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Time-dependent density functional theory (TDDFT) is widely used for understanding and predicting properties and behaviors of matter. As one of the fundamental theorems in TDDFT, van Leeuwen's theorem [Phys. Rev. Lett. 82, 3863 (1999)]…

Statistical Mechanics · Physics 2024-03-08 Jiong-Hang Liang , Tian-Xing Hu , D. Wu , Zheng-Mao Sheng , J. Zhang

Quantum computing with qudits, quantum systems with $d > 2$ levels, offers a powerful extension beyond qubits, expanding the computational possibilities of quantum systems, allowing the simplification of the implementation of several…

Quantum Physics · Physics 2024-10-10 Francesco Pudda , Mario Chizzini , Luca Crippa

One route to numerically propagating quantum systems is time-dependent density functional theory (TDDFT). The application of TDDFT to a particular system's time evolution is predicated on $V$-representability which we have analyzed in a…

Quantum Physics · Physics 2020-10-27 James Brown , Jun Yang , James D Whitfield

This paper establishes the applicability of density functional theory methods to quantum computing systems. We show that ground-state and time-dependent density functional theory can be applied to quantum computing systems by proving the…

Quantum Physics · Physics 2015-05-13 Frank Gaitan , Franco Nori

The key features of density-functional theory (DFT) within a minimalistic implementation of quantum electrodynamics are demonstrated, thus allowing to study elementary properties of quantum-electrodynamical density-functional theory…

An approximate solution to the time-dependent density functional theory (TDDFT) response equations for finite systems is developed, yielding corrections to the single-pole approximation. These explain why allowed Kohn-Sham transition…

Materials Science · Physics 2009-11-07 H. Appel , E. K. U. Gross , K. Burke

Density-potential functional theory (DPFT) is an alternative formulation of orbital-free density functional theory that may be suitable for modeling the electronic structure of large systems. To date, DPFT has been applied mainly to quantum…

Materials Science · Physics 2023-04-21 Martin-Isbjörn Trappe , William C. Witt , Sergei Manzhos

We present time-dependent density functional theory (TDDFT) calculations for single and dimerized Coumarin-343 molecules in order to investigate the quantum mechanical effects of chromophore aggregation in extended systems designed to…

Chemical Physics · Physics 2013-09-23 Donghyun Lee , Loren Greenman , Mohan Sarovar , K. Birgitta Whaley

The time-dependent density functional (TDDFT) equations may be written either for the Kohn-Sham orbitals in Hilbert space or for the single electron density matrix in Liouville space. A collective-oscillator, quasiparticle, representation…

Strongly Correlated Electrons · Physics 2009-11-10 Oleg Berman , Shaul Mukamel

The primary computational challenge when simulating nonadiabatic ab initio molecular dynamics is the unfavorable compute costs of electronic structure calculations with molecular size. Simple electronic structure theories, like…

Chemical Physics · Physics 2023-06-28 Justin J. Talbot , Martin Head-Gordon , Stephen J. Cotton

The quantum Fourier transform for discrete variable (dvQFT) is an efficient algorithm for several applications. It is usually considered for the processing of quantum bits (qubits) and its efficient implementation is obtained with two…

Quantum Physics · Physics 2025-12-16 Gianfranco Cariolaro , Edi Ruffa , Amir Mohammad Yaghoobianzadeh , Jawad A. Salehi

We present a unified heterogeneous computing framework for real-time time-dependent density functional theory (RT-TDDFT) based on numerical atomic orbitals (NAOs), implemented in the ABACUS package. We introduce three co-designed…

Materials Science · Physics 2026-03-24 Taoni Bao , Yuanbo Li , Zichao Deng , Haotian Zhao , Denghui Lu , Yike Huang , Chao Lian , Lixin He , Mohan Chen

The time-dependent density functional theory (TDDFT) provides a unified description of the structure and reaction. The linear approximation leads to the random-phase approximation (RPA) which is capable of describing a variety of collective…

Nuclear Theory · Physics 2016-05-09 Kai Wen , Kouhei Washiyama , Ni Fang , Takashi Nakatsukasa

What interactions are sufficient to simulate arbitrary quantum dynamics in a composite quantum system? We provide an efficient algorithm to simulate any desired two-body Hamiltonian evolution using any fixed two-body entangling n-qubit…

Quantum Physics · Physics 2009-11-07 Jennifer L. Dodd , Michael A. Nielsen , Michael J. Bremner , Robert T. Thew

Real-time, time-dependent density functional theory (RT-TDDFT) has gained popularity as a first-principles approach to study a variety of excited-state phenomena such as optical excitations and electronic stopping. Within RT-TDDFT…

Materials Science · Physics 2019-07-23 Dillon C. Yost , Yi Yao , Yosuke Kanai

In the present paper, we intent to enlarge the axiomatic framework of non-commutative quantum field theories (QFT). We consider QFT on non-commutative spacetimes in terms of the tempered ultrahyperfunctions of Sebasti\~ao e Silva…

Mathematical Physics · Physics 2008-02-23 Daniel H. T. Franco , José A. Lourenço , Luiz H. Renoldi

We show that a lattice formulation of density-functional theory (DFT), guided by renormalization-group concepts, can be used to obtain numerical predictions of energy gaps, spin-density profiles, critical exponents, sound velocities,…

Strongly Correlated Electrons · Physics 2009-11-13 Francisco C. Alcaraz , Klaus Capelle

Large scale Density Functional Theory (DFT) based electronic structure calculations are highly time consuming and scale poorly with system size. While semi-empirical approximations to DFT result in a reduction in computational time versus…

Materials Science · Physics 2016-12-21 Ganesh Hegde , R. Chris Bowen

As a universal quantum mechanical approach to the dynamical many-body problem, the time-dependent density functional theory (TDDFT) might be inadequate to describe crucial observables that rely on two-body evolution behavior, like the…

Computational Physics · Physics 2025-11-17 Jiong-Hang Liang , Yunfeng Xiong

The presence of pairing correlations within the time-dependent density functional theory (TDDFT) extension to superfluid systems, is tantamount to the presence of a quantum collision integral in the evolution equations, which leads to an…

Nuclear Theory · Physics 2024-06-24 Aurel Bulgac , Matthew Kafker , Ibrahim Abdurrahman , Ionel Stetcu