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Infrared (IR) absorption spectra of individual polycyclic aromatic hydrocarbons (PAHs) containing methyl (-CH3), methylene (>CH2), or diamond-like *CH groups and IR spectra of mixtures of methylated and hydrogenated PAHs prepared by gas…

Complex organic molecules (COMs) are detected in many regions of the interstellar medium, including prestellar cores. However, their formation mechanisms in cold (~10 K) cores remain to this date poorly understood. The formyl radical HCO is…

Astrophysics of Galaxies · Physics 2016-03-23 A. Bacmann , E. García-García , A. Faure

The interstellar hydride hydroxyl (OH) is a potential tracer of CO-dark molecular gas. We present new absorption line observations of OH at 18-cm wavelength towards four continuum sources. We compare these to the [CII] line at 1.9 THz…

We perform a complete census of molecular ions with an abundance larger than 1e-10 in the protostellar shock L1157-B1 by means of an unbiased high-sensitivity survey obtained with the IRAM-30m and Herschel/HIFI. By means of an LVG radiative…

Astrophysics of Galaxies · Physics 2015-06-18 L. Podio , B. Lefloch , C. Ceccarelli , C. Codella , R. Bachiller

The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…

Astrophysics · Physics 2009-11-06 T. R. Geballe

Molecular hydrogen has an important role in the early stages of star formation as well as in the production of many other molecules that have been detected in the interstellar medium. In this review we show that it is now possible to study…

We report the second study from the FUSE survey of molecular hydrogen in translucent clouds, for the line of sight toward HD 110432. This star lies beyond the Coalsack dark nebula, and with E(B-V) = 0.40, and A_V = 1.32 this line of sight…

Complex organic molecules (COMs) in starless cores provide critical insights into the early stages of star formation and prebiotic chemistry. We present a chemical survey of 16 starless cores (including five prestellar cores) in the Orion A…

The interstellar medium (ISM) seems to have a significant surplus of oxygen which was dubbed as the "O crisis": independent of the adopted interstellar reference abundance, the total number of O atoms depleted from the gas phase far exceeds…

Astrophysics of Galaxies · Physics 2015-09-30 Shu Wang , Aigen Li , B. W. Jiang

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

Atomic carbon ([CI]) is a key species in the carbon chemistry of the interstellar medium (ISM). Using the Submillimeter Wave Astronomy Satellite (SWAS), we conducted a [CI]($^3$P$_1$--$^3$P$_0$) 492 GHz survey covering approximately 4…

We investigate the correlation between OH and H2 column densities in diffuse Galactic clouds, in order to identify potential molecular tracers of interstellar H2. For this, we analyse near-UV spectra extracted from the ESO/VLT archives…

Astrophysics of Galaxies · Physics 2023-06-09 Katherine Rawlins , Bhaswati Mookerjea

Many of the baryons in our Galaxy probably lie outside the well known disk and bulge components. Despite a wealth of evidence for the presence of some gas in galactic halos, including absorption line systems in the spectra of quasars, high…

Astrophysics of Galaxies · Physics 2017-04-10 Huanian Zhang , Dennis Zaritsky

C$_4$H and $c$-C$_3$H$_2$, as unsaturated hydrocarbon molecules, are important for forming large organic molecules in the interstellar medium. We present mapping observations of C$_4$H ($N$=9$-8$) lines, $c$-C$_3$H$_2$…

Astrophysics of Galaxies · Physics 2024-07-01 Yijia Liu , Junzhi Wang , Shu Liu , Ningyu Tang , Yan Gong , Yuqiang Li , Juan LI , Rui Luo , Yani Xu

We have searched for emission from the 557 GHz ortho-water line in the interstellar medium of six nearby starburst galaxies. We used the Odin satellite to observe the 1_10-1_01 transition of o-H2O in the galaxies NGC253, IC342, M82,…

Mon R2, at a distance of 830 pc, is the only ultracompact HII region (UC HII) where the photon-dominated region (PDR) between the ionized gas and the molecular cloud can be resolved with Herschel. HIFI observations of the abundant compounds…

Interstellar dust shows ubiquitous interstellar infrared spectrum (IR) due to polycyclic aromatic hydrocarbon (PAH). By our previous quantum chemistry calculation, it was suggested that a molecule group having hydrocarbon pentagon-hexagon…

Astrophysics of Galaxies · Physics 2017-07-24 Norio Ota

We detected the H2O 6.3 micron bands in more than 30 normal red giants stars from K5III to M8III as well as in some early M supergiants on the SWS spectra retrieved from the ISO Data Archive. This result, however, shows serious…

Astrophysics · Physics 2007-05-23 Takashi Tsuji

The chemical composition of the interstellar medium is determined by gas phase chemistry, assisted by grain surface reactions, and by shock chemistry. The aim of this study is to measure the abundance of the hydroxyl radical (OH) in diffuse…

Polycyclic aromatic hydrocarbon (PAH) molecules, as revealed by the distinctive set of emission bands at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 $\mu$m characteristic of their vibrational modes, are abundant and widespread throughout the…

Astrophysics of Galaxies · Physics 2020-03-25 Aigen Li