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In the dynamics of atoms and molecules at metal surfaces, electron-hole pair excitations can play a crucial role. In the case of hyperthermal hydrogen atom scattering, they lead to nonadiabatic energy loss and highly inelastic scattering.…

Materials Science · Physics 2024-12-02 Connor L. Box , Nils Hertl , Wojciech G. Stark , Reinhard J. Maurer

First-principles molecular dynamics simulations based on density-functional theory and the projector augmented wave (PAW) technique have been used to study the structural and dynamical properties of liquid iron under Earth's core…

Condensed Matter · Physics 2009-10-31 D. Alfe` , G. Kresse , M. J. Gillan

We compare the observed peaked iron abundance profiles for a small sample of groups and clusters with the predictions of a simple model involving the metal ejection from the brightest galaxy and the subsequent diffusion of metals by…

Astrophysics · Physics 2009-11-11 P. Rebusco , E. Churazov , H. Boehringer , W. Forman

In this work we study the diffusion mechanisms in lithium disilicate melt using molecular dynamics simulation, which has an edge over other simulation methods because it can track down actual atomic rearrangements in materials once a…

Materials Science · Physics 2014-05-30 Luis G. V. Gonçalves , José P. Rino

Long-timescale simulations of the diffusion of a H$_2$O admolecule on the (0001) basal plane of ice Ih were carried out over a temperature range of 100 to 200 K using the adaptive kinetic Monte Carlo method and TIP4P/2005f interaction…

Computational Physics · Physics 2015-08-04 Andreas Pedersen , Leendertjan Karssemeijer , Herma M. Cuppen , Hannes Jónsson

The metallic regime of the hydrogen plasma is studied by ab initio Molecular Dynamics simulations, for classical protons and fully degenerate electrons, in the strong coupling regime of the protons. The breakdown of linear screening…

mtrl-th · Physics 2009-10-30 Jorge Kohanoff , Jean-Pierre Hansen

The preference of water self-ions (hydronium and hydroxide) towards air/oil-water interfaces is one of the hottest topics in water research due to its importance for understanding properties, phenomena, and reactions of interfaces. In this…

Chemical Physics · Physics 2025-02-04 Pengchao Zhang , Xuefei Xu

The behavior of hydrogen in iron and iron alloys is of interest in many fields of physics and materials science. To enable large-scale molecular dynamics simulations of systems with Fe-H interactions, we develop, based on density-functional…

Materials Science · Physics 2016-04-12 Pekko Kuopanportti , Erin Hayward , Chu-Chun Fu , Antti Kuronen , Kai Nordlund

The analytical solutions of the equations describing impurity diffusion due to migration of nonequilibrium impurity interstitials were obtained for the impurity redistribution during ion implantation at elevated temperatures and for…

Materials Science · Physics 2008-02-24 O. I. Velichko , N. A. Sobolevskaya

Deep saline aquifers are one of the best options for large-scale and long-term hydrogen storage. Predicting the diffusion coefficient of hydrogen molecules at the conditions of saline aquifers is critical for modelling hydrogen storage. The…

The diffusion of atoms and radicals on interstellar dust grains is a fundamental ingredient for predicting accurate molecular abundances in astronomical environments. Quantitative values of diffusivity and diffusion barriers usually rely…

Astrophysics of Galaxies · Physics 2021-12-22 Viktor Zaverkin , Germán Molpeceres , Johannes Kästner

The model of hydrogen migration and of the reactions of hydrogen atoms with electrically active impurity, developed earlier, has been applied to simulate hydrogen diffusion and passivation process during plasma deuteration of silicon…

Materials Science · Physics 2015-06-12 O. I. Velichko , Yu. P. Shaman , A. P. Kovaliova

The temperature-dependent diffusion coefficients of interstitial helium atom in $\alpha$-Ti are predicted using the transition state theory. The microscopic parameters in the pre-factor and activation energy of the impurity diffusion…

Materials Science · Physics 2015-06-16 Yong Lu , Fawei Zheng , Ping Zhang

We study the distribution of hydrogen and various hydride configurations in realistic models of a-Si:H for two different concentration generated via experimentally constrained molecular relaxation approach (ECMR) [1]. The microstructure…

Materials Science · Physics 2015-05-14 Rajendra Timilsina , Parthapratim Biswas

The solvation of Al and its hydrolyzed species in water clusters has been studied by means of ab initio molecular dynamics simulations. The hexa-hydrate aluminum ion formed a stable complex in the finite temperature cluster simulation of…

Soft Condensed Matter · Physics 2009-10-31 M. I. Lubin , J. H. Bylaska , J. H. Weare

Hydrogen intercalation in solids is common, complicated, and very difficult to monitor. In a new approach to the problem, we have studied the profile of hydrogen diffusion in single-crystal nanobeams and plates of VO2, exploiting the fact…

Strongly Correlated Electrons · Physics 2016-08-24 T. Serkan Kasırga , Jim M. Coy , Jae H. Park , David H. Cobden

Inelastic neutron scattering was performed for an iron-based superconductor LaFeAsO0.9D0.1, where most of D (deuterium) replaces oxygen, while a tiny amount goes into interstitial sites. By first-principle calculation, we characterize the…

The calculated effects of interstitial hydrogen on the elastic properties of alpha-iron from our earlier work are used to describe the H interactions with homogeneous strain fields using ab initio methods. In particular we calculate the H…

Materials Science · Physics 2012-03-06 D. Psiachos

The kinetics of hydrogen diffusion in C15 cubic and C14 hexagonal TiCr$_2$H$_x$ (0 < $x$ <= 4) Laves-phase hydrogen storage alloys is investigated with density functional theory (DFT) and machine learning interatomic potentials (MLIPs).…

Materials Science · Physics 2026-02-26 Pranav Kumar , Fritz Körmann , Kaveh Edalati , Blazej Grabowski , Yuji Ikeda

This paper presents an $ab$ $initio$ study of hydrogen dynamics inside nanometer-size voids in $a$-Si within the framework of the density-functional theory for a varying hydrogen load of 10 to 30 H atoms/void at the low and high temperature…

Materials Science · Physics 2021-10-04 Parthapratim Biswas , Dil Limbu