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Spin-reorientation phase transitions that involve the rotation of a crystal$'$s magnetization have been well characterized in distorted-perovskite oxides such as the orthoferrites. In these systems spin reorientation occurs due to competing…

Strongly Correlated Electrons · Physics 2020-06-29 A. M. Vibhakar , D. D. Khalyavin , P. Manuel , J. Liu , A. A. Belik , R. D. Johnson

We refined the crystal structure of AMnO3, with A = Y, Er, Yb and Lu by single crystal x-ray diffraction. Our results show some distinct differences with previous reports on LuMnO3 and YbMnO3. We show that the ferroelectric behaviour is…

Strongly Correlated Electrons · Physics 2007-05-23 Bas B. van Aken , Auke Meetsma , Thomas T. M. Palstra

Magnetic structures and the relationship between spin and charge-orbital orderings of an A-site ordered double-perovskite manganite SmBaMn2O6, an anticipated multiferroic material, were investigated by means of neutron diffraction. The spin…

Strongly Correlated Electrons · Physics 2021-07-14 Ryoji Kiyanagi , Shigeki Yamada , Hiroshi Aoki , Hajime Sagayama , Taketo Moyoshi , Akiko Nakao , Takahisa Arima

We use ab initio electronic structure calculations in combination with Monte Carlo simulations to investigate the magnetic and ferroelectric properties of bulk orthorhombic HoMnO$_3$ and ErMnO$_3$. Our goals are to explain the…

Materials Science · Physics 2018-12-12 Natalya S. Fedorova , Amadé Bortis , Christoph Findler , Nicola A. Spaldin

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

Multiferroics where at least two primary ferroic orders are present and coupled in a single system constitute an important class of materials. They attracted special consideration as they present both intriguing fundamental physics problems…

The direction of ferroelectric polarization is prescribed by the symmetry of the crystal structure. Therefore, rotation of the polarization direction is largely limited, despite the opportunity it offers in understanding important…

We have investigated orthorhombic $R$MnO$_{3}$ ($R$=(Gd$_{1-y}$Tb$_{y}$)) crystals near the phase boundary between the paraelectric $A$-type-antiferromagnetic (AF) phase (PA) and the ferroelectric transverse-spiral-AF one (FS). The spiral…

Strongly Correlated Electrons · Physics 2015-06-25 K. Noda , M. Akaki , F. Nakamura , D. Akahoshi , H. Kuwahara

We present a first-principles study on the interface between perovskite ferroelectrics (PbTiO3) and conducting magnetic manganites La_{1-x}Sr_xMnO3. We show that by switching the ferroelectric polarization, additional carriers are…

Materials Science · Physics 2015-06-11 Hanghui Chen , Sohrab Ismail-Beigi

Orthorhombic HoMnO3 is a multiferroic in which Mn antiferromagnetic order induces ferroelectricity. A second transition occurs within the multiferroic phase, in which a strong enhancement of the ferroelectric polarization occurs…

Strongly Correlated Electrons · Physics 2021-01-04 Y. W. Windsor , M. Ramakrishnan , L. Rettig , A. Alberca , T. Lippert , C. W. Schneider , U. Staub

The design of novel multiferroic ABO$_3$ perovskites is complicated by the presence of necessary magnetic cations and ubiquitous antiferrodistortive modes, both of which suppress polar distortions. Using first-principles simulations, we…

Materials Science · Physics 2024-06-10 Cameron A. M. Scott , Nicholas C. Bristowe

The double perovskite Y_2NiMnO_6 displays ferromagnetic transition at Tc = 81 K. The ferromagnetic order at low temperature is confirmed by the saturation value of magnetization (M_s) and also, validated by the refined ordered magnetic…

Strongly Correlated Electrons · Physics 2016-09-16 Hariharan Nhalil , Harikrishnan S. Nair , C. M. N. Kumar , Andre M. Strydom , Suja Elizabeth

We show that using epitaxial strain and chemical pressure in orthorhombic YMnO3 and Co-substituted (YMn0.95Co0.05O3) thin films, a ferromagnetic response can be gradually introduced and tuned. These results, together with the measured…

By means of magnetic, specific heat and pyroelectric measurements, we report on magnetic ferroelectricity in the quadruple perovskite \namno, characterized by a canted antiferromagnetic (AFM) CE structure. Surprisingly, ferroelectricity is…

By means of density-functional simulations for half-doped manganites, such as pseudocubic Pr0.5Ca0.5MnO3 and bilayer PrCa2Mn2O7, we discuss the occurrence of ferroelectricity and we explore its crucial relation to the crystal structure and…

Strongly Correlated Electrons · Physics 2013-10-07 Kunihiko Yamauchi , Silvia Picozzi

Orthorhombic single crystals of TbMn0.5Fe0.5O3 are found to exhibit spin-reorientation, magnetization reversal and weak ferromagnetism. Strong anisotropy effects are evident in the temperature dependent magnetization measurements along the…

A monoclinic phase was recently discovered near the morphotropic phase boundary in several high-performance piezoelectric perovskite solid solutions, but its properties have not been reported. In this paper the dielectric, piezo- and…

Materials Science · Physics 2016-08-31 A. A. Bokov , Z. -G. Ye

The functional properties of transition metal perovskite oxides are known to result from a complex interplay of magnetism, polarization, strain, and stoichiometry. Here, we show that for materials with a cooperative Jahn-Teller distortion,…

Materials Science · Physics 2021-01-04 Chiara Ricca , Nicolas Niederhauser , Ulrich Aschauer

We report x-ray diffraction, resistivity, thermopower, and magnetization of Sr3ErMn4-xGaxO10.5-d, in which A-site ordered tetragonal phase appears above x=1, and reveal that the system exhibits typical properties seen in the…

Materials Science · Physics 2015-05-27 W. Kobayashi , T. Ishibashi

High pressure x-ray diffraction (XRD) measurements on RMnO3 (R=Dy, Ho and Lu) reveals that varying structural changes occurs for different R ions. Large lattice changes (orthorhombic strain) occur in DyMnO3 and HoMnO3 while the Jahn-Teller…

Strongly Correlated Electrons · Physics 2014-04-01 T. Wu , T. A. Tyson , H. Chen , P. Gao , T. Yu , Z. Chen , Z. Liu , K. H. Ahn , X. Wang , S. -W. Cheong