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Structural and electronic properties of CaCu{3}Ti{4}O{12} have been calculated using density-functional theory within the local spin-density approximation. After an analysis of structural stability, zone-center optical phonon frequencies…

Materials Science · Physics 2009-11-07 Lixin He , J. B. Neaton , Morrel H. Cohen , David Vanderbilt , C. C. Homes

We have investigated the structural and dielectric properties of Sr$_{2}$TiO$_{4}$,the first member of the Sr$_{n+1}$Ti$_{n}$O$_{3n+1}$ Ruddlesden-Popper series, within density functional theory. Motivated by recent work in which thin films…

Materials Science · Physics 2009-11-10 Craig J. Fennie , Karin M. Rabe

We have performed a first-principles study of the structural and vibrational properties of the three low-pressure (cubic, tetragonal, and especially monoclinic) phases of ZrO2, with special attention to the computation of the zone-center…

Materials Science · Physics 2009-11-07 Xinyuan Zhao , David Vanderbilt

We derive a dielectric function tensor model approach to render the optical response of monoclinic and triclinic symmetry materials with multiple uncoupled infrared and farinfrared active modes. We apply our model approach to monoclinic…

Crystalline structures, zone-center phonon modes, and the related dielectric response of the three low-pressure phases of HfO2 have been investigated in density-functional theory using ultrasoft pseudopotentials and a plane-wave basis. The…

Materials Science · Physics 2009-11-07 Xinyuan Zhao , David Vanderbilt

Structural, vibrational, and lattice dielectric properties of CdCu{3}Ti{4}O{12} are studied using density-functional theory within the local spin-density approximation, and the results are compared with those computed previously for…

Materials Science · Physics 2009-11-07 Lixin He , J. B. Neaton , David Vanderbilt , Morrel H. Cohen

The structural, dielectric and dynamical properties of the low temperature antiferromagnetic orthorhombic phase of CaMnO$_3$ have been computed from first principles using a density functional theory approach within the local spin density…

Materials Science · Physics 2009-11-13 Satadeep Bhattacharjee , Eric Bousquet , Philippe Ghosez

We have investigated the electronic, vibrational, optical, thermal and piezoelectric properties of LiNbO$_3$, LiTaO$_3$ and Li$_2$NbTaO$_6$ using the first-principles calculation based on the density functional theory. It also shows…

Materials Science · Physics 2025-03-28 Debidutta Pradhan , Rojalin Swain , Souvagya Kumar Biswal , Jagadish Kumar

The optical and electronic properties of the {\alpha}-SiTe, {\beta}-SiTe, and RX-SiTe_2 are investigated. A detailed analysis of electronic properties is done using standard density functional theory (DFT) and hybrid functional (HSE06)…

Materials Science · Physics 2021-06-30 Romakanta Bhattarai , Xiao Shen

Present work provides extensive DFT study of TlReO4 using pseudopotential approach for understanding the structural and vibrational properties and full-potential linearized augmented plane wave method for electronic band structure and…

Materials Science · Physics 2019-06-18 S. Mondal , G. Vaitheeswaran , Daniel Errandonea

Using the linear response theory, the vibrational and dielectric properties are calculated for c-BN, w-BN and h-BN. Calculations of the zone-center optical-mode frequencies (including LO-TO splittings) are reported. All optic modes are…

Materials Science · Physics 2011-08-02 Yongqing Cai , Litong Zhang , Qingfeng Zeng , Laifei Cheng , Yongdong Xu

We calculate the lattice dielectric function of strongly anharmonic rutile $\mathrm{TiO}_2$ from ab initio anharmonic lattice dynamics methods. Since an accurate calculation of the $\Gamma$ point phonons is essential for determining optical…

Materials Science · Physics 2023-03-24 Tomohito Amano , Tamio Yamazaki , Ryosuke Akashi , Terumasa Tadano , Shinji Tsuneyuki

We have performed a first principles study of structural, mechanical, electronic, and optical properties of orthorhombic Sb2S3 and Sb2Se3 compounds. The calculations have been carried out within the local density approximation using norm…

Materials Science · Physics 2015-06-04 H. Koc , Amirullah M. Mamedov , E. Deligoz

Vibration properties of Zn(1-x)Be(x)Se, a mixed II-VI semiconductor haracterized by a high contrast in elastic properties of its pure constituents, ZnSe and BeSe, are simulated by first-principles calculations of electronic structure,…

Materials Science · Physics 2009-11-10 A. V. Postnikov , Olivier Pages , Joseph Hugel

The dynamical, dielectric and elastic properties of GeTe, a ferroelectric material in its low temperature rhombohedral phase, have been investigated using first-principles density functional theory. We report the electronic energy bands,…

Materials Science · Physics 2009-01-06 R. Shaltaf , E. Durgun , J. -Y. Raty , Ph. Ghosez , X. Gonze

Mg-IV-N\textsubscript{2} compounds with IV=Si, Ge, Sn are ultra-wide band gap semiconductors with various potential electronic and optoelectronic applications. They share the \textit{Pna}2\textsubscript{1} space group crystal structure.…

Materials Science · Physics 2026-04-17 Sarker Md. Sadman , Walter R. L. Lambrecht

The structural, electronic, elastic and optical properties of tetragonal (P4mm) phase of Pb0.5Sn0.5TiO3 (PSTO) and Pb0.5Sn0.5Ti0.5(Zr0.5)O3 (PSTZO) are examined by first-principles calculations based on the density functional theory (DFT)…

Materials Science · Physics 2021-03-30 S. G. Kuma , M. M. Woldemariam

We determine the frequency dependence of four independent CdWO$_4$ Cartesian dielectric function tensor elements by generalized spectroscopic ellipsometry within mid-infrared and far-infrared spectral regions. Single crystal surfaces cut…

Materials Science · Physics 2017-04-26 A. Mock , R. Korlacki , S. Knight , M. Schubert

Structural stability and vibrational properties of KN$_3$ have been studied under pressure using the first principles calculations based on the density functional theory (DFT) as well as with semi empirical dispersion correction to the DFT…

Materials Science · Physics 2013-11-08 K. Ramesh Babu , G. Vaitheeswaran

We study the charge-density wave phase in $\textup{TiSe}_2$ by using first principle calculations. We show that, regardless of the local functional used and as long as the cell parameters are in agreement with the experiment,…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Raffaello Bianco , Matteo Calandra , Francesco Mauri
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