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The Gaussian expansion method (GEM) is extensively applied to the calculations in the random-phase approximation (RPA). We adopt the mass-independent basis-set that has been tested in the mean-field calculations. By comparing the RPA…

Nuclear Theory · Physics 2015-05-13 H. Nakada , K. Mizuyama , M. Yamagami , M. Matsuo

In this paper the authors study a non-linear elliptic-parabolic system, which is motivated by mathematical models for lithium-ion batteries. One state satisfies a parabolic reaction diffusion equation and the other one an elliptic equation.…

Numerical Analysis · Mathematics 2023-08-02 Behzad Azmi , Andrea Petrocchi , Stefan Volkwein

We investigate the applicability of the two major approximations which are most commonly employed in the study of the quantum Rabi model, namely the description of a resonant cavity mode as a single-mode quantized field and the use of the…

Quantum Physics · Physics 2017-09-25 I. D. Feranchuk , A. V. Leonov , O. D. Skoromnik

The squeezing effect arises in the interacting qubit-oscillator system is studied with the presence of a parametric oscillator in the Rabi model. Based on the generalized rotating wave approximation which works well in the wide range of…

Quantum Physics · Physics 2021-05-25 V. Yogesh , Prosenjit Maity

Extensive variational computations are reported for the ground state energy of the non-relativistic two-electron atom. Several different sets of basis functions were systematically explored, starting with the original scheme of Hylleraas.…

Atomic Physics · Physics 2009-11-07 Charles Schwartz

We demonstrate that, if a truncated expansion of a wave function is Large, then the standard excited states computational method, of optimizing one root of a secular equation, according to the theorem of Hylleraas, Undheim and McDonald…

Chemical Physics · Physics 2016-12-07 Z. Xiong , J. Zang , H. J. Liu , D. Karaoulanis , Q. Zhou , N. C. Bacalis

We study an expansion method for high-dimensional parabolic PDEs which constructs accurate approximate solutions by decomposition into solutions to lower-dimensional PDEs, and which is particularly effective if there are a low number of…

Analysis of PDEs · Mathematics 2016-11-08 Christoph Reisinger , Rasmus Wissmann

Effective Hamiltonians, when used in tandem with statistical mechanics techniques, offer a rigorous connection between 0 Kelvin ab-initio predictions and finite temperature experimental observations. For alloys, cluster expansion…

Materials Science · Physics 2016-09-26 Elizabeth Decolvenaere , Michael J. Gordon , Anton Van der Ven

A novel, exact, theoretical method for the study of the excited states of a system is presented. It is demonstrated how to transform the excited state problem of one Hamiltonian into the ground state problem of an auxiliary one. From this,…

Quantum Physics · Physics 2012-06-22 Ramón Alain Miranda Quintana

The Rabi Hamiltonian describes a single mode of electromagnetic radiation interacting with a two-level atom. Using the coupled cluster method, we investigate the time evolution of this system from an initially empty field mode and an…

Quantum Physics · Physics 2009-11-07 R. F. Bishop , C. Emary

The Hubbard model is a challenging quantum many-body problem and serves as a benchmark for quantum computing research. Accurate computation of its ground and excited state energies is essential for understanding correlated electron systems.…

Quantum Physics · Physics 2025-09-03 Mrinal Dev , Bikash K. Behera , Vivek Vyas , Prasanta K. Panigrahi

We investigate an extension of excited state mean-field theory in which the energy expression is augmented with density functional components in an effort to include the effects of weak electron correlations. The approach remains…

Chemical Physics · Physics 2020-02-05 Luning Zhao , Eric Neuscamman

We consider the task of simulating time evolution under a Hamiltonian $H$ within its low-energy subspace. Assuming access to a block-encoding of $H'=(H-E)/\lambda$ for some $E \in \mathbb R$, the goal is to implement an…

Quantum Physics · Physics 2024-08-28 Alexander Zlokapa , Rolando D. Somma

A systematic method for determining correlated wavefunctions of extended systems in the ground and excited states is presented. It allows to fully exploit the power of quantum-chemical programs designed for correlation calculations of…

Other Condensed Matter · Physics 2007-05-23 V. Bezugly

We consider the problem of estimating the energy of a quantum state preparation for a given Hamiltonian in Pauli decomposition. For various quantum algorithms, in particular in the context of quantum chemistry, it is crucial to have energy…

Quantum Physics · Physics 2025-08-20 Alexander Gresch , Uğur Tepe , Martin Kliesch

We present an analytical method for the two-qubit quantum Rabi model. While still operating in the frame of the generalized rotating-wave approximation (GRWA), our method further embraces the idea of introducing variational parameters. The…

Quantum Physics · Physics 2019-04-23 Bin-Bin Mao , Liangsheng Li , Yimin Wang , Wen-Long You , Wei Wu , Maoxin Liu , Hong-Gang Luo

Extensions of statistical mechanics are routinely being used to infer free energies from the work performed over single-molecule nonequilibrium trajectories. A key element of this approach is the ubiquitous expression dW/dt=\partial H(x,t)/…

Statistical Mechanics · Physics 2009-11-13 Jose M. G. Vilar , J. Miguel Rubi

We show that, as in Hartree Fock theory, the orbitals for excited state mean field theory can be optimized via a self-consistent one-electron equation in which electron-electron repulsion is accounted for through mean field operators. In…

Chemical Physics · Physics 2020-12-02 Tarini S. Hardikar , Eric Neuscamman

Hamiltonian Truncation Effective Theory is a framework that aims to improve the results of Hamiltonian truncation in a systematic, order-by-order fashion using Effective Field Theory methodology. The result is a truncated effective…

High Energy Physics - Theory · Physics 2025-07-30 Ekrem Demiray , Kara Farnsworth , Rachel Houtz

It is proven that the exact excited-state wave function and energy may be obtained by minimizing the energy expectation value of trial wave functions that are constrained only to have the correct nodes of the state of interest. This…

Quantum Physics · Physics 2018-08-24 Federico Zahariev , Mark S. Gordon , Mel Levy