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Built on a realistic multiband tight-binding model, mirror symmetry is used to map a calcium-intercalated bilayer graphene Hamiltonian into two independent single layer graphene-like Hamiltonians with renormalized hopping. The…

Superconductivity · Physics 2020-02-03 Rouhollah Gholami , Rostam Moradian , Sina Moradian , Warren E. Pickett

Graphene, a zero-gap semimetal, can be transformed into a metallic, semiconducting or insulating state by either physical or chemical modification. Superconductivity is conspicuously missing among these states despite considerable…

Superconductivity · Physics 2016-04-05 J. Chapman , Y. Su , C. A. Howard , D. Kundys , A. Grigorenko , F. Guinea , A. K. Geim , I. V. Grigorieva , R. R. Nair

We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-04-29 Valentin N. Popov , Philippe Lambin

The intercalated graphite superconductor CaC6 with Tc ~ 11.5 K has been synthesized and characterized with magnetoresistance measurements. Above the transition, the resistivity follows a T^2 dependence up to 50 K, which suggests Fermi…

Superconductivity · Physics 2007-05-23 E. Jobiliong , H. D. Zhou , J. A. Janik , Y. -J. Jo , L. Balicas , J. S. Brooks , C. R. Wiebe

We investigate the structural and electronic properties of Li-intercalated monolayer graphene on SiC(0001) using combined angle-resolved photoemission spectroscopy and first-principles density functional theory. Li intercalates at room…

We have investigated the atomic structure of superconducting Ca-intercalated bilayer graphene on a SiC(0001) substrate using total-reflection high-energy positron diffraction. By comparing the experimental rocking-curves with ones…

Materials Science · Physics 2019-11-20 Y. Endo , Y. Fukaya , I. Mochizuki , A. Takayama , T. Hyodo , S. Hasegawa

Using the continuum model, we investigate theoretically contribution of the low-energy electronic excitations to the Raman spectrum of superconducting monolayer graphene. We consider superconducting phases characterised by an isotropic…

Mesoscale and Nanoscale Physics · Physics 2018-04-11 Aitor García-Ruiz Fuentes , Marcin Mucha-Kruczynski , Vladimir Falko

Two-dimensional (2D) materials may exhibit intriguing band structure features (e.g., Dirac points), that lay far away from the Fermi level. They are, thus, not usable in applications. The semiconducting 2D material PC6 has two Dirac cones…

Materials Science · Physics 2021-10-01 Maximilian A. Springer , Thomas Brumme , Agnieszka Kuc , Thomas Heine

The deposition and intercalation of metal atoms can induce superconductivity in monolayer and bilayer graphenes. For example, it has been experimentally proved that Li-deposited graphene is a superconductor with critical temperature $T_{c}$…

Superconductivity · Physics 2024-05-07 Jin-Han Tan , Hao Wang , Ying-Jie Chen , Na Jiao , Meng-Meng Zheng , Hong-Yan Lu , Ping Zhang

The nature of the coupling leading to superconductivity in layered materials such as high-Tc superconductors and graphite intercalation compounds (GICs) is still unresolved. In both systems, interactions of electrons with either phonons or…

Strongly Correlated Electrons · Physics 2007-05-24 Jessica L. McChesney , Aaron Bostwick , Taisuke Ohta , Konstantin V. Emtsev , Thomas Seyller , Karsten Horn , Eli Rotenberg

We use anhydrous ferric chloride (FeCl3) to intercalate graphite flakes consisting of 2 to 4 graphene layers and to dope graphene monolayers. The intercalant, staging, stability and doping of the resulting intercalation compounds (ICs) are…

Materials Science · Physics 2011-06-07 W. J. Zhao , P. H. Tan , J. Liu , A. C. Ferrari

We present a theoretical investigation on electron-phonon superconductivity of honeycomb MX$_2$ layered structures. Where X is one element of the group-IV (C, Si or Ge) and M an alkali or an alkaline-earth metal. Among the studied…

Superconductivity · Physics 2015-06-23 José A. Flores-Livas , Antonio Sanna

There has been a long-standing debate about the mechanism of the unusual superconductivity in alkali-intercalated fulleride superconductors. In this work, using high-resolution angle-resolved photoemission spectroscopy, we systematically…

Two-dimensional (2D) materials, composed of single atomic layers, have attracted vast research interest since the breakthrough discovery of graphene. One major benefit of such systems is the simple ability to tune the chemical potential by…

Superconductivity · Physics 2020-10-01 Gopi Nath Daptary , Eyal Walach , Efrat Shimshoni , Aviad Frydman

We report the observation of superconductivity in rhombohedral trilayer graphene electrostatically doped with holes. Superconductivity occurs in two distinct regions within the space of gate-tuned charge carrier density and applied electric…

Mesoscale and Nanoscale Physics · Physics 2021-10-25 Haoxin Zhou , Tian Xie , Takashi Taniguchi , Kenji Watanabe , Andrea F. Young

We theoretically investigate the possibility of achieving a superconducting state in transition-metal dichalcogenide bilayers through intercalation, a process previously and widely used to achieve metallization and superconducting states in…

Superconductivity · Physics 2017-09-20 R. Szczesniak , A. P. Durajski , M. W. Jarosik

The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC6 and YbC6…

The 2D Fermi surface of 1st stage PdAl2Cl8 acceptor-type graphite intercalation compounds (GICs) has been investigated using the Shubnikov-de Haas (SdH) effect. One fundamental frequency is observed, the angular variation of which confirms…

Materials Science · Physics 2007-05-23 R. T. F. van Schaijk , A. de Visser , E. McRae , B. Sundqvist , T. Wagberg , R. Vangelisti

The state with a spontaneous interlayer phase coherence in a graphene based bilayer quantum Hall system is studied. This state can be considered as a gas of superfluid electron-hole pairs with the components of the pair belonging to…

Superconductivity · Physics 2009-12-23 D. V. Fil , L. Yu. Kravchenko

The effect of Mn intercalation on the atomic, electronic and magnetic structure of the graphene/Cu(111) interface is studied using state-of-the-art density functional theory calculations. Different structural models of the…

Materials Science · Physics 2021-12-23 Qilin Guo , Yuriy Dedkov , Elena Voloshina