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One possible way to produce ultracold, high-phase-space-density quantum gases of molecules in the rovibronic ground state is given by molecule association from quantum-degenerate atomic gases on a Feshbach resonance and subsequent coherent…

One possibility for the creation of ultracold, high-phase-space-density quantum gases of molecules in the rovibrational ground state relies on first associating weakly-bound molecules from quantum-degenerate atomic gases on a Feshbach…

We present a study of two-photon pathways for the transfer of NaCs molecules to their rovibrational ground state. Starting from NaCs Feshbach molecules, we perform bound-bound excited state spectroscopy in the wavelength range from 900~nm…

We report a detailed molecular spectroscopy study on the lowest excited electronic states of $^{23}\rm{Na}^{87}\rm{Rb}$ for producing ultracold $^{23}\rm{Na}^{87}\rm{Rb}$ molecules in the electronic, rovibrational and hyperfine ground…

Quantum Gases · Physics 2017-11-22 Mingyang Guo , Romain Vexiau , Bing Zhu , Bo Lu , Nadia Bouloufa-Maafa , Olivier Dulieu , Dajun Wang

We have studied interspecies scattering in an ultracold mixture of $^{87}$Rb and $^{133}$Cs atoms, both in their lowest-energy spin states. The three-body loss signatures of 30 incoming s- and p-wave magnetic Feshbach resonances over the…

We create an ultracold dense quantum gas of ground state molecules bound by more than 1000 wavenumbers by stimulated two-photon transfer of molecules associated on a Feshbach resonance from a Bose-Einstein condensate of cesium atoms. The…

We report the creation of ultracold samples of $^{39}$K$^{133}$Cs molecules in their rovibrational ground state. By investigating potentially suitable excited states using one- and two-photon spectroscopy, we have identified a pathway to…

We report on high-resolution spectroscopy of ultracold fermionic \nak~Feshbach molecules, and identify a two-photon pathway to the rovibrational singlet ground state via a resonantly mixed \Bcres intermediate state. Photoassociation in a…

Quantum Gases · Physics 2015-08-28 Jee Woo Park , Sebastian A. Will , Martin W. Zwierlein

We spectroscopically investigate a pathway for the conversion of $^{23}\textrm{Na}^{39}\textrm{K}$ Feshbach molecules into rovibronic ground state molecules via STImulated Raman Adiabatic Passage (STIRAP). Using photoassociation…

Using resonance-enhanced two-photon ionization, we detect ultracold, ground-state RbCs molecules formed via photoassociation in a laser-cooled mixture of 85Rb and 133Cs atoms. We obtain extensive bound-bound excitation spectra of these…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , Thomas Bergeman , David DeMille

We report the production of ultracold RbCs molecules in the rovibronic ground state, i.e., $X^1\Sigma^+ (v=0, J=0)$, by short-range photoassociation to the $2^3\Pi_{0}$ state followed by spontaneous emission. We use narrowband depletion…

Atomic Physics · Physics 2015-06-22 Toshihiko Shimasaki , Michael Bellos , C. D. Bruzewicz , Zack Lasner , David DeMille

Two-color photoassociation of ground state $^6$Li$^{87}$Rb molecules via the $\mathrm{B}^1\Pi$ electronic state using short pulses near a magnetic Feshbach resonance is studied theoretically. A near-resonant magnetic field is applied to mix…

Atomic Physics · Physics 2014-02-04 Marko Gacesa , Subhas Ghosal , Jason Byrd , Robin Côté

We produce an ultracold and dense sample of rovibronic ground state Cs_2 molecules close to the regime of quantum degeneracy, in a single hyperfine level, in the presence of an optical lattice. The molecules are individually trapped, in the…

Control over all internal and external degrees of freedom of molecules at the level of single quantum states will enable a series of fundamental studies in physics and chemistry. In particular, samples of ground-state molecules at ultralow…

We report on the direct conversion of laser-cooled 41K and 87Rb atoms into ultracold 41K87Rb molecules in the rovibrational ground state via photoassociation followed by stimulated Raman adiabatic passage. High-resolution spectroscopy based…

Atomic Physics · Physics 2015-05-19 K. Aikawa , D. Akamatsu , M. Hayashi , K. Oasa , J. Kobayashi , P. Naidon , T. Kishimoto , M. Ueda , S. Inouye

We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by…

We produce ultracold dense trapped samples of 87Rb133Cs molecules in their rovibrational ground state, with full nuclear hyperfine state control, by stimulated Raman adiabatic passage (STIRAP) with efficiencies of 90%. We observe the onset…

We demonstrate the coherent creation of a single NaCs molecule in its rotational, vibrational, and electronic (rovibronic) ground state in an optical tweezer. Starting with a weakly bound Feshbach molecule, we locate a two-photon transition…

We examine dark quantum superposition states of weakly bound Rb2 Feshbach molecules and tightly bound triplet Rb2 molecules in the rovibrational ground state, created by subjecting a pure sample of Feshbach molecules in an optical lattice…

We explore possible pathways for the creation of ultracold polar NaK molecules in their absolute electronic and rovibrational ground state starting from ultracold Feshbach molecules. In particular, we present a multi-channel analysis of the…

Atomic Physics · Physics 2017-09-14 T. A. Schulze , I. I. Temelkov , M. W. Gempel , T. Hartmann , H. Knöckel , S. Ospelkaus , E. Tiemann
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