Related papers: Ices in starless and starforming cores
Context. The formation and destruction of molecules in the interstellar medium is a complex interplay between gas-phase reactions as well as processes on grain surfaces and within icy mantles. For many decades, the gas-phase composition of…
(abridged) Data and results from the WISH key program are summarized, designed to provide a legacy data set to address its physics and chemistry. WISH targeted ~80 sources along the two axes of luminosity and evolutionary stage: from low-…
Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…
The 4.62 micron absorption band, observed along the line-of-sight towards various young stellar objects, is generally used as a qualitative indicator for energetic processing of interstellar ice mantles. This interpretation is based on the…
CO is the most widely used gas tracer of protoplanetary disks. Its abundance is usually assumed to be an interstellar ratio throughout the warm molecular layer of the disk. But recent observations of low CO gas abundance in many…
Even today in our Galaxy, stars form from gas cores in a variety of environments, which may affect the properties of resulting star and planetary systems. Here we study the role of pressure, parameterized via ambient clump mass surface…
Complex organic molecules (COMs) detected in the gas phase are thought to be mostly formed on icy grains, but no unambiguous detection of icy COMs larger than CH3OH has been reported so far. Exploring this matter in more detail has become…
Chemical models and experiments indicate that interstellar dust grains and their ice mantles play an important role in the production of complex organic molecules (COMs). To date, the most complex solid-phase molecule detected with…
To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms…
Recent studies of the nearest star-forming clouds of the Galaxy at submillimeter wavelengths with the Herschel Space Observatory have provided us with unprecedented images of the initial conditions and early phases of the star formation…
The formation of stars and planetary systems is a complex phenomenon, which relies on the interplay of multiple physical processes. Nonetheless, it represents a crucial stage for our understanding of the Universe, and in particular of the…
We report the detection of a unique CO2 ice band toward the deeply embedded, low-mass protostar HOPS-68. Our spectrum, obtained with the Infrared Spectrograph onboard the Spitzer Space Telescope, reveals a 15.2 micron CO2 ice bending mode…
H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent…
Determining the locations of the major snowlines in protostellar environments is crucial to fully understand the planet formation process and its outcome. Despite being located far enough from the central star to be spatially resolved with…
Nitrogen-bearing molecules are more difficult to observe than oxygen-bearing ones, mainly due to the lower abundance of nitrogen in the interstellar medium. Therefore, the formation pathways of many of these species is still under debate.…
The gas near the midplanes of planet-forming protostellar disks remains largely unprobed by observations due to the high optical depth of commonly observed molecules such as CO and H$_2$O. However, rotational emission lines from rare…
Recent observations of the HDO/H$_2$O ratio toward protostars in isolated and clustered environments show an apparent dichotomy, where isolated sources show higher D/H ratios than clustered counterparts. Establishing which physical and…
HCN is among the most commonly detected molecules in star- and planet-forming regions. It is of broad interest as a tracer of star-formation physics, a probe of nitrogen astrochemistry, and an ingredient in prebiotic chemical schemes.…
CO$_2$ is an important, stable, and abundant molecule in the Universe, but it is very difficult to detect because it has no observable pure rotational transitions. The unique sensitivity and resolution of the James Webb Space Telescope…
The main accretion phase of star formation is investigated in clouds with different metallicities in the range of 0 \le Z \le Z_\odot, resolving the protostellar radius. Starting from a near-equilibrium prestellar cloud, we calculate the…