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We present elastic and inelastic spin-changing cross sections for cold and ultracold NH($X\,^3\Sigma^-$) + NH($X\,^3\Sigma^-$) collisions, obtained from full quantum scattering calculations on an accurate \textit{ab initio} quintet…

Elastic and spin-changing inelastic collision cross sections are presented for cold and ultracold magnetically trapped NH. The cross sections are obtained from coupled-channel scattering calculations as a function of energy and magnetic…

We carry out calculations on $M$-changing collisions of NH ($^3\Sigma^-$) molecules in magnetically trappable states using a recently calculated potential energy surface. We show that elastic collision rates are much faster than inelastic…

Chemical Physics · Physics 2015-05-13 Alisdair O. G. Wallis , Jeremy M. Hutson

We present a detailed analysis of the role of the magnetic dipole-dipole interaction in cold and ultracold collisions. We focus on collisions between magnetically trapped NH molecules, but the theory is general for any two paramagnetic…

Chemical Physics · Physics 2015-05-27 Liesbeth M. C. Janssen , Ad van der Avoird , Gerrit C. Groenenboom

We calculate the interaction potential between N atoms and NH molecules and use it to investigate cold and ultracold collisions important for sympathetic cooling. The ratio of elastic to inelastic cross sections is large over a wide range…

Chemical Physics · Physics 2011-02-23 Piotr S. Żuchowski , Jeremy M. Hutson

We present a rigorous quantum scattering study of the effects of hyperfine and Zeeman interactions on cold Li - H$_{2}$ collisions in the presence of an external magnetic field using a recent ab initio potential energy surface. We find that…

Chemical Physics · Physics 2024-03-06 Hubert Jóźwiak , Timur V. Tscherbul , Piotr Wcisło

We investigate the ultracold reaction dynamics of magnetically trapped NH($X ^3\Sigma^-$) radicals using rigorous quantum scattering calculations involving three coupled potential energy surfaces. We find that the reactive NH + NH cross…

Chemical Physics · Physics 2013-02-06 Liesbeth M. C. Janssen , Ad van der Avoird , Gerrit C. Groenenboom

We report on the influence of hyperfine interaction on the optical orientation of singly charged excitons X+ and X- in self-assembled InAs/GaAs quantum dots. All measurements were carried out on individual quantum dots studied by…

Materials Science · Physics 2009-04-10 O. Krebs , B. Eble , A. Lemaître , P. Voisin , B. Urbaszek , X. Marie , T. Amand

Hyperfine interactions, magnetic interactions between the spins of electrons and nuclei, in graphene and related carbon nanostructures are studied. By using a combination of accurate first principles calculations on graphene fragments and…

Materials Science · Physics 2008-04-09 Oleg V. Yazyev

We calculate the quartet potential energy surface for Li+NH and use it to calculate elastic and spin-relaxation cross sections for collisions in magnetically trappable spin-stretched states. The potential is strongly anisotropic but…

The effects of hyperfine structure on ultracold molecular collisions in external fields are largely unexplored due to major computational challenges associated with rapidly proliferating hyperfine and rotational channels coupled by highly…

Atomic Physics · Physics 2023-11-28 Timur V. Tscherbul , Jose P. D'Incao

The effect of conical intersections (CIs) on electronic relaxation, transitions from excited states to ground states, is well studied, but their influence on hyperfine quenching in a reactant molecule is not known. Here, we report on…

Chemical Physics · Physics 2021-01-29 Ming Li , Jacek Klos , Alexander Petrov , Hui Li , Svetlana Kotochigova

Nuclear spins are among the potential candidates prospected for quantum information technology. A recent breakthrough enabled to atomically resolve their interaction with the electron spin, the so-called hyperfine interaction, within…

Mesoscale and Nanoscale Physics · Physics 2021-06-09 Sufyan Shehada , Manuel dos Santos Dias , Filipe Souza Mendes Guimarães , Muayad Abusaa , Samir Lounis

We report on the magnetic and Mossbauer properties of polycrystalline HoFe1-xCrxO3 compounds. Magnetization data reveals the continuous tailoring of magnetic transition due to weakening of Ho3+ Fe3+ and Fe3+ Fe3+ interactions in the entire…

Materials Science · Physics 2017-03-08 Ganesh Kotnana , V. Raghavendra Reddy , S. Narayana Jammalamadaka

We have calculated elastic and state-resolved inelastic cross sections for cold and ultracold collisions in the Rb($^1 S$) + OH($^2 \Pi_{3/2}$) system, including fine-structure and hyperfine effects. We have developed a new set of five…

Atomic Physics · Physics 2015-06-26 Manuel Lara , John L. Bohn , Daniel E. Potter , Pavel Soldán , Jeremy M. Hutson

Collisions with chemically inert atoms or molecules change the hyperfine coupling of an alkali-metal atom through the hyperfine-shift interaction. This interaction is responsible for the pressure shifts of the microwave resonances of…

Atomic Physics · Physics 2013-06-04 B. H. McGuyer

While attaining external field control of bimolecular chemical reactions has long been a coveted goal of physics and chemistry, the role of hyperfine interactions and dc magnetic fields in achieving such control has remained elusive. We…

Chemical Physics · Physics 2020-02-12 Timur V. Tscherbul , Jacek Kłos

We consider the spin-exchange in ultracold collisions of hydrogen ($H$) and antihydrogen ($\bar{H}$) atoms. The cross sections for transitions between various hyperfine states are calculated. We show that the process of spin exchange in…

Atomic Physics · Physics 2015-05-13 A. Yu. Voronin , P. Froelich

The Radical Pair Mechanism is a canonical model for the magnetosensitivity of chemical reaction processes. The key ingredient of this model is the hyperfine interaction that induces a coherent mixing of singlet and triplet electron spin…

Chemical Physics · Physics 2018-09-12 Robert H. Keens , Salil Bedkihal , Daniel R. Kattnig

We explore the suitability of ultracold collisions between spin-polarized SrF($^2\Sigma^+$) molecules and Rb($^2$S) atoms as elementary steps for the sympathetic cooling of SrF($^2\Sigma^+$) molecules in a magnetic trap. To this end, we…

Atomic Physics · Physics 2018-10-17 Masato Morita , Maciej B. Kosicki , Piotr S. Żuchowski , Timur V. Tscherbul
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