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The intrinsic doping level of graphene prepared by mechanical exfoliation and standard lithography procedures on thermally oxidized silicon varies significantly and seems to depend strongly on processing details and the substrate…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Myrsini Lafkioti , Benjamin Krauss , Timm Lohmann , Ute Zschieschang , Hagen Klauk , Klaus v. Klitzing , Jurgen H. Smet

Graphene has attracted increasing interests due to its remarkable properties, however, the zero band gap of monolayer graphene might limit its further electronic and optoelectronic applications. Herein, we have successfully synthesized…

We have demonstrated that the island nucleation in the initial stage of epitaxial thin film growth can be tuned by substrate surface charge doping. This charge effect was investigated using spin density functional theory calculation in…

Materials Science · Physics 2015-06-19 Wenmei Ming , Feng Liu

Nitrogen-doped epitaxial graphene grown on SiC(000?1) was prepared by exposing the surface to an atomic nitrogen flux. Using Scanning Tunneling Microscopy (STM) and Spectroscopy (STS), supported by Density Functional Theory (DFT)…

We present a technique to tune the charge density of epitaxial graphene via an electrostatic gate that is buried in the silicon carbide substrate. The result is a device in which graphene remains accessible for further manipulation or…

We present a microscopic study on the impact of doping on the carrier dynamics in graphene, in particular focusing on its influence on the technologically relevant carrier multiplication in realistic, doped graphene samples. Treating the…

Mesoscale and Nanoscale Physics · Physics 2017-01-17 Faris Kadi , Torben Winzer , Andreas Knorr , Ermin Malic

At very high doping levels the van Hove singularity in the $\pi^*$ band of graphene becomes occupied and exotic ground states possibly emerge, driven by many-body interactions. Employing a combination of ytterbium intercalation and…

Mesoscale and Nanoscale Physics · Physics 2020-10-20 Philipp Rosenzweig , Hrag Karakachian , Dmitry Marchenko , Kathrin Küster , Ulrich Starke

Graphene is known as the strongest 2D material in nature, yet we show that moderate charge doping of either electrons or holes can further enhance its ideal strength by up to ~17%, based on first principles calculations. This unusual…

Materials Science · Physics 2015-06-11 Chen Si , Wenhui Duan , Zheng Liu , Feng Liu

Graphene multilayers are grown epitaxially on single crystal silicon carbide. This system is composed of several graphene layers of which the first layer is electron doped due to the built-in electric field and the other layers are…

Self-doping in graphene has been studied by examining single-layer epitaxially grown graphene samples with differing characteristic lateral terrace widths. Low energy electron microscopy was used to gain real-space information about the…

Mesoscale and Nanoscale Physics · Physics 2009-01-15 D. A. Siegel , S. Y. Zhou , F. El Gabaly , A. V. Fedorov , A. K. Schmid , A. Lanzara

We perform a phenomenological analysis of the problem of the electronic doping of a graphene sheet by deposited transition metal atoms, which aggregate in clusters. The sample is placed in a capacitor device such that the electronic doping…

Strongly Correlated Electrons · Physics 2015-03-19 Jaime E. Santos , Nuno M. R. Peres , Joao M. B. Lopes dos Santos , Antonio H. Castro Neto

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

Materials Science · Physics 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

While the mechanical distortions change the electronic properties of graphene significantly, the effects of electronic manipulation on its mechanical properties have not been known. Using first-principles calculation methods, we show that,…

Materials Science · Physics 2013-02-20 S. J. Woo , Young-Woo Son

We present a new way to tune the electron-phonon coupling (EPC) in graphene by changing the deformation potential with electron/hole doping. We show the EPC for highest optical branch at the high symmetry point K, acquires a strong…

Materials Science · Physics 2011-05-03 Claudio Attaccalite , Ludger Wirtz , Michele Lazzeri , Francesco Mauri , Angel Rubio

It has been shown that graphene doping is sufficient to lead to an improvement in the critical current density - field performance (Jc(B)), with little change in the transition temperature in MgB2. At 3.7 at% graphene doping of MgB2 an…

Superconductivity · Physics 2015-05-18 X. Xu , S. X. Dou , X. L. Wang , J. H. Kim , J. A. Stride , M. Choucair , W. K. Yeoh , R. K. Zheng , S. P. Ringer

Due to their unique dimensionality, the physical properties of two-dimensional materials are deeply impacted by their surroundings, calling for a thorough understanding and control of these effects. We investigated the influence of the…

We report on the existence of water-gated charge doping of graphene deposited on atomically flat mica substrates. Molecular films of water in units of ~0.4 nm-thick bilayers were found to be present in regions of the interface of…

Materials Science · Physics 2021-07-16 Jihye Shim , Chun Hung Lui , Taeg Yeoung Ko , Young-Jun Yu , Philip Kim , Tony F. Heinz , Sunmin Ryu

The implementation of graphene in semiconducting technology requires the precise knowledge about the graphene-semiconductor interface. In our work the structure and electronic properties of the graphene/$n$-Ge(110) interface are…

In this review we highlight recent theoretical and experimental work on sublattice asymmetric doping of impurities in graphene, with a focus on substitutional Nitrogen dopants. It is well known that one current limitation of graphene in…

Mesoscale and Nanoscale Physics · Physics 2014-11-13 James A. Lawlor , Mauro S. Ferreira

The doping efficiency of lithium deposited at cryogenic temperatures on epitaxial and CVD monolayer graphene has been investigated under ultra-high vacuum conditions. Change of charge carrier density was monitored by gate voltage shift of…

Mesoscale and Nanoscale Physics · Physics 2016-11-15 Ali Khademi , Ebrahim Sajadi , Pinder Dosanjh , Doug Bonn , Joshua A. Folk , Alexander Stöhr , Stiven Forti , Ulrich Starke