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The dissociation of molecules, even the most simple hydrogen molecule, cannot be described accurately within density functional theory because none of the currently available functionals accounts for strong on-site correlation. This problem…

Strongly Correlated Electrons · Physics 2011-01-14 N. Helbig , I. V. Tokatly , A. Rubio

The variational determination of the two-boson reduced density matrix is described for a one-dimensional system of $N$ (where $N$ ranges from $2$ to $10^4$) harmonically trapped bosons interacting via contact interaction. The ground-state…

Quantum Gases · Physics 2026-04-27 Mitchell J. Knight , Harry M. Quiney , Andy M. Martin

We apply reduced density-matrix functional theory to the parabolically confined quantum Hall droplet in the spin-frozen strong magnetic field regime. One-body reduced density matrix functional method performs remarkably well in obtaining…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 E. Tölö , A. Harju

We examine the density-functional theory of macroscopic insulators, obtained in the large-cluster limit or under periodic boundary conditions. For polar crystals, we find that the two procedures are not equivalent. In a large-cluster case,…

Materials Science · Physics 2009-10-28 X. Gonze , Ph. Ghosez , R. W. Godby

One of the most powerful strategies to address properties of real many-body systems is to incorporate data obtained for models, for example, to use data of the homogeneous electron gas in order to build the Local Density Approximation for…

Materials Science · Physics 2026-05-05 Muhammed Hüseyin Güneş , Ayoub Aouina , Vitaly Gorelov , Matteo Gatti , Lucia Reining

We calculate the `exact' potential corresponding to a one-dimensional interacting system of two electrons with a specific, tailored density. We use one-dimensional density-functional theory with a local-density approximation (LDA) on the…

Other Condensed Matter · Physics 2015-05-13 J. P. Coe , I. D'Amico

The exact static and time-dependent Kohn-Sham (KS) exchange-correlation (xc) potential is extremely challenging to approximate as it is a local multiplicative potential that depends on the electron density everywhere in the system. The KS…

Strongly Correlated Electrons · Physics 2021-01-15 M. J. P. Hodgson , J. Wetherell

Density functional approximations to the exchange-correlation energy of Kohn-Sham theory, such as the local density approximation and generalized gradient approximations, lack the well-known integer discontinuity, a feature that is critical…

Chemical Physics · Physics 2015-06-18 Martin A. Mosquera , Adam Wasserman

We present a first-principles approach to electronic many-body systems strongly coupled to cavity modes in terms of matter-photon one-body reduced density matrices. The theory is fundamentally non-perturbative and thus captures not only the…

In order to extend the density-matrix renormalization-group (DMRG) method to two-dimensional systems, we formulate two alternative methods to prepare the initial states. We find that the number of states that is needed for accurate energy…

Condensed Matter · Physics 2007-05-23 Shoudan Liang , Hanbin Pang

The correlation energy in density functional theory can be expressed exactly in terms of the change in the probability of finding two electrons at a given distance $r_{12}$ (intracule density) when the electron-electron interaction is…

Other Condensed Matter · Physics 2017-08-23 Paola Gori-Giorgi , Michael Seidl , Andreas Savin

Kohn-Sham spin-density functional theory provides an efficient and accurate model to study electron-electron interaction effects in quantum dots, but its application to large systems is a challenge. An efficient algorithm for the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Hong Jiang , Harold U. Baranger , Weitao Yang

The non-relativistic interacting electron gas in an external field of positively charged massive cores is dealt with in the scheme of second quantization. Ladder operators that change between stationary states of contiguous energy…

Quantum Physics · Physics 2025-02-27 Miguel Lagos

We investigate the effects of randomness in a strongly correlated electron model in one-dimension at half-filling. The ground state correlation functions are exactly written by products of 3$\times$3 transfer matrices and are evaluated…

Strongly Correlated Electrons · Physics 2009-10-28 Masanori Yamanaka , Mahito Kohmoto

We present an extension of reverse engineered Kohn-Sham potentials from a density matrix renormalization group calculation towards the construction of a density functional theory functional via deep learning. Instead of applying machine…

Disordered Systems and Neural Networks · Physics 2021-05-05 Peter Schmitteckert

We have devised and implemented a local ab initio Density Matrix Renormalization Group (DMRG) algorithm to describe multireference nondynamic correlations in large systems. For long molecules that are extended in one of their spatial…

Strongly Correlated Electrons · Physics 2009-11-11 Johannes Hachmann , Wim Cardoen , Garnet Kin-Lic Chan

The density matrix renormalization group (DMRG) method allows an efficient computation of the properties of interacting 1D quantum systems. Two-dimensional (2D) systems, capable of displaying much richer quantum behavior, generally lie…

Strongly Correlated Electrons · Physics 2014-08-06 Samuel Moukouri , Eytan Grosfeld

We introduce a numerical method of the adaptive time-dependent density-matrix renormalization-group to compute one-dimensional quantum spin systems with periodic boundary condition. We check our algorithm to study the dynamic correlation in…

Statistical Mechanics · Physics 2011-06-01 Jie Ren

We introduce a method that ensures efficient computation of one-dimensional quantum systems with long-range interactions across all temperatures. Our algorithm operates within a quasi-polynomial runtime for inverse temperatures up to…

Quantum Physics · Physics 2025-05-19 Rakesh Achutha , Donghoon Kim , Yusuke Kimura , Tomotaka Kuwahara

Path integral techniques for the density matrix of a one-dimensional statistical system near a boundary previously employed in black-hole physics are applied to providing a new interpretation of the density matrix renormalization group: its…

Statistical Mechanics · Physics 2008-11-26 Jose Gaite