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Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

We present a sub-grid model for star formation in galaxy simulations, incorporating molecular hydrogen ($\mathrm{H}_2$) production via dust grain condensation and its destruction through star formation and photodissociation. Implemented…

Astrophysics of Galaxies · Physics 2025-10-02 E. Lozano , C. Scannapieco , S. E. Nuza , Y. Ascasibar , V. Springel

Observations of spiral galaxies show a strong linear correlation between the ratio of molecular to atomic hydrogen surface density R_mol and midplane pressure. To explain this, we simulate three-dimensional, magnetized turbulence, including…

Astrophysics of Galaxies · Physics 2015-05-20 Mordecai-Mark Mac Low , Simon C. O. Glover

A prominent chemical reaction in interstellar clouds is the formation of molecular hydrogen by recombination, which essentially takes place on dust grain surfaces. Analytical approaches to model such a system have hitherto neglected the…

Astrophysics · Physics 2009-11-11 Ingo Lohmar , Joachim Krug

Star formation activity in molecular clouds is often found to be correlated with the amount of material above a column density threshold of $\sim 10^{22} \, {\rm cm^{-2}}$. Attempts to connect this column density threshold to a ${\it…

Astrophysics of Galaxies · Physics 2023-10-11 F. D. Priestley , P. C. Clark , S. C. O. Glover , S. E. Ragan , O. Fehér , L. R. Prole , R. S. Klessen

We study the formation of water and methanol in the dense cloud conditions to find the dependence of its production rate on the binding energies, reaction mechanisms, temperatures, and grain site number. We wish to find the effective grain…

Astrophysics · Physics 2009-11-13 Ankan Das , Kinsuk Acharyya , Sonali Chakrabarti , Sandip Kumar Chakrabarti

The H2 molecule has two nuclear spin isomers, the so-called ortho and para isomers. Nuclear spin conversion (NSC) between these states is forbidden in the gas phase. The energy difference between the lowest ortho and para states is as large…

Astrophysics of Galaxies · Physics 2021-03-10 Masashi Tsuge , Toshinobu Namiyoshi , Kenji Furuya , Tomoya Yamazaki , Akira Kouchi , Naoki Watanabe

The conversion of the IR emission into star formation rate can be strongly dependent on the physical properties of the dust, which are affected by the environmental conditions where the dust is embedded. We study here the dust properties of…

This paper presents an analysis of the concentration of the hydrogen molecule inside the ionized region of planetary nebulae. The equations corresponding to the ionization and chemical equilibria of H, H+, H-, H2, H2+, and H3+ are coupled…

Astrophysics · Physics 2009-11-10 I. Aleman , R. Gruenwald

We have carried out an investigation of the chemical evolution of gas in different carbon-rich circumstellar environments. Previous studies have tended to invoke terrestrial flame chemistries, based on acetylene (C2H2) combustion to model…

Astrophysics of Galaxies · Physics 2015-06-15 Harpreet Dhanoa , Jonathan M. C. Rawlings

Detailed models for the density and temperature profiles of gas and dust in protoplanetary disks are constructed by taking into account X-ray and ultraviolet (UV) irradiation from a central T Tauri star, as well as dust size growth and…

Astrophysics · Physics 2011-02-11 H. Nomura , Y. Aikawa , M. Tsujimoto , Y. Nakagawa , T. J. Millar

The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…

The chemical inventory of protoplanetary midplanes is the basis for forming planetesimals. Among them, solid-state reactions based on CO/CO$_2$ toward molecular complexity on interstellar dust grains have been studied in theoretical and…

Solar and Stellar Astrophysics · Physics 2023-10-31 K. -J. Chuang , C. Jaeger , N. -E. Sie , C. -H. Huang , C. -Y. Lee , Y. -Y. Hsu , Th. Henning , Y. -J. Chen

It is a fact that interstellar formation processes are thermodynamically affected. Based on this, the seven heterocycles; imidazole, pyridine, pyrimidine, pyrrole, quinoline, isoquinoline and furan that have been searched for from different…

Astrophysics of Galaxies · Physics 2021-09-08 Emmanuel E. Etim , ROA Adelagun , Chrysanthus Andrew , Oladimeji Enock Oluwole

The storage of hydrogen (H$_2$) is of economic and ecological relevance, because it could potentially replace petroleum-based fuels. However, H$_2$ storage at mild condition remains one of the bottlenecks for its widespread usage. In order…

Materials Science · Physics 2019-12-24 Srimanta Pakhira , Jose L. Mendoza-Cortes

We present a novel framework to self-consistently model the effects of radiation fields, dust physics and molecular chemistry (H$_2$) in the interstellar medium (ISM) of galaxies. The model combines a state-of-the-art radiation…

Molecular clouds typically consist of 3/4 H2, 1/4 He and traces of heavier elements. In an earlier work we showed that at very low temperatures and high densities, H2 can be in a phase transition leading to the formation of ice clumps as…

Astrophysics of Galaxies · Physics 2016-06-30 Andreas Füglistaler , Daniel Pfenniger

In the interstellar medium of the Milky Way, certain elements -- e.g., Mg, Si, Al, Ca, Ti, Fe -- reside predominantly in interstellar dust grains. These grains absorb, scatter, and emit electromagnetic radiation, heat the interstellar…

Astrophysics · Physics 2007-05-23 B. T. Draine

[Abridged] Do some environments favor efficient conversion of molecular gas into stars? To answer this, we need to be able to estimate the H2 mass. Traditionally, this is done using CO and a few assumptions but the Herschel observations in…

In this study, we present a suite of high-resolution numerical simulations of an isolated galaxy to test a sub-grid framework to consistently follow the formation and dissociation of H$_2$ with non-equilibrium chemistry. The latter is…

Astrophysics of Galaxies · Physics 2017-12-27 Alessandro Lupi , Stefano Bovino , Pedro R. Capelo , Marta Volonteri , Joseph Silk