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We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

The simplicity of single-molecule junctions based on direct bonding of a small molecule between two metallic electrodes make them an ideal system for the study of fundamental questions related to molecular electronics. Here we study the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 O. Tal , M. Kiguchi , W. H. A. Thijssen , D. Djukic , C. Untiedt , R. H. M. Smit , J. M. van Ruitenbeek

The characteristics of molecular electronic devices are critically determined by metal-organic interfaces, which influence the arrangement of the orbital levels that participate in charge transport. Studies on self-assembled monolayers…

A single molecule break junction device serves as a tunable model system for probing the many body Kondo state. The low-energy properties of this state are commonly described in terms of a Kondo model, where the response of the system to…

Strongly Correlated Electrons · Physics 2013-06-28 Gavin D. Scott , Douglas Natelson , Stefan Kirchner , Enrique Muñoz

Impressive advances in the field of molecular spintronics allow one to study electron transport through individual magnetic molecules embedded between metallic leads in the purely quantum regime of single electron tunneling. Besides…

Strongly Correlated Electrons · Physics 2019-09-05 Alessandro Chiesa , Emilio Macaluso , Paolo Santini , Stefano Carretta , Eva Pavarini

Metallic atomic junctions pose the ultimate limit to the scaling of electrical contacts. They serve as model systems to probe electrical and thermal transport down to the atomic level as well as quantum effects occurring in one-dimensional…

Mesoscale and Nanoscale Physics · Physics 2017-05-24 Nico Mosso , Ute Drechsler , Fabian Menges , Peter Nirmalraj , Siegfried Karg , Heike Riel , Bernd Gotsmann

The effect on molecular transport due to chemical modification of the metal-molecule interface is investigated, using as an example the prototypical molecular device formed by attaching a p-disubstituted benzene molecule onto two gold…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

Recently Smit et al. [Nature 419, 906 (2002)] have reported that a single hydrogen molecule can form a bridge between Pt electrodes, which has a conductance close to one quantum unit, carried by a single channel. We present density…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. Heurich , F. Pauly , J. C. Cuevas , W. Wenzel , Gerd Schoen

Stable organic radicals integrated into molecular junctions represent a practical realization of the single-orbital Anderson impurity model. Motivated by recent experiments for perchlorotriphenylmethyl (PTM) molecules contacted to gold…

Strongly Correlated Electrons · Physics 2018-10-02 W. H. Appelt , A. Droghetti , L. Chioncel , M. M. Radonjic , E. Munoz , S. Kirchner , D. Vollhardt , I. Rungger

We present a systematic study of the ballistic electron conductance through sp and 3d transition metal atoms attached to copper and palladium crystalline electrodes. We employ the 'ab initio' screened Korringa-Kohn-Rostoker Green's function…

Materials Science · Physics 2007-05-23 Alexei Bagrets , Nikos Papanikolaou , Ingrid Mertig

The linear and nonlinear transport properties of the single-electron transistor at the degeneracy point are investigated for the case of weak single-mode tunnel junctions. Two opposing scenarios are considered, distinguished by whether or…

Strongly Correlated Electrons · Physics 2007-05-23 Amnon Buxboim , Avraham Schiller

Electronic transport properties for single-molecule junctions have been widely measured by several techniques, including mechanically controllable break junctions, electromigration break junctions or by means of scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2020-07-22 Ferdinand Evers , Richard Korytár , Sumit Tewari , Jan M. van Ruitenbeek

Using the tight-binding model and the generalized Green's function formalism, the effect of quantum interference on the electron transport through the benzene molecule in a semiconductor/benzene/semiconductor junction is numerically…

Mesoscale and Nanoscale Physics · Physics 2016-08-09 Javad Vahedi , Zahra Sartipi

In the present work we theoretically analyze thermoelectric transport in single-molecule junctions (SMJ) characterized by strong interactions between electrons on the molecular linkers and phonons in their nuclear environments where…

Mesoscale and Nanoscale Physics · Physics 2024-01-17 Natalya A. Zimbovskaya

Quantum transport properties through single polycyclic hydrocarbon molecules attached to two metallic electrodes are studied by the use of Green's function technique. A parametric approach based on the tight-binding model is introduced to…

Mesoscale and Nanoscale Physics · Physics 2009-12-20 Santanu K. Maiti

Self-assembled-monolayer (SAM) molecular junctions (MJs) constitute a promising building block candidate for future molecular electronic devices. Transport properties of SAM-MJs are usually calculate using either the phenomenological…

Mesoscale and Nanoscale Physics · Physics 2015-06-30 Yonatan Dubi

We present a theoretical study of the transport characteristics of molecular junctions, where first-row diatomic molecules are attached to (001) gold and platinum electrodes. We find that the conductance of all of these junctions is of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 J. Ferrer , V. M. Garcia-Suarez

We investigate electron transport through a mono-atomic wire which is tunnel coupled to two electrodes and also to the underlying substrate. The setup is modeled by a tight-binding Hamiltonian and can be realized with a scanning tunnel…

Mesoscale and Nanoscale Physics · Physics 2010-11-25 Tomasz Kwapinski , Sigmund Kohler , Peter Hanggi

We propose a tight-binding model to investigate electronic transport properties of single helical protein molecules incorporating both the helical symmetry and the possibility of multiple charge transfer pathways. Our study reveals that due…

Mesoscale and Nanoscale Physics · Physics 2016-06-10 Sourav Kundu , S. N. Karmakar

We explore electron transport properties in molecular wires made of heterocyclic molecules (pyrrole, furan and thiophene) by using the Green's function technique. Parametric calculations are given based on the tight-binding model to…

Mesoscale and Nanoscale Physics · Physics 2009-09-13 Santanu K. Maiti , S. N. Karmakar