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Scaling transformations involving a small parameter ({\em degenerate scalings}) are frequently used for ordinary differential equations that model (bio-) chemical reaction networks. They are motivated by quasi-steady state (QSS) of certain…

Dynamical Systems · Mathematics 2022-09-20 Christian Lax , Sebastian Walcher

The dynamics of a quantum system following a sudden, highly non-adiabatic change of its control parameter (quantum quench) is studied with quasiclassical techniques. Recent works have shown, using exact quantum mechanical approach, that…

Mathematical modeling of fluid dynamics for computer graphics requires high levels of theoretical rigor to ensure visually plausible and computationally efficient simulations. This paper presents an in-depth theoretical framework analyzing…

Fluid Dynamics · Physics 2024-11-05 Rômulo Damasclin Chaves dos Santos

The quasi-steady-state approximation (or stochastic averaging principle) is a useful tool in the study of multiscale stochastic systems, giving a practical method by which to reduce the number of degrees of freedom in a model. The method is…

Chemical Physics · Physics 2015-06-18 Maria Bruna , S. Jonathan Chapman , Matthew J. Smith

For a theoretical understanding of the reactivity of complex chemical systems, relative energies of stationary points on potential energy hypersurfaces need to be calculated to high accuracy. Due to the large number of intermediates present…

Chemical Physics · Physics 2018-10-30 Gregor N. Simm , Markus Reiher

The problem of how to obtain quasi-classical states for quantum groups is examined. A measure of quantum indeterminacy is proposed, which involves expectation values of some natural quantum group operators. It is shown that within any…

q-alg · Mathematics 2008-02-03 R. Delbourgo , R. B. Zhang

The quasi-static evolution of steady states far from equilibrium is investigated from the point of view of quantum statistical mechanics. As a concrete example of a thermodynamic system, a two-level quantum dot coupled to several reservoirs…

Mathematical Physics · Physics 2009-11-11 Walid K. Abou Salem

We present a novel approach to kinetic theory modeling enabling the simulation of a generic, real gas presented by its corresponding equation of state. The model is based on mass, momentum and energy conservation, and unlike the lattice…

Fluid Dynamics · Physics 2020-02-25 Ehsan Reyhanian , Benedikt Dorschner , Ilya Karlin

The standard two-step model of homogeneous-catalyzed reactions had been theoretically analyzed at various levels of approximations from time to time. The primary aim was to check the validity of the quasi-steady-state approximation, and…

Chemical Physics · Physics 2019-11-14 Kamal Bhattacharyya , Sharmistha Dhatt

The work analyzes the stability of the quantum eigenstates when they are submitted to fluctuations by using the stochastic generalization of the Madelung quantum hydrodynamic approach. In the limit of sufficiently slow kinetics, the quantum…

Quantum Physics · Physics 2020-12-01 Simone Chiarelli , Piero Chiarelli

The incompressible Navier-Stokes equations currently represent the primary model for describing stratified turbulent fluid flows at low Mach number. The validity of the incompressible assumption, however, has so far only been rigorously…

Fluid Dynamics · Physics 2007-11-20 Remi Tailleux

During the past decade a number of attempts to formulate a continuum description of complex states of matter have been proposed to circumvent more cumbersome many-body and simulation methods. Typically these have been quantum systems (e.g.,…

Fluid Dynamics · Physics 2020-04-22 James Dufty , Kai Luo , Jeffrey Wrighton

In this paper we consider the one dimensional quantum hydrodynamics (QHD) system, with a genuine hydrodynamic approach. The global existence of weak solutions with large data has been obtained in [2, 3], in several space dimensions, by…

Analysis of PDEs · Mathematics 2021-01-26 Paolo Antonelli , Pierangelo Marcati , Hao Zheng

Identifying transition states (TSs), the high-energy configurations that molecules pass through during chemical reactions, is essential for understanding and designing chemical processes. However, accurately and efficiently identifying…

Chemical Physics · Physics 2025-07-23 Samir Darouich , Vinh Tong , Tanja Bien , Johannes Kästner , Mathias Niepert

Quantum indistinguishability plays a crucial role in many low-energy physical phenomena, from quantum fluids to molecular spectroscopy. It is, however, typically ignored in most high temperature processes, particularly for ionic…

Chemical Physics · Physics 2018-09-20 Matthew P. A. Fisher , Leo Radzihovsky

The evolution of a passive scalar field is considered for a slowly varying stratified medium, which is convected in an incompressible sheared flow with many overlapping static flux islands. Within the quasilinear/random phase approximation,…

Plasma Physics · Physics 2019-12-03 Kurt S. Riedel

The notion of semi-classical states is first sharpened by clarifying two issues that appear to have been overlooked in the literature. Systems with linear and quadratic constraints are then considered and the group averaging procedure is…

General Relativity and Quantum Cosmology · Physics 2014-11-17 Abhay Ashtekar , Luca Bombelli , Alejandro Corichi

We describe a computational framework linking Uncertainty Quantification (UQ) methods for continuum problems depending on random parameters with Equation-Free (EF) methods for performing continuum deterministic numerics by acting directly…

Dynamical Systems · Mathematics 2007-05-23 Yu Zou , Ioannis G. Kevrekidis

I present time-dependent analytical solutions of quasi-steady shocks with cooling, where quasi-steady shocks are objects composed of truncated steady-state models of shocks at any intermediate time. I compare these solutions to simulations…

Astrophysics · Physics 2015-05-13 P. Lesaffre

Accurate simulations of molecules require high-level electronic-structure theory in combination with rigorous methods for approximating the quantum dynamics. Machine-learning approaches can significantly reduce the computational expense of…

Chemical Physics · Physics 2026-02-24 Valerii Andreichev , Jindra Dušek , Markus Meuwly , Jeremy O. Richardson