanoporous Solids…
We present a theoretical study of the intrusion of an ambient liquid into pores of a nano-corrugated wall w. The pores are prefilled with a liquid lubricant which adheres to the walls of the pores more strongly than the ambient liquid. The…
Boiling heat transfer is the basis of many commonly used cooling techniques. In cooling of electronic devices, for example, it is desirable to further miniaturize heat exchangers to achieve higher heat transfer, and thus it is necessary to…
A particle-water discrete element based approach to describe water movement in partially saturated granular media is presented and tested. Water potential is governed by both capillary bridges, dominant at low saturations, and the pressure…
Hypothesis: A broad range of phenomena, such as emulsification and emulsion stability, foam formation or liquid evaporation, are closely related to the dynamics of adsorbing colloidal particles. Elucidation of the mechanisms implied is key…
Adsorption of water vapor in nanoporous carbons is rather complex due to an interplay between the pore structure and surface chemistry of these materials. Deciphering the mechanism of adsorption requires the knowledge of the spatial…
Recent theoretical research on the fundamentals of statistical mechanics has led to a remarkable discovery [2-4]: with a locally nonchaotic energy barrier, a macroscopic system may produce useful work in a cycle by absorbing heat from a…
We show that during evaporation of a pore network, liquid can refill the gas occupied pores, snapping off a gas bubble, which then moves to a stable configuration. This phenomenon is induced by the capillary instability due to the…
Transition boiling is an intermediate regime occurring between nucleate boiling, where bubbles at the surface efficiently carry heat away, and film boiling, where a layer of vapor formed over the surface insulates the system reducing heat…
Molecular dynamics simulations are used to study the behavior of closely-fitting spherical and ellipsoidal particles moving through a fluid-filled cylinder at nanometer scales. The particle, the cylinder wall and the fluid solvent are all…
Spatial confinement in nanoporous media affects the structure, thermodynamics and mobility of molecular soft matter often markedly. This article reviews thermodynamic equilibrium phenomena, such as physisorption, capillary condensation,…
In this work we report studies of nitrogen adsorption and desorption onto solid surfaces using computer simulations of the three dimensional Ising model, for systems with complex porous structures at the mesoscopic and microscopic levels. A…
Continuum models of porous media use macroscopic parameters and state variables to capture essential features of pore-scale physics. We propose a macroscopic property "accessivity" ($\alpha$) to characterize the network connectivity of…
We develop a model for the thermodynamics and evaporation dynamics of aerosol droplets of a liquid such as water, surrounded by the gas. When the temperature and the chemical potential (or equivalently the humidity) are such that the vapour…
Contact angle hysteresis and generation of dynamics angle are two fundamental phenomena about the contact angle deviation from the equilibrium state. Roughness on the solid surface, disjoining pressure in the thin film, and liquid-solid…
A liquid drop moves on a solid surface if it is subjected to a gradient of wettability or temperature. However, the pinning defects on the surface manifested in terms of a wetting hysteresis, or first-order nonlinear friction, limit the…
In nanoparticle haloing, charged nanoparticles have been found to enhance the stability of colloidal suspensions by forming a non-adsorbing layer surrounding neutral colloids which induces an electrostatic repulsion between them. However,…
Modification of surface properties by polymer adsorption is a widely used technique to tune interactions in molecular experiments such as nanopore sensing. Here, we investigate how the ionic current noise through solid-state nanopores…
We propose a self-consistent model taking into account variations in adsorption properties of the adsorbent surface in the process of adsorption--desorption of molecules of gas on it. We introduce a dimensionless coupling parameter that…
Low-energy structures of a hybrid system consisting of a polymer and an attractive nanowire substrate as well as the thermodynamics of the adsorption transition are studied by means of Monte Carlo computer simulations. Depending on…
We explore the thermodynamic behavior of gases adsorbed within a nanopore. The theoretical description employs a simple lattice gas model, with two species of site, expected to describe various regimes of adsorption and condensation…