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The depletion interactions between two colloidal plates or between two colloidal spheres, induced by interacting polymers in a good solvent, are calculated theoretically and by computer simulations. A simple analytical theory is shown to be…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , P. G. Bolhuis , E. J. Meijer , J. P. Hansen

Conjugated polymers are observed to aggregate in solution. To account for this observation we propose a inter-chain binding mechanism based on the intermolecular tunneling of the delocalized $\pi$-electrons occurring at points where the…

Soft Condensed Matter · Physics 2013-05-29 Jeremy D. Schmit , Alex J. Levine

When a rigid object approaches a soft material in a viscous fluid, hydrodynamic stresses arise in the lubricated contact region and deform the soft material. The elastic deformation modifies in turn the flow, hence generating a…

Materials Science · Physics 2023-03-29 Caroline Kopecz-Muller , Vincent Bertin , Elie Raphael , Joshua D Mcgraw , Thomas Salez

Interaction of particles of many systems can be effectively approximated by multiscale interaction potentials. Such potentials are widely used for investigation of colloidal systems and colloid-polymer mixtures, complex liquids (for…

Soft Condensed Matter · Physics 2019-02-13 Yu. D. Fomin , V. N. Ryzhov , E. N. Tsiok

We present a detailed numerical study of effective interactions between micron-sized silica spheres, induced by highly charged zirconia nanoparticles. It is demonstrated that the effective interactions are consistent with a recently…

Soft Condensed Matter · Physics 2016-08-31 Jiwen Liu , Erik Luijten

Understanding multibody interactions between colloidal particles out of equilibrium has a profound impact on dynamical processes such as colloidal self assembly. However, traditional colloidal interactions are effectively quasi-static on…

Soft Condensed Matter · Physics 2023-03-17 Yaxin Xu , Kyu Hwan Choi , Sachit G. Nagella , Sho C. Takatori

Charged colloidal monolayers at the interface between water and air (or oil) are used in a large number of chemical, physical and biological applications. Although a considerable experimental and theoretical effort has been devoted in the…

Soft Condensed Matter · Physics 2018-12-03 Aviv Karnieli , Tomer Markovich , David Andelman

Softer means stickier for solid adhesives, because material compliance facilitates close contact between non-conformal surfaces. Recent discoveries have revealed that soft materials can exhibit a rich array of new physics arising from…

Using experiments, theory and simulations, we show that the arrested state observed in a colloidal clay at intermediate concentrations is stabilized by the screened Coulomb repulsion (Wigner glass). Dilution experiments allow us to…

Soft Condensed Matter · Physics 2015-05-18 B. Ruzicka , L. Zulian , E. Zaccarelli , R. Angelini , M. Sztucki , A. Moussaid , G. Ruocco

Using a minimal model based on the continuum theory of a 2D hard-core/square-shoulder ensemble, we reinterpret the main features of cluster mesophases formed by colloids with soft concave repulsive interactions. We rederive the lattice…

Soft Condensed Matter · Physics 2011-06-06 P. Ziherl , Randall D. Kamien

We present single contact friction experiments between a glassy polymer and smooth silica substrates grafted with alkylsilane layers of different coverage densities and morphologies. This allows us to adjust the polymer/substrate…

Soft Condensed Matter · Physics 2007-05-23 Lionel Bureau , Christiane Caroli , Tristan Baumberger

We consider the surface pressure of a colloid-laden liquid interface. As micron-sized particles of suitable wettability can be irreversibly bound to the liquid interface on experimental timescales, we use the canonical ensemble to derive an…

Soft Condensed Matter · Physics 2022-03-07 R. Mears , I. Muntz , J. H. J. Thijssen

We investigate the non-equilibrium fluid structure mediated forces between two colloids driven through a suspension of mutually non-interacting Brownian particles as well as between a colloid and a wall in stationary situations. We solve…

Soft Condensed Matter · Physics 2009-11-13 Matthias Krüger , Markus Rauscher

Performing light scattering experiments we show that introducing short-ranged attraction to a colloidal suspension of nearly hard spheres by addition of free polymer produces new glass transition phenomena. We observe a dramatic…

Soft Condensed Matter · Physics 2009-11-07 Thomas Eckert , Eckhard Bartsch

We consider a system of spherical colloidal particles with a size polydispersity and use a simple van der Waals description in order to study the combined effect of both the polydispersity and the spatial non-uniformity induced by a planar…

Statistical Mechanics · Physics 2009-11-07 L. Bellier-Castella , H. Xu , M. Baus

We present some recent theory and simulation results addressing the phenomena of colloidal gelation at both high and low volume fractions, in the presence of short-range attractive interactions. We discuss the ability of mode-coupling…

Soft Condensed Matter · Physics 2009-11-10 M. E. Cates , M. Fuchs , K. Kroy , W. C. K. Poon , A. M. Puertas

When a liquid film of colloidal solution consisting of particles of different sizes is dried on a substrate, the colloids often stratify, where smaller colloids are laid upon larger colloids. This phenomenon is counter intuitive because…

Soft Condensed Matter · Physics 2017-03-20 Jiajia Zhou , Ying Jiang , Masao Doi

Colloidal particles trapped at an interface between two fluids can form a wide range of different structures. Replacing one of the fluid with a liquid crystal increases the complexity of interactions and results in a greater range of…

Soft Condensed Matter · Physics 2014-03-20 Anne Claire Pawsey , Juho Lintuvuori

Motivated by recent experiments on colloidal systems with competing attractive and repulsive interactions, we simulate a two-dimensional system of colloids with competing interactions that can undergo fragmentation. In the absence of any…

Soft Condensed Matter · Physics 2008-11-26 C. J. Olson Reichhardt , C. Reichhardt , A. R. Bishop

Using computer simulations, we identify the mechanisms causing aggregation and structural arrest of colloidal suspensions interacting with a short-ranged attraction at moderate and high densities. Two different non-ergodicity transitions…

Condensed Matter · Physics 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates