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The k.p perturbation method for determination of electronic structure first pioneered by Kohn and Luttinger continues to provide valuable insight to several band structure features. This method has been adopted to heterostructures confined…

Mesoscale and Nanoscale Physics · Physics 2019-08-17 Parijat Sengupta , Hoon Ryu , Sunhee Lee , Yaohua Tan , Gerhard Klimeck

We explore the principles of many-body Hamiltonian complexity reduction via downfolding on an effective low-dimensional representation. We present a unique measure of fidelity between the effective (reduced-rank) description and the full…

Computational Physics · Physics 2024-11-26 Annabelle Canestraight , Zhen Huang , Vojtech Vlcek

For large scale electronic structure calculation, the Krylov subspace method is introduced to calculate the one-body density matrix instead of the eigenstates of given Hamiltonian. This method provides an efficient way to extract the…

Materials Science · Physics 2009-11-10 Ryu Takayama , Takeo Hoshi , Takeo Fujiwara

Recent advances in laser technology enable to follow electronic motion at its natural time-scale with ultrafast pulses, leading the way towards atto- and femtosecond spectroscopic experiments of unprecedented resolution. Understanding of…

Chemical Physics · Physics 2023-07-12 Marius Kadek , Lukas Konecny , Michal Repisky

Localized interface states in abrupt semiconductor heterojunctions are studied within a tight-binding model. The intention is to provide a microscopic foundation for the results of similar studies which were based upon the two-band model…

Materials Science · Physics 2009-11-07 A. V. Kolesnikov , R. Lipperheide , U. Wille

We present a matrix-product-state-based numerical approach for simulating systems composed of several qubits and a common one-dimensional waveguide. In the presented approach, the one-dimensional waveguide is modeled in real space. Thus,…

Quantum Physics · Physics 2026-01-22 Shimpei Goto

Embedding calculations that find approximate solutions to the Schr\"{o}dinger equation for large molecules and realistic solids are performed commonly in a three step procedure involving (i) construction of a model system with effective…

Strongly Correlated Electrons · Physics 2016-11-15 Alexander A. Rusakov , Jordan J. Phillips , Dominika Zgid

We present a new approach to compute low lying eigenvalues and corresponding eigenvectors for strongly correlated many-body systems. The method was inspired by the so-called Automated Multilevel Sub-structuring Method (AMLS). Originally, it…

Computational Physics · Physics 2010-04-28 Ralf Gamillscheg , Gundolf Haase , Wolfgang von der Linden

We present an approach to accelerate real-space electronic structure methods several fold, without loss of accuracy, by reducing the dimension of the discrete eigenproblem that must be solved. To accomplish this, we construct an efficient,…

Computational Physics · Physics 2018-05-01 Qimen Xu , Phanish Suryanarayana , John E. Pask

We present a scheme to controllably improve the accuracy of tight-binding Hamiltonian matrices derived by projecting the solutions of plane-wave ab initio calculations on atomic orbital basis sets. By systematically increasing the…

With the advent of near-term quantum computers, the simulation of properties of solids using quantum algorithms becomes possible. By an adequate description of the system's Hamiltonian, variational methods enable to fetch the band structure…

Quantum Physics · Physics 2023-03-07 Raphael César de Souza Pimenta , Anibal Thiago Bezerra

Non-hermiticity presents a vast newly opened territory that harbors new physics and applications such as lasing and sensing. However, only non-Hermitian systems with real eigenenergies are stable, and great efforts have been devoted in…

Other Condensed Matter · Physics 2022-10-25 Russell Yang , Jun Wei Tan , Tommy Tai , Jin Ming Koh , Linhu Li , Stefano Longhi , Ching Hua Lee

An approximate relativistic two-component Hamiltonian for use in molecular electronic structure calculations is derived in the form of a sum of fixed atom-centered kinetic and spin-orbit operators added to the non-relativistic Hamiltonian.…

Chemical Physics · Physics 2019-02-13 Dimitri N. Laikov

We present a method for the calculation of electronic structure of systems that contain tens of thousands of atoms. The method is based on the division of the system into mutually overlapping fragments and the representation of the…

Materials Science · Physics 2011-03-09 Nenad Vukmirović , Lin-Wang Wang

The use of near-term quantum devices that lack quantum error correction, for addressing quantum chemistry and physics problems, requires hybrid quantum-classical algorithms and techniques. Here we present a process for obtaining the…

Quantum Physics · Physics 2023-08-14 Pejman Jouzdani , Stefan Bringuier

Modeling low energy eigenstates of fermionic systems can provide insight into chemical reactions and material properties and is one of the most anticipated applications of quantum computing. We present three techniques for reducing the cost…

A new formalism to calculate electronic states of vacancies in diamond has been developed using many-body techniques.This model is based on prevoius molecular models but does not use configuration interaction and molecular orbital…

Materials Science · Physics 2007-05-23 Mehdi Heidari Saani , Mohammad Ali Vesaghi , Keivan Esfarjani

We describe a semidefinite relaxation method which finds lower bounds to the ground state energy of a quantum Hamiltonian subject to Hermitian linear constraints along with approximations of ground state expectation values. We show that…

Strongly Correlated Electrons · Physics 2026-05-29 Michael G. Scheer

Classical computation of electronic properties in large-scale materials remains challenging. Quantum computation has the potential to offer advantages in memory footprint and computational scaling. However, general and practical quantum…

Computational Physics · Physics 2025-10-14 Yiran Bai , Feng Xiong , Xueheng Kuang

The title material has a quasi-one-dimensional electronic structure and is of considerable interest because it has a metallic phase with properties different from a simple Fermi liquid, a poorly understood "insulating" phase, and a…

Strongly Correlated Electrons · Physics 2015-06-04 Jaime Merino , Ross H. McKenzie