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The electronic properties of a graphene sheet with attached hydrogen atoms is studied using a modified Falicov-Kimball model on the honeycomb lattice. It is shown that in the ground state this system separates into two phases: fully…

Mesoscale and Nanoscale Physics · Physics 2012-11-30 A. L. Rakhmanov , A. V. Rozhkov , A. O. Sboychakov , Franco Nori

We investigate the microscopic processes leading to graphene growth by the chemical vapor deposition of propane in the argon atmosphere at the SiC surface. Experimentally, it is known that the presence of argon fastens the dehydrogenation…

Materials Science · Physics 2017-09-13 Malgorzata Wierzbowska , Adam Dominiak , Kamil Tokar

Graphene, the 2D form of carbon, has excellent mechanical, electrical and thermal properties and a variety of potential applications including NEMS, protective coatings, transparent electrodes in display devices and biological applications.…

Mesoscale and Nanoscale Physics · Physics 2018-08-20 Narasimha G Boddeti , Rong Long , Martin L Dunn

We performed a first principles investigation on the structural and electronic properties of group-IV (C, SiC, Si, Ge, and Sn) graphene-like sheets in flat and buckled configurations and the respective hydrogenated or fluorinated…

Materials Science · Physics 2012-04-16 Joelson Cott Garcia , Denille B. de Lima , Lucy V. C. Assali , João F. Justo

When it is oxidized, graphite can be easily exfoliated forming graphene oxide (GO). GO is a critical intermediate for massive production of graphene, and it is also an important material with various application potentials. With many…

Materials Science · Physics 2009-12-31 Wenhua Zhang , Vincenzo Carravetta , Zhenyu Li , Yi Luo , Jinlong Yang

Graphene has recently attracted a great deal of interest in both academia and industry because of its unique electronic and optical properties [1,2], as well as its chemical, thermal, and mechanical properties. The superb characteristics of…

Materials Science · Physics 2010-06-29 Mingsheng Xu , Daisuke Fujita , Keisuke Sagisaka , Eiichiro Watanabe , Nobutaka Hanagata

We study the effects of polarizable substrates such as SiO2 and SiC on the carrier dynamics in graphene. We find that the quasiparticle spectrum acquires a finite broadening due to the long-range interaction with the polar modes at the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Fratini , F. Guinea

Using spin-density functional theory we investigated various possible structures of the hematite (0001) surface. Depending on the ambient oxygen partial pressure, two geometries are found to be particularly stable under thermal equilibrium:…

Materials Science · Physics 2009-10-31 X. -G. Wang , W. Weiss , Sh. K. Shaikhutdinov , M. Ritter , M. Petersen , F. Wagner , R. Schloegl , M. Scheffler

Graphene is a material of great potential in a broad range of applications, for each of which specific tuning of the materials properties is required. This can be achieved, for example, by covalent functionalization. We have exploited two…

We report on an investigation of quasi-free-standing graphene on 6H-SiC(0001) which was prepared by intercalation of hydrogen under the buffer layer. Using infrared absorption spectroscopy we prove that the SiC(0001) surface is saturated…

Materials Science · Physics 2011-10-03 F. Speck , J. Jobst , F. Fromm , M. Ostler , D. Waldmann , M. Hundhausen , H. B. Weber , Th. Seyller

The electrical transport properties of epitaxial graphene layers are correlated with the SiC surface morphology. In this study we show by atomic force microscopy and Raman measurements that the surface morphology and the structure of the…

The structure of the SiC(000-1) surface, the C-face of the {0001} SiC surfaces, is studied as a function of temperature and of pressure in a gaseous environment of disilane (Si2H6). Various surface reconstructions are observed, both with…

Mesoscale and Nanoscale Physics · Physics 2019-08-28 Jun Li , Qingxiao Wang , Guowei He , Michael Widom , Lydia Nemec , Volker Blum , Moon Kim , Patrick Rinke , Randall M. Feenstra

Understanding the adhesion between graphene and other materials is crucial for achieving more reliable graphene-based applications in electronic devices and nanocomposites. The ultra-thin profile of graphene, however, poses significant…

Materials Science · Physics 2011-11-10 Zhao Zhang , Teng Li

The visibility of graphene sheets on different types of substrates has been investigated both theoretically and experimentally. Although single layer graphene is observable on various types of dielectrics under an optical microscope, it is…

Materials Science · Physics 2009-12-29 Guoquan Teo , Haomin Wang , Yihong Wu , Jun Zhang , Zaibing Guo , Zhenhua Ni , Zexiang Shen

Computer simulations are employed to investigate the adsorption mechanisms of ethane on both homogeneous and inhomogeneous substrates. For homogeneous surfaces, the full range of surface phase transitions - from incomplete to complete…

Soft Condensed Matter · Physics 2026-04-01 Ł. Baran , D. Tarasewicz , W. Rżysko

We evaluate the optical reflectivity for a uniaxially strained graphene single layer between a SiO2 substrate and air. A tight binding model for the band dispersion of graphene is employed. As a function of the strain modulus and direction,…

Mesoscale and Nanoscale Physics · Physics 2010-01-04 F. M. D. Pellegrino , G. G. N. Angilella , R. Pucci

The growth of graphene on copper by atmospheric pressure chemical vapor deposition in a system free of pumping equipment is investigated. The emphasis is put on the necessity of hydrogen presence during graphene synthesis and cooling. In…

Hydrogenation has proven to be an effective tool to open the bandgap of graphene. In the present density functional study we demonstrate that single-side-hydrogenated graphene is a semiconductor with an indirect bandgap of 1.89 eV, in…

Materials Science · Physics 2011-03-01 Bhalchandra S. Pujari , Sergey Gusarov , Michael Brett , Andriy Kovalenko

We calculate the electronic structure and magnetic properties of hydrogenated graphite surfaces using van der Waals density functional theory (DFT) and model Hamiltonians. We find, as previously reported, that the interaction between…

Mesoscale and Nanoscale Physics · Physics 2015-03-06 M. Moaied , J. V. Alvarez , J. J. Palacios

We probe the local inhomogeneities of the electronic properties of graphene at the nanoscale using scanning probe microscopy techniques. First, we focus on the study of the electronic inhomogeneities caused by the graphene-substrate…

Mesoscale and Nanoscale Physics · Physics 2012-10-16 A. Castellanos-Gomez , Arramel , M. Wojtaszek , R. H. M. Smit , N. Tombros , N. Agraït , B. J. van Wees , G. Rubio-Bollinger
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