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Including on-site electronic interactions described by the multi-orbital Hubbard model we study the correlation effects in the electronic structure of bulk palladium. We use a combined density functional and dynamical mean field theory,…

Strongly Correlated Electrons · Physics 2016-05-04 A. Östlin , W. H. Appelt , I. Di Marco , W. Sun , M. Radonjic , M. Sekania , L. Vitos , O. Tjernberg , L. Chioncel

By using a relativistic linear augmented-plane-wave method, we clarify energy band structure and the Fermi surfaces of recently synthesized thorium compound ThRhIn$_5$. We find several cylindrical Fermi surface sheets, which are similar to…

Strongly Correlated Electrons · Physics 2009-11-11 Takahiro Maehira , Takashi Hotta

We present measurements of the thermoelectric power of the plutonium-based unconventional superconductor PuCoGa$_{5}$. The data is interpreted within a phenomenological model for the quasiparticle density of states of intermediate valence…

Strongly Correlated Electrons · Physics 2016-11-10 K. Gofryk , J-C. Griveau , P. S. Riseborough , T. Durakiewicz

We report the electronic structure of monoclinic CuO as obtained from first principles calculations utilizing density functional theory plus effective Coulomb interaction (DFT + U) method. In contrast to standard DFT calculations taking…

Strongly Correlated Electrons · Physics 2014-02-19 C. E. Ekuma , V. I. Anisimov , J. Moreno , M. Jarrell

Since the recent discovery of plutonium-based superconductors such as PuCoIn$_{\rm 5}$, systematic studies of the electronic properties for plutonium compounds are providing insight into the itinerancy-localization crossover of Pu 5$f$…

Strongly Correlated Electrons · Physics 2015-06-15 C. -C. Joseph Wang , M. D. Jones , Jian-Xin Zhu

First principles linear combinations of Gaussian type orbitals-fitting function (LCGTO-FF) electronic structure calculations are used to study thickness dependencies in the surface energies and work functions of ultra-thin (111) films of…

Strongly Correlated Electrons · Physics 2009-11-10 A. K. Ray , J. C. Boettger

We present a theoretical model of the electronic structure of delta-Pu that is consistent with many of the electronic structure related properties of this complex metal. In particular we show that the theory is capable of reproducing the…

Strongly Correlated Electrons · Physics 2007-05-23 J. M. Wills , O. Eriksson , A. Delin , P. H. Andersson , J. J. Joyce , T. Durakiewicz , M. T. Butterfield , L. A. Morales , D. P. Moore , A. J. Arko

We have investigated the low-energy electronic structure of the heavy fermion superconductor CeCoIn5 by angle-resolved photoemission and band structure calculations. We measured the Fermi surface and energy distribution maps along the…

Originating from a broken spatial inversion symmetry, ferroelectricity is a functionality of materials with an electric dipole that can be switched by external electric fields. Spontaneous polarization is a crucial ferroelectric property,…

Materials Science · Physics 2017-08-03 Yubo Zhang , Jianwei Sun , John P. Perdew , Xifan Wu

The electronic structure and properties of PuO$_{2}$ and Pu$_{2}$O$_{3}$ have been studied from first principles by the all-electron projector-augmented-wave (PAW) method. The local density approximation (LDA)+$U$ and the generalized…

Materials Science · Physics 2007-12-24 Bo Sun , Ping Zhang , Xian-Geng Zhao

PuCoGa5 has attracted significant attention due to its record-breaking superconducting transition temperature Tc=18.5 K among known f-electron superconductors. Here we systematically investigated the evolution of correlated electronic…

Strongly Correlated Electrons · Physics 2024-11-20 Li Huang , Haiyan Lu

Electronic structure calculations combining the local-density approximation with an exact diagonalization of the Anderson impurity model show an intermediate 5f^5-5f^6-valence ground state and delocalization of the 5f^5 multiplet of the Pu…

Strongly Correlated Electrons · Physics 2015-06-12 A. B. Shick , J. Kolorenc , J. Rusz , P. M. Oppeneer , A. I. Lichtenstein , M. I. Katsnelson , R. Caciuffo

In this work using the density functional theory (DFT), we have studied the structural, electronic and magnetic properties of uranium dioxide with antiferromagnetic 1k-, 2k-, and 3k-order structures. Ordinary approximations in DFT, such as…

Materials Science · Physics 2020-08-25 Samira Sheykhi , Mahmoud Payami

Electronic correlations associated with incipient magnetism have long been recognized as an important factor in stabilizing the largest atomic volume $\delta$ phase of plutonium, yet their strength compared to those in the rare earths and…

Strongly Correlated Electrons · Physics 2022-01-10 M. Wartenbe , P. H. Tobash , J. Singleton , L. E. Winter , S. Richmond , N. Harrison

The local-density approximation combined with the dynamical mean-field theory (LDA+DMFT) is applied to the paramagnetic phase of light actinide dioxides: UO2, NpO2, and PuO2. The calculated band gaps and the valence-band electronic…

Strongly Correlated Electrons · Physics 2015-08-25 Jindrich Kolorenc , Alexander B. Shick , Alexander I. Lichtenstein

The calculation of electronic properties of materials is an important task of solid state theory, albeit particularly difficult if electronic correlations are strong, for example in transition metals, their oxides and in f-electron systems.…

Strongly Correlated Electrons · Physics 2009-09-29 K. Held

The electronic structure of Samarium (Sm) was calculated using the density functional theory combined with the single-site dynamical mean-field theory. In this work, we investigated the electronic properties of {\alpha}, \b{eta} and…

Strongly Correlated Electrons · Physics 2026-05-15 Shengsong Xu , Zhenfeng Ouyang , Li Huang , Zhong-Yi Lu

PuCoGa$_5$ has emerged as a prototypical heavy-fermion superconductor, with its transition temperature ($T_c\simeq18.5$ K) being the highest amongst such materials. Nonetheless, a clear description as to what drives the superconducting…

Strongly Correlated Electrons · Physics 2016-11-15 G. Koutroulakis , H. Yasuoka , P. H. Tobash , J. N. Mitchell , E. D. Bauer , J. D. Thompson

The kagome metals $A$V$_3$Sb$_5$ ($A=$ K, Cs, Rb) have become a fascinating materials platform following the discovery of many novel quantum states due to the interplay between electronic correlation, topology, and geometry. Understanding…

Strongly Correlated Electrons · Physics 2025-10-28 Keyu Zeng , Zhan Wang , Kun Jiang , Ziqiang Wang

The journey of theoretical study on semiconductors is reviewed in a non-conventional way. We have started with the basic introduction of Hartree-Fock method and introduce the fundamentals of Density Functional Theory (DFT). From the oldest…

Materials Science · Physics 2021-05-04 Sujoy Datta , Debnarayan Jana