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The $\mathrm{H}_2$ formation on grains is known to be sensitive to dust temperature, which is also known to fluctuate for small grain sizes due to photon absorption. We aim at exploring the consequences of simultaneous fluctuations of the…

Astrophysics of Galaxies · Physics 2014-10-01 Emeric Bron , Jacques Le Bourlot , Franck Le Petit

Context. The formation of water on the dust grains in the interstellar medium may proceed with hydrogen peroxide (H2O2) as an intermediate. Recently gas-phase H2O2 has been detected in {\rho} Oph A with an abundance of ~1E-10 relative to…

Astrophysics of Galaxies · Physics 2015-06-03 Fujun Du , Berengere Parise , Per Bergman

At low temperatures (10 K), hydrogen atoms can diffuse quickly on grain ice mantles and frequently encounter hydrogen molecules, which cover a notable fraction of grain surface. The desorption energy of H atoms on H2 substrates is much less…

Solar and Stellar Astrophysics · Physics 2021-03-31 Qiang Chang , Xuli Zheng , Xia Zhang , Donghui Quan , Yang Lu , Qingkuan Meng , Xiaohu Li , Long-Fei Chen

Molecular hydrogen (H2) is the primary component of the reservoirs of cold, dense gas that fuel star formation in our galaxy. While the H2 abundance is ultimately regulated by physical processes operating on small scales in the interstellar…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-11 Robert Feldmann , Jose Hernandez , Nickolay Y. Gnedin

We consider the survival of solid H2 in the diffuse interstellar medium, with application to grains which are small enough to qualify as dust. Consideration of only the thermal aspects of this problem leads to the familiar conclusion that…

Astrophysics of Galaxies · Physics 2015-06-16 Mark A. Walker

An analysis of the kinetics of H2 formation on interstellar dust grains is presented using rate equations. It is shown that semi-empirical expressions that appeared in the literature represent two different physical regimes. In particular,…

Astrophysics · Physics 2009-10-30 O. Biham , I. Furman , N. Katz , V. Pirronello , G. Vidali

Condensation of H 2 in the interstellar medium (ISM) has long been seen as a possibility, either by deposition on dust grains or thanks to a phase transition combined with self-gravity. H 2 condensation might explain the observed low…

Astrophysics of Galaxies · Physics 2018-06-06 Andreas Füglistaler , Daniel Pfenniger

Hydrogen sulfide (H$_2$S) is thought to be efficiently formed on grain surfaces through the successive hydrogenation of S atoms. Its non-detection so far in astronomical observations of icy dust mantles thus indicates that effective…

Astrophysics of Galaxies · Physics 2023-08-17 Julia C. Santos , Harold Linnartz , Ko-Ju Chuang

Methods: The microscopic equations of H2-formation and protonation are integrated numerically over time in such a manner that the overall structures evolve self-consistently under benign conditions. Results: The equilibrium H2 formation…

Astrophysics of Galaxies · Physics 2009-11-13 H. S. Liszt

H2 is the simplest and the most abundant molecule in the ISM, and its formation precedes the formation of other molecules. Understanding the dynamical influence of the environment and the interplay between the thermal processes related to…

Astrophysics of Galaxies · Physics 2016-02-24 Valeska Valdivia , Patrick Hennebelle , Maryvonne Gérin , Pierre Lesaffre

Unlike gas-phase reactions, chemical reactions taking place on interstellar dust grain surfaces cannot always be modeled by rate equations. Due to the small grain sizes and low flux,these reactions may exhibit large fluctuations and thus…

Astrophysics of Galaxies · Physics 2018-05-02 F. Le Petit , B. Barzel , O. Biham , E. Roueff , J. le Bourlot

We have investigated the time scale for formation of molecular clouds by examining the conversion of HI to H2 using a time-dependent model. H2 formation on dust grains and cosmic ray and photo destruction are included in one-dimensional…

Astrophysics · Physics 2008-11-26 Paul F. Goldsmith , Di Li , Marko Krco

Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…

Solar and Stellar Astrophysics · Physics 2018-09-28 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

A knowledge of the recombination time on the grain surfaces has been a major obstacle in deciding the production rate of molecular hydrogen and other molecules in the interstellar medium. We present a numerical study to compute this time…

Astrophysics · Physics 2009-06-30 Sandip Kumar Chakrabarti , Ankan Das , Kinsuk Acharyya , Sonali Chakrabarti

Context. Interstellar dust particles, which represent 1% of the total mass, are recognized to be very powerful interstellar catalysts in star-forming regions. The presence of dust can have a strong impact on the chemical composition of…

Solar and Stellar Astrophysics · Physics 2015-12-23 S. Cazaux , M. Minissale , F. Dulieu , S. Hocuk

Stars form out of molecular gas and supply dust grains during their last evolutionary stages; in turn hydrogen molecules (H2) are produced more efficiently on dust grains. Therefore, dust can drastically accelerate H2 formation, leading to…

Astrophysics · Physics 2009-11-07 H. Hirashita , A. Ferrara

Nearby spiral galaxies show an extremely tight correlation between tracers of molecular hydrogen (H_2) in the interstellar medium (ISM) and tracers of recent star formation, but it is unclear whether this correlation is fundamental or…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 Mark R. Krumholz , Adam K. Leroy , Christopher F. McKee

The formation of compact dusty clouds in diffuse interstellar medium (ISM) has been recently proposed and studied by Tsytovich et al. (2014). In the present paper, an effect of the clouds on the rate of H$\to$H$_2$ transition in the ISM is…

Astrophysics of Galaxies · Physics 2018-07-11 A. V. Ivlev , A. Burkert , A. Vasyunin , P. Caselli

In the interstellar clouds, molecular hydrogens are formed from atomic hydrogen on grain surfaces. An atomic hydrogen hops around till it finds another one with which it combines. This necessarily implies that the average recombination…

Astrophysics · Physics 2009-11-13 Sandip Kumar Chakrabarti , Ankan Das , Kinsuk Acharyya , Sonali Chakrabarti

Context: Fast surface conversion between ortho- and para-H2 has been observed in laboratory studies, and this mechanism has been proposed to play a role in the control of the ortho-para ratio in the interstellar medium. Observations of…

Astrophysics of Galaxies · Physics 2016-03-16 Emeric Bron , Franck Le Petit , Jacques Le Bourlot