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Trions are charged excitons that form upon optical or electrical excitation of low-dimensional semiconductors in the presence of charge carriers (holes or electrons). Trion emission from semiconducting single-walled carbon nanotubes…

Materials Science · Physics 2023-02-17 Sonja Wieland , Abdurrahman Ali El Yumin , Jan M. Gotthardt , Jana Zaumseil

We present a study of free carrier photo-generation and multi-carrier bound states, such as biexcitons and trions (ionized excitons), in semiconducting single-walled carbon nanotubes. Pump-and-probe measurements performed with fs pulses…

Photophysics of single-wall carbon nanotubes (SWCNTs) is intensively studied due to their potential application in light harvesting and optoelectronics. Excited states of SWCNTs form strongly bound electron-hole pairs, excitons, of which…

Mesoscale and Nanoscale Physics · Physics 2021-01-28 J. Palotas , M. Negyedi , S. Kollarics , A. Bojtor , P. Rohringer , Th. Pichler , F. Simon

Doping substantially influences the electronic and photophysical properties of semiconducting single-wall carbon nanotubes (s-SWNTs). Although prior studies have noted that surplus charge carriers modify optical spectra and accelerate…

Materials Science · Physics 2023-07-19 Klaus H. Eckstein , Pascal Kunkel , Markus Voelckel , Friedrich Schöppler , Tobias Hertel

We demonstrate exciton and charged exciton (trion) electroluminescence from frozen p-n junctions in networks of polymer-sorted, semiconducting (6,5) single-walled carbon nanotubes. Electrolyte-gating with an ionic liquid was employed to…

We observe trion emission from suspended carbon nanotubes where carriers are introduced electrostatically using field-effect transistor structures. The trion peak emerges below the $E_{11}$ emission energy at gate voltages that coincide…

Mesoscale and Nanoscale Physics · Physics 2016-01-13 M. Yoshida , A. Popert , Y. K. Kato

Theory predicts peculiar features for excited-state dynamics in one dimension (1D) that are difficult to be observed experimentally. Single-walled carbon nanotubes (SWNTs) are an excellent approximation to 1D quantum confinement, due to…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Giancarlo Soavi , Francesco Scotognella , Daniele Viola , Timo Hefner , Tobias Hertel , Giulio Cerullo , Guglielmo Lanzani

We report the first observation of trions (charged excitons), three-particle bound states consisting of one electron and two holes, in hole-doped carbon nanotubes at room temperature. When p-type dopants are added to carbon nanotube…

Mesoscale and Nanoscale Physics · Physics 2013-08-26 Ryusuke Matsunaga , Kazunari Matsuda , Yoshihiko Kanemitsu

Charged optical excitations (trions) generated by charge carrier injection are crucial for emerging optoelectronic technologies as they can be produced and manipulated by electric fields. Trions and neutral excitons can be efficiently…

Atomic and Molecular Clusters · Physics 2021-12-23 Jiří Doležal , Sofia Canola , Pablo Merino , Martin Švec

We report the first observation of an optical transition from a ground trion state T to excited trion state T* in (6,5) single-wall carbon nanotubes non-covalently doped with hydrochloric acid. The position of such an excited trion level T*…

Mesoscale and Nanoscale Physics · Physics 2018-05-07 T. V. Eremin , P. A. Obraztsov , V. A. Velikanov , T. V. Shubina , E. D. Obraztsova

We studied the excitation density dependence of photoluminescence (PL) spectra of excitons and trions (charged excitons) in hole-doped single-walled carbon nanotubes. We found that the PL intensity of trions exhibited a strong nonlinear…

Single walled carbon nanotubes as emerging quantum-light sources may fill a technological gap in silicon photonics due to their potential use as near infrared, electrically driven, classical or non-classical emitters. Unlike in…

The recent development of efficient chirality sorting techniques has opened the way to the use of single-walled carbon nanotubes (SWCNTs) in a plethora of nanoelectronic, photovoltaic, and optoelectronic applications. However, to understand…

Mesoscale and Nanoscale Physics · Physics 2019-12-25 María Rosa Preciado-Rivas , Victor Alexander Torres-Sánchez , Duncan J. Mowbray

Semiconducting single-wall carbon nanotubes (SWCNTs) are a promising material platform for near-infrared in-vivo imaging, optical sensing, and single-photon emission at telecommunication wavelengths. The functionalization of SWCNTs with…

Materials Science · Physics 2024-11-20 Finn L. Sebastian , Simon Settele , Han Li , Benjamin S. Flavel , Jana Zaumseil

We studied the nonlinear time-resolved luminescence signals due to multiexciton recombination processes in single-walled carbon nanotubes (SWNTs) using femtosecond excitation correlation (FEC) spectroscopy. From theoretical analysis of the…

Materials Science · Physics 2015-05-13 Yuhei Miyauchi , Kazunari Matsuda , Yoshihiko Kanemitsu

Semiconducting single-walled carbon-nanotubes (SWCNTs) are an interesting material for strong-light matter coupling due to their stable excitons, narrow emission in the near infrared and high charge carrier mobilities. Furthermore, they…

Materials Science · Physics 2021-03-17 Jan M. Lüttgens , Felix J. Berger , Jana Zaumseil

We report on single-wall carbon nanotube (SWCNT) specific $^{13}$C isotope enrichment. The high temperature annealing of isotope enriched fullerenes encapsulated in SWCNTs yields double-wall carbon nanotubes (DWCNTs) with a high isotope…

Materials Science · Physics 2007-05-23 F. Simon , Ch. Kramberger , R. Pfeiffer , H. Kuzmany , V. Zolyomi , J. Kurti , P. M. Singer , H. Alloul

The intrinsic near-infrared photoluminescence observed in long single walled carbon nanotubes is systematically quenched in ultrashort single-walled carbon nanotubes (usCNTs, below 100 nm length) due to their short dimension as compared to…

The functionalization of single-walled carbon nanotubes (SWCNTs) with luminescent sp$^{3}$ defects has greatly improved their performance in applications such as quantum light sources and bioimaging. Here, we report the covalent…

Single-walled carbon nanotubes (SWCNTs) are quasi-one-dimensional systems with poor Coulomb screening and enhanced electron-phonon interaction, and are good candidates for excitons and exciton-phonon couplings in metallic state. Here we…

Materials Science · Physics 2009-04-20 Hualing Zeng , Hongbo Zhao , Fu-Chun Zhang , Xiaodong Cui
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