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Measurements and calculations have shown significant disagreement regarding the sign and variations of the thermal expansion coefficient (TEC) of graphene $\alpha(T)$. Here we report dedicated Raman scattering experiments conducted for…

We use suspended graphene electromechanical resonators to study the variation of resonant frequency as a function of temperature. Measuring the change in frequency resulting from a change in tension, from 300 K to 30 K, allows us to extract…

Mesoscale and Nanoscale Physics · Physics 2010-04-13 Vibhor Singh , Shamashis Sengupta , Hari S. Solanki , Rohan Dhall , Adrien Allain , Sajal Dhara , Prita Pant , Mandar M. Deshmukh

Contrary to most materials, graphene exhibits a negative thermal expansion coefficient (TEC), i.e it contracts when heated. This contraction is due to the thermal excitation of low energy out-of-plane vibration modes. These flexural modes…

We report a joint study, using Raman micro-spectroscopy and molecular dynamics simulations, on the substrate effect on thermal properties of 2D materials and revisit measurement of thermal expansion coefficient (TEC) of supported 2D film.…

Materials Science · Physics 2020-09-22 Qianchi Feng , Dongshan Wei , Yudan Su , Zhiguang Zhou , Feng Wang , Chuanshan Tian

In this file, we apply the nonequilibrium Green's function method to calculate the coefficient of thermal expansion (CTE) in multiple layers of graphene. We focus on the effect from different layer number $N$. Our main prediction is that:…

Materials Science · Physics 2011-08-31 Jin-Wu Jiang , Jian-Sheng Wang

Graphene and its derivatives distinguish themselves for their large negative thermal expansion even at temperatures as high as 1000K. The linear thermal expansion coefficients (LTEC) of two-dimensional honeycomb structured pure graphene and…

Mesoscale and Nanoscale Physics · Physics 2017-05-01 Sarita Mann , Ranjan Kumar , V. K. Jindal

Based on the first principles calculation combined with quasi-harmonic approximation, in this work we focus on the analysis of temperature dependent lattice geometries, thermal expansion coefficients, elastic constants and ultimate strength…

Materials Science · Physics 2015-06-04 Tianjiao Shao , Bin Wen , Roderick Melnik , Shan Yao , Yoshiyuki Kawazoe , Yongjun Tian

The thermal conductivity of suspended single-layer graphene was measured as a function of temperature using Raman scattering spectroscopy on clean samples prepared directly on a prepatterned substrate by mechanical exfoliation without…

Mesoscale and Nanoscale Physics · Physics 2011-03-18 Jae-Ung Lee , Duhee Yoon , Hakseong Kim , Sang Wook Lee , Hyeonsik Cheong

Proceeding from the model of a two-dimensional elastic continuum, we describe the characteristic features of thermal expansion of graphene using an approach that goes beyond the quasi-harmonic approximation. The negative value of the…

Mesoscale and Nanoscale Physics · Physics 2018-01-24 Viktor N. Bondarev , Vadym Adamyan , Volodymyr V. Zavalniuk

We carried out micro-Raman spectroscopy of graphene layers over the temperature range from approximately 80 K to 370 K. The number of layers was independently confirmed by the quantum Hall measurements and atomic force microscopy. The…

Materials Science · Physics 2008-03-15 I. Calizo , A. A. Balandin , F. Miao , W. Bao , C. N. Lau

The nonequilibrium Green's function method is applied to investigate the coefficient of thermal expansion (CTE) in single-walled carbon nanotubes (SWCNT) and graphene. It is found that atoms deviate about 1% from equilibrium positions at…

Materials Science · Physics 2009-12-01 Jin-Wu Jiang , Jian-Sheng Wang , Baowen Li

We report on the first measurement of the thermal conductivity of a suspended single layer graphene. The measurements were performed using a non-contact optical technique. The near room-temperature values of the thermal conductivity in the…

Materials Science · Physics 2008-03-15 A. A. Balandin , S. Ghosh , W. Bao , I. Calizo , D. Teweldebrhan , F. Miao , C. N. Lau

We explore thermodynamics of a quantum membrane, with a particular application to suspended graphene membrane and with a particular focus on the thermal expansion coefficient. We show that an interplay between quantum and classical…

Mesoscale and Nanoscale Physics · Physics 2016-11-30 I. S. Burmistrov , I. V. Gornyi , V. Yu. Kachorovskii , M. I. Katsnelson , A. D. Mirlin

Thermal conduction was explored and discussed through a combined theoretical and simulation approach in this work. The thermal conductivity k of polycrystalline graphene was calculated by molecular dynamics simulations based on a hexagonal…

Materials Science · Physics 2014-06-05 Yanlei Wang , Zhigong Song , Zhiping Xu

Thermal properties of graphene monolayers are studied by path-integral molecular dynamics (PIMD) simulations, which take into account the quantization of vibrational modes in the crystalline membrane, and allow one to consider anharmonic…

Materials Science · Physics 2017-09-18 Carlos P. Herrero , Rafael Ramirez

The temperature-induced shift of the Raman G line in epitaxial graphene on SiC and Ni surfaces, as well as in graphene supported on SiO2, is investigated with Raman spectroscopy. The thermal shift rate of epitaxial graphene on 6H-SiC(0001)…

Mesoscale and Nanoscale Physics · Physics 2011-02-18 Nicola Ferralis , Roya Maboudian , Carlo Carraro

We investigate the thermal conductivity of suspended graphene as a function of the density of defects, ND, introduced in a controllable way. Graphene layers are synthesized using chemical vapor deposition, transferred onto a transmission…

In this paper, we propose a model to investigate the electron thermionic emission from a single-layer graphene (ignoring the effects of substrate) and to explore its application as the emitter of thermionic energy convertor (TIC). An…

Mesoscale and Nanoscale Physics · Physics 2015-01-22 Shi-Jun Liang , L. K. Ang

We present a simple analytical approach to study anharmonic effects in single layer, bilayer, and multilayer graphene. The coupling between in plane and out of plane modes leads to negative Gr\"uneisen coefficients and negative thermal…

Materials Science · Physics 2015-06-05 P. L. de Andres , F. Guinea , M. I. Katsnelson

Thermal properties of graphene display peculiar characteristics associated to the two-dimensional nature of this crystalline membrane. These properties can be changed and tuned in the presence of applied stresses, both tensile and…

Materials Science · Physics 2018-06-07 Carlos P. Herrero , Rafael Ramirez
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