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The hydroxyl radical (OH) is found in various environments within the interstellar medium (ISM) of the Milky Way and external galaxies, mostly either in diffuse interstellar clouds or in the warm, dense environments of newly formed low-mass…

OH is an important molecule in the H2O chemistry and the cooling budget of star-forming regions. The goal of the Herschel key program `Water in Star-forming regions with Herschel' (WISH) is to study H2O and related species during…

Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…

OH is a key species in the water chemistry of star-forming regions, because its presence is tightly related to the formation and destruction of water. This paper presents OH observations from 23 low- and intermediate-mass young stellar…

There is a robust polyatomic chemistry in diffuse, partially-molecular interstellar gas that is readily accessible in absorption at radio/mm/sub-mm wavelengths. Accurate column densities are derived owing to the weak internal excitation, so…

Astrophysics of Galaxies · Physics 2023-02-15 Harvey Liszt , Maryvonne Gerin

Chemical diversity of the gas in low-mass protostellar cores is widely recognized. In order to explore its origin, a survey of chemical composition toward 36 Class 0/I protostars in the Perseus molecular cloud complex, which are selected in…

The most abundant interstellar molecule, molecular Hydrogen (H$_{2}$), is practically invisible in cold molecular clouds. Astronomers typically use carbon monoxide (CO) to trace the bulk distribution and mass of H$_{2}$ in our galaxy and…

Astrophysics of Galaxies · Physics 2023-11-23 Michael P. Busch

To date O2 has definitely been detected in only two sources, namely rho Oph A and Orion, reflecting the extremely low abundance of O2 in the interstellar medium. One of the sources in the HOP program is the +50 km/s Cloud in the Sgr A…

Astrophysics of Galaxies · Physics 2015-12-09 Aa. Sandqvist , B. Larsson , Å. Hjalmarson , P. Encrenaz , M. Gerin , P. F. Goldsmith , D. C. Lis , R. Liseau , L. Pagani , E. Roueff , S. Viti

Interstellar polycyclic aromatic hydrocarbon (PAHs) are an important component of the interstellar medium of galaxies, containing some 10 percent of the elemental carbon. Their vibrational emission dominates the mid-infrared spectra of…

Astrophysics of Galaxies · Physics 2026-03-06 A. G. G. M. Tielens

We present the first detection in space of O-protonated carbonyl sulfide (\ch{HOCS+}), in the midst of an ultradeep molecular line survey toward the G+0.693-0.027 molecular cloud. From the observation of all $K$$_a$ = 0 transitions ranging…

In the interstellar medium, formic acid (HCOOH) plays a significant role in the synthesis of the simplest amino acid, glycine (NH$_{2}$CH$_{2}$COOH). The presence of HCOOH suggests that oxygen-bearing molecules may be directly involved in…

Astrophysics of Galaxies · Physics 2026-02-11 Arijit Manna , Sabyasachi Pal , Sekhar Sinha , Sushanta Kumar Mondal

The astrochemistry of the HnO+ (n=1..3) ions is important as the main gas-phase formation route for water, and as tracer of the interstellar ionization rate by cosmic rays and other processes. While interstellar H3O+ has been known since…

Cosmology and Nongalactic Astrophysics · Physics 2010-11-03 Floris van der Tak

We report the first detection of the phosphorus monoxide ion (PO$^{+}$) in the interstellar medium. Our unbiased and very sensitive spectral survey towards the G+0.693$-$0.027 molecular cloud covers four different rotational transitions of…

Hydroxyl (OH) is expected to be abundant in diffuse interstellar molecular gas as it forms along with $H_2$ under similar conditions and within a similar extinction range. We have analyzed absorption measurements of OH at 1665 MHz and 1667…

The properties of the first-discovered interstellar object (ISO), 1I/2017 (`Oumuamua), differ from both Solar System asteroids and comets, casting doubt on a protoplanetary disk origin. In this study, we investigate the possibility that it…

Earth and Planetary Astrophysics · Physics 2021-05-05 W. Garrett Levine , Gregory Laughlin

Hydroxyl ($\rm OH$) is known to form efficiently in cold gas ($T\sim 100$K) along with the molecule $\rm H_2$ and can be used as an efficient tracer of the diffuse molecular gas in the interstellar medium (ISM). Using a simple formalism…

Astrophysics of Galaxies · Physics 2021-04-28 Sergei Balashev , Neeraj Gupta , Daria Kosenko

We report the detection of hot H$_{2}$O and OH emission from the Herbig Ae/Be star HD$~101412$ using the Cryogenic Infrared Echelle Spectrograph on the $\textit{Very Large Telescope}$. Previous studies of Herbig Ae/Be stars have shown the…

Solar and Stellar Astrophysics · Physics 2019-02-25 Steven C. Adams , Máté Ádámkovics , John S. Carr , Joan R. Najita , Sean D. Brittain

Propargyl alcohol (HC2CH2OH, PA) has yet to be observed in the interstellar medium (ISM) although one of its stable isomers, propenal (CH2CHCHO), has already been detected in Sagittarius B2(N) with the 100-meter Green Bank Telescope in the…

Astrophysics of Galaxies · Physics 2017-01-24 Prasanta Gorai , Ankan Das , Liton Majumdar , Sandip Kumar Chakrabarti , Bhalamurugan Sivaraman , Eric Herbst