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Accurate characterization of entropy plays a pivotal role in capturing reversible and irreversible heating in supercapacitors during charging/discharging cycles. However, numerical methods that can faithfully capture entropy variation in…

Numerical Analysis · Mathematics 2024-09-17 Jie Ding , Xiang Ji , Shenggao Zhou

We use a simple hard-core gas model to study the dynamics of small exploding systems. The system is initially prepared in a thermalized state in a spherical container and then allowed to expand freely into the vacuum. We follow the…

Nuclear Theory · Physics 2015-06-26 J. P. Bondorf , I. N. Mishustin , G. Neergaard

Distinct entropy definitions have been used to obtain an inverse correlation between the residual size and entropy for Heavy Ion Collisions. This explains the existence of several temperatures for different residual size bins, as reported…

Nuclear Theory · Physics 2007-05-23 A. Barrañón , J. A. López , J. Escamilla Roa

The volume of phase space may grow super-exponentially ("explosively") with the number of degrees of freedom for certain types of complex systems such as those encountered in biology and neuroscience, where components interact and create…

Statistical Mechanics · Physics 2018-07-26 Henrik Jeldtoft Jensen , Roozbeh H. Pazuki , Gunnar Pruessner , Piergiulio Tempesta

We illustrate the application of Quantum Computing techniques to the investigation of the thermodynamical properties of a simple system, made up of three quantum spins with frustrated pair interactions and affected by a hard sign problem…

The 2nd law of thermodynamics yields an irreversible increase in entropy until thermal equilibrium is achieved. This irreversible increase is often assumed to require large and complex systems to emerge from the reversible microscopic laws…

Statistical Mechanics · Physics 2023-11-21 Ralph V. Chamberlin

The entropy definition in the microcanonical ensemble is revisited. We propose a novel definition for the microcanonical entropy that resolve the debate on the correct definition of the microcanonical entropy. In particular we show that…

Statistical Mechanics · Physics 2019-08-15 Roberto Franzosi

For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that…

Statistical Mechanics · Physics 2007-05-23 R. P. Venkataraman

We comment on some conceptual and and technical problems related to computational mechanics, point out some errors in several papers, and straighten out some wrong priority claims. We present explicitly the correct algorithm for…

Data Analysis, Statistics and Probability · Physics 2018-04-09 Peter Grassberger

Dissipative quantum systems are frequently described within the framework of the so-called "system-plus-reservoir" approach. In this work we assign their description to the Maximum Entropy Formalism and compare the resulting thermodynamic…

Statistical Mechanics · Physics 2017-01-04 Lisan M. M. Durão , Amir O. Caldeira

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

Estimating vibrational entropy is a significant challenge in thermodynamics and statistical mechanics due to its reliance on quantum mechanical properties. This paper introduces a quantum algorithm designed to estimate vibrational entropy…

Quantum Physics · Physics 2025-11-25 Shangjie Guo , Corneliu Buda , Nathan Wiebe

In this paper I propose a new way for counting the microstates of a system out of equilibrium. As, according to quantum mechanics, things happen as if a given particle can be found in more than one state at once, I extend this concept to…

Quantum Physics · Physics 2009-11-13 Norton G. de Almeida

Using information entropy formalism, we consider a one-dimensional system with heat flux and extend the meaning of equilibrium variables to non equilibrium scenarios when classical local equilibrium approach is not applicable; this is…

Statistical Mechanics · Physics 2019-09-10 Sergey Sobolev

Preparing thermal equilibrium states is an essential task for finite-temperature quantum simulations. In statistical mechanics, microstates in thermal equilibrium can be obtained from statistical ensembles. To date, numerous ensembles have…

Quantum Physics · Physics 2025-05-23 Yasushi Yoneta

Due to the equivalence of the statistical ensembles thermostatic properties of physical systems with short-range interactions can be calculated in different ensembles leading to the same physics. In particular, the ensemble equivalence…

Statistical Mechanics · Physics 2009-11-11 Hans Behringer

A general formulation of stochastic thermodynamics is presented for open systems exchanging energy and particles with multiple reservoirs. By introducing a partition in terms of "macrostates" (e.g. sets of "microstates"), the consequence on…

Statistical Mechanics · Physics 2015-06-03 Massimiliano Esposito

I present a theoretical model of a quantum statistical ensemble for which, unlike in conventional physics, the total number of particles is extremely small. The thermodynamical quantities are calculated by taking a small $N$ by virtue of…

Quantum Physics · Physics 2010-01-15 Enrico Prati

This paper argues that the requirement of applicableness of quantum linearity to any physical level from molecules and atoms to the level of macroscopic extensional world, which leads to a main foundational problem in quantum theory…

Quantum Physics · Physics 2014-06-25 Arkady Bolotin

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati