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In 1897 Ostwald formulated his step rule for formation of the most stable crystal state for a system with crystal polymorphism. The rule describes the irreversible way a system converts to the crystal with lowest free energy. But in fact…

Chemical Physics · Physics 2016-09-07 Søren Toxvaerd

We propose a simple, self-consistent kinetic model for the evolution of a mixture of droplets and vapor expanding adiabatically in vacuum after rapid, almost isochoric heating. We study the evolution of the two-phase fluid at intermediate…

Fluid Dynamics · Physics 2011-06-01 Julien Armijo , John J. Barnard

We carry out molecular dynamics (MD) and Monte Carlo (MC) simulations to characterize nucleation in liquid clusters of 600 Lennard-Jones particles over a broad range of temperatures. We use the formalism of mean first-passage times to…

Materials Science · Physics 2016-10-05 Shahrazad M. A. Malek , Gregory P. Morrow , Ivan Saika-Voivod

We present an investigation of chemical influences on the growth of ice crystals from water vapor. In one set of experiments, we grew ice crystals in a vapor diffusion chamber, observing crystal morphologies at temperatures from 0 C to -25…

Materials Science · Physics 2011-01-04 Kenneth G. Libbrecht , Robert Bell

Acoustic levitation is a container-free method for examining novel crystallization effects, though liquid-to-solid phase change has seen little investigation for levitated nanofluids. Recent developments have allowed for examining the…

Applied Physics · Physics 2024-09-13 Adam McElligott , André Guerra , Alejandro D. Rey , Phillip Servio

We use a stochastic model and direct numerical simulation to study the impact of turbulence on cloud droplet growth by condensation. We show that the variance of the droplet size distribution increases in time as t^{1/2}, with growth rate…

Fluid Dynamics · Physics 2015-10-06 Gaetano Sardina , Francesco Picano , Luca Brandt , Rodrigo Caballero

In this contribution, we compute the $^1$H nuclear magnetic resonance (NMR) relaxation rate of liquid water at ambient conditions. We are using structural and dynamical information from Coupled Cluster Molecular Dynamics (CCMD) trajectories…

The evaporation coefficients of water in air and nitrogen were found as a function of temperature, by studying the evaporation of pure water droplet. The droplet was levitated in an electrodynamic trap placed in a climatic chamber…

Chemical Physics · Physics 2016-09-28 M. Zientara , D. Jakubczyk , K. Kolwas , M. Kolwas

We report studies of solid helium contained inside a torsional oscillator, at temperatures between 1.07K and 1.87K. We grew single crystals inside the oscillator using commercially pure $^4$He and $^3$He-$^4$He mixtures containing 100 ppm…

Other Condensed Matter · Physics 2011-03-01 Anna Eyal , Emil Polturak

Results for the kinetics of vapor-liquid transitions, following temperature quenches with different densities, are presented from the molecular dynamics simulations of a Lennard-Jones system. For critical density, bicontinuous liquid and…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , Subir K. Das

We present measurements of the diffusion-limited growth of ice crystals from water vapor at different supersaturation levels in air at a temperature of -15 C. Starting with thin, c-axis ice needle crystals, the subsequent growth…

Materials Science · Physics 2015-12-14 Kenneth Libbrecht , Christopher Miller , Ryan Potter , Nina Budaeva , Cameron Lemon , Sarah Thomas

To predict the radiative forcing of clouds it is necessary to know the rate with which ice homogeneously nucleates in supercooled water. Such rate is often measured in drops to avoid the presence of impurities. At large supercooling small…

Soft Condensed Matter · Physics 2020-03-06 Jorge R. Espinosa , Carlos Vega , Eduardo Sanz

The method of formation of nanoparticle aggregates such as high-coverage spherical shells of microspheres or 3-D micro crystals grown in the geometry unaffected by a substrate is described. In the reported experiment, the evaporation of…

Soft Condensed Matter · Physics 2011-04-05 GGennadiy Derkachov , Krystyna Kolwas , Daniel Jakubczyk , Marcin Zientara , Maciej Kolwas

The "burst-like growth" regime is observed for the $^4$He crystals with the growth defects. The observation has confirmed the hypothesis for the same physical mechanisms responsible for the transition of the crystalline facets to the state…

Other Condensed Matter · Physics 2021-03-02 V. L. Tsymbalenko

Results from the state-of-the-art molecular dynamics simulations are presented for both equilibrium and nonequilibrium dynamics following vapor-liquid transition in a single component Lennard-Jones system. We have fixed the overall density…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , Subir K. Das

Drying of colloidal droplets on solid, rigid substrates is associated with a capillary pressure developing within the droplet. In due course of time, the capillary pressure builds up due to droplet evaporation resulting in the formation of…

Fluid Dynamics · Physics 2017-02-03 Udita Uday Ghosh , Jayabrata Dhar , Suman Chakraborty , Sunando DasGupta

Dynamics of the pendant drop coalescing with a sessile drop to form a single daughter droplet is known to form a bridge. The bridge evolution begins with a point contact between the two drops leading to a liquid neck of size comparable to…

Fluid Dynamics · Physics 2022-10-12 Sarath Chandra Varma , Abhineet Singh Rajput , Aloke Kumar

The phase separation mechanism of a binary liquid mixture off-critically quenched in its miscibility gap is nucleation and growth, its homogeneous phase reaching a metastable equilibrium state. The successive stages of growth of the…

Statistical Mechanics · Physics 2009-11-18 Jean Colombani , Jacques Bert

A systematic experimental study of dispersions of charged colloidal spheres is presented on the effect of steady shear flow on nucleation and crystal-growth rates. In addition, the non-equilibrium phase diagram as far as the melting line is…

Soft Condensed Matter · Physics 2016-08-31 P. Holmqvist , M. P. Lettinga , J. Buitenhuis , J. K. G. Dhont

Experiments and simulations are used to study the kinetics of crystal growth in a mixture of magnetic and nonmagnetic particles suspended in ferrofluid. The growth process is quantified using both a bond order parameter and a mean domain…

Soft Condensed Matter · Physics 2017-01-11 An T. Pham , Ryohei Seto , Johannes Schonke , Daniel Y. Joh , Ashutosh Chilkoti , Eliot Fried , Benjamin B. Yellen