Related papers: The Spitzer ice legacy: Ice evolution from cores t…
We study the formation conditions of icy planetesimals in protoplanetary disks in order to determine the composition of ices in small and cold extrasolar planets. Assuming that ices are formed from hydrates, clathrates, and pure…
Understanding the chemical evolution in star-forming cores is a necessary pre-condition to correctly assess physical conditions when using molecular emission. We follow the evolution of chemistry and molecular line profiles through the…
We present the combined 2.5$-$30$\mu$m spectra of four protostars acquired with the infrared camera and the infrared spectrograph on board the AKARI and Spitzer space telescopes, respectively. To analyze the ice absorption features in the…
The evolution of C and O abundances in the Milky Way can impose strong constraints on stellar nucleosynthesis and help understanding the formation and evolution of our Galaxy. The aim is to review the measured C and O abundances in the disk…
The main accretion phase of star formation is investigated in clouds with different metallicities in the range of 0 \le Z \le Z_\odot, resolving the protostellar radius. Starting from a near-equilibrium prestellar cloud, we calculate the…
The icy mantles of interstellar dust grains are the birthplaces of the primordial prebiotic molecular inventory that may eventually seed nascent solar systems and the planets and planetesimals that form therein. Here, we present a study of…
Nitrogen-bearing molecules are more difficult to observe than oxygen-bearing ones, mainly due to the lower abundance of nitrogen in the interstellar medium. Therefore, the formation pathways of many of these species is still under debate.…
We present a comprehensive study of the evolution of the abundances of intermediate mass elements, from C to Zn, in the Milky Way halo and in the local disk. We use a consistent model to describe the evolution of those two galactic…
Using the DR12 public release of APOGEE data, we show that thin and thick disk separate very well in the space defined by [$\alpha$/Fe], [Fe/H] and [C/N]. Thick disk giants have both higher [C/N] and higher [$\alpha$/Fe] than do thin disk…
We report the detection of a unique CO2 ice band toward the deeply embedded, low-mass protostar HOPS-68. Our spectrum, obtained with the Infrared Spectrograph onboard the Spitzer Space Telescope, reveals a 15.2 micron CO2 ice bending mode…
Elemental abundances, particularly the C/O ratio, are seen as a way to connect the composition of planetary atmospheres with planet formation scenario and the disc chemical environment. We model the chemical composition of gas and ices in a…
We present a Spitzer InfraRed Spectrometer search for 10-36 micron molecular emission from a large sample of protoplanetary disks, including lines from H2O, OH, C2H2, HCN and CO2. This paper describes the sample and data processing and…
Context. Carbon, oxygen and nitrogen (CNO) are key elements in stellar formation and evolution, and their abundances should also have a significant impact on planetary formation and evolution. Aims. We present a detailed spectroscopic…
(abridged) Data and results from the WISH key program are summarized, designed to provide a legacy data set to address its physics and chemistry. WISH targeted ~80 sources along the two axes of luminosity and evolutionary stage: from low-…
The volatile composition of a planet is determined by the inventory of gas and ice in the parent disk. The volatile chemistry in the disk is expected to evolve over time, though this evolution is poorly constrained observationally. We…
Astrochemical models are essential to bridge the gap between the timescales of reactions, experiments, and observations. Ice chemistry in these models experiences a large computational complexity as a result of the many parameters required…
Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…
Complex organic molecules (COMs) are known to be abundant toward some low-mass young stellar objects (YSOs), but how these detections relate to typical COM abundance are not yet understood. We aim to constrain the frequency distribution of…
We model the temperature and chemical structure of molecular clouds as a function of depth into the cloud, assuming a cloud of constant density n illuminated by an external FUV (6 eV < E < 13.6 eV) flux G_0 (scaling factor in multiples of…
Nitrogen-bearing complex organic molecules have been commonly detected in the gas phase but not yet in interstellar ices. This has led to the long-standing question of whether these molecules form in the gas phase or in ices. $\textit{James…