Related papers: The Spitzer ice legacy: Ice evolution from cores t…
The chemical evolution in star forming regions is driven by the interplay between gas and ice mantles. Identifying the ice compositions at the early stage of star formation thus provides constraints on the chemical processes inaccessible…
We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…
Stars form from the gravitational collapse of dense molecular cloud cores. In the protostellar phase, mass accretes from the core onto a protostar, likely through an accretion disk, and it is during this phase that the initial masses of…
We present 5.2-37.2 micron spectroscopy of the edge-on circumstellar disk CRBR 2422.8-3423 obtained using the InfraRed Spectrograph (IRS) of the Spitzer Space Telescope. The IRS spectrum is combined with ground-based 3-5 micron spectroscopy…
The icy material within protoplanetary disks plays a central role in planet formation, yet remains poorly characterized by observations. We present 1.6-28$\mu$m spectra of five disks obtained as part of the JWST Edge-on Disk Ice (JEDIce)…
Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study…
Icy grain mantles are the main reservoir of the volatile elements that link chemical processes in dark, interstellar clouds with the formation of planets and composition of their atmospheres. The initial ice composition is set in the cold,…
To date, at least three comets -- 2I/Borisov, C/2016 R2 (PanSTARRS), and C/2009 P1 (Garradd) -- have been observed to have unusually high CO concentrations compared to water. We attempt to explain these observations by modeling the effect…
NH3 and CH3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and HCOOCH3. Despite a number of recent studies, little is known about their abundances in the…
[ABRIDGED] In order to trace the origin and evolution of carbon in the Galactic disk we have determined carbon abundances in 51 nearby F and G dwarf stars. The sample is divided into two kinematically distinct subsamples with 35 and 16…
We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…
Ices are the main carriers of volatiles in protoplanetary disks and are crucial to our understanding of the chemistry that ultimately sets the organic composition of planets. The ERS program Ice Age on the JWST follows the ice evolution…
A rich inventory of complex organic molecules (COMs) has been observed in high abundances in the gas phase toward Class 0 protostars. These molecules are suggested to be formed in ices and sublimate in the warm inner envelope close to the…
A powerful way to observe directly the solid state inventory of dense molecular clouds is by infrared spectroscopy of background stars. We present Spitzer/IRS 5-20 micron spectra of ices toward stars behind the Serpens and Taurus molecular…
CO is thought to be the main reservoir of volatile carbon in protoplanetary disks, and thus the primary initial source of carbon in the atmospheres of forming giant planets. However, recent observations of protoplanetary disks point towards…
The origin of the elevated C/O ratios in discs around late M dwarfs compared to discs around solar-type stars is not well understood. Here we endeavour to reproduce the observed differences in the disc C/O ratios as a function of stellar…
Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…
Water is detected in environments representing every stage of star and solar system formation, but its chemical evolution throughout these stages remains poorly constrained. Deuterium ratios offer a means of probing chemical links between…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Massive young stellar objects in the Magellanic Clouds show infrared absorption features corresponding to significant abundances of CO, CO$_2$ and H$_2$O ice along the line of sight, with the relative abundances of these ices differing…