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The effect of interstitial hydrogen on the elastic properties of $\alpha$-iron is investigated using \textit{ab initio} density functional theory. We find that while the overall strength properties are reduced by H, the effects are mainly…

Materials Science · Physics 2012-09-14 D. Psiachos , T. Hammerschmidt , R. Drautz

The effect of hydrostatic strain and of interstitial hydrogen on the elastic properties of $\alpha$-iron is investigated using \textit{ab initio} density-functional theory calculations. We find that the cubic elastic constants and the…

Materials Science · Physics 2014-04-07 D. Psiachos , T. Hammerschmidt , R. Drautz

Dislocation core properties of Al with and without H impurities are studied using the Peierls-Nabarro model with parameters determined by ab initio calculations. We find that H not only facilitates dislocation emission from the crack tip…

Materials Science · Physics 2009-11-07 Gang Lu , Qing Zhang , Nicholas Kioussis , Efthimios Kaxiras

We employ density-functional-theory calculations to analyze the interactions between oxygen interstitial atoms and <a>-type screw dislocations (<a> = a<11-20>/3 ) in alpha-titanium, based on investigations of generalized stacking fault…

Materials Science · Physics 2015-02-19 Liang Qi , Tomohito Tsuru , Mark Asta , Daryl Chrzan

First-principles density-functional theory has been used to investigate equilibrium geometries, total energies, and diffusion barriers for H as an interstitial impurity absorbed in $\alpha$-Fe. Internal strains/stresses upon hydrogen…

Materials Science · Physics 2011-06-03 J. Sanchez , J. Fullea , C. Andrade , P. L. de Andres

The interaction of C atoms with a screw and an edge dislocation is modelled at an atomic scale using an empirical Fe-C interatomic potential based on the Embedded Atom Method (EAM) and molecular statics simulations. Results of atomic…

Materials Science · Physics 2008-09-10 Emmanuel Clouet , Sébastien Garruchet , Hoang Nguyen , Michel Perez , Charlotte Becquart

First-principles atomistic molecular dynamics simulation in the micro-canonical and canonical ensembles has been used to study the diffusion of interstitial hydrogen in $\alpha$-iron. Hydrogen to Iron ratios between $\theta=1/16 and 1/2…

Materials Science · Physics 2011-06-03 J. Sanchez , F. Fullea , M. C. Andrade , P. L. de Andres

Hydrogen embrittlement (HE) poses a significant challenge to the durability of materials used in hydrogen production and utilization. Disentangling the competing nanoscale mechanisms driving HE often relies on simulations and…

Modeling hydrogen diffusion and its absorption in traps is a fundamental first step towards the understanding and prediction of hydrogen embrittlement. In this study, a multiscale approach which includes DFT simulations, OkMC, and…

Materials Science · Physics 2025-12-22 Gonzalo Álvarez , Álvaro Ridruejo , Javier Segurado

Metals are important structural materials for transport and the built environment. Low carbon steels can fail through strain localisation due to the role of interstitial solute atoms (such as carbon and nitrogen) interacting with mobile…

Materials Science · Physics 2019-01-24 James L R Hickey , S Rouland , T B Britton

The dislocation core field, which comes in addition to the Volterra elastic field, is studied for the <111> screw dislocation in alpha-iron. This core field, evidenced and characterized using ab initio calculations, corresponds to a biaxial…

Materials Science · Physics 2011-12-22 Emmanuel Clouet , Lisa Ventelon , F. Willaime

In classical elasticity theory the stress-field of a dislocation is characterized by a $1/r$-type singularity. When such a dislocation is considered together with an Allen-Cahn-type phase-field description for microstructure evolution this…

Materials Science · Physics 2021-07-02 M. Budnitzki , S. Sandfeld

We introduced a method to obtain the continuum description of the elastic properties of mono- layer h-BN through ab initio density functional theory. This thermodynamically rigorous contin- uum description of the elastic response is…

Materials Science · Physics 2012-02-01 Qing Peng , Amir R. Zamiri , Suvranu De

High-manganese twinning-induced plasticity (TWIP) steels exhibit high strain hardening, high tensile strength, and high ductility, which make them attractive for structural applications. At low tensile strain rates, TWIP steels are prone to…

Materials Science · Physics 2023-04-27 Heena Khanchandani , Dirk Ponge , Stefan Zaefferer , Baptiste Gault

Dislocation-solute interaction plays fundamental roles in mechanical properties of alloys. Here, we disclose the essential features of dislocation-carbon interaction in austenitic Fe at the atomistic scale. We show that passage of a…

Materials Science · Physics 2020-01-20 Ruiwen Xie , Song Lu , Wei Li , Yanzhong Tian , Levente Vitos

Tensile stress relaxation is combined with transmission electron microscopy to reveal dramatic changes in dislocation structure and sub structure in pure alpha iron as a result of the effects of dissolved hydrogen. We find that hydrogen…

Materials Science · Physics 2019-12-20 Peng Gong , Ivaylo H. Katzarov , Anthony T. Paxton , W. Mark Rainforth

Using ab-initio density functional theory we study the role of interstitial hydrogen on the energetics of the phase transformation of iron from bcc to hcp along Bain's pathway. The impurity creates an internal stress field that can be…

Materials Science · Physics 2011-06-03 A. Castedo , J. Sanchez , J. Fullea , M. C. Andrade , P. L. de Andres

The interaction between carbon and screw dislocations in tungsten is investigated using ab initio calculations. The presence of carbon atoms in the vicinity of the dislocation induces a reconstruction, with the dislocation relaxing to a…

Materials Science · Physics 2021-06-14 Guillaume Hachet , Lisa Ventelon , François Willaime , Emmanuel Clouet

High entropy alloys (HEA) represent a class of materials with promising properties, such as high strength and ductility, radiation damage tolerance, etc. At the same time, a combinatorially large variety of compositions and a complex…

Materials Science · Physics 2025-10-03 Franco Moitzi , Lorenz Romaner , Andrei V. Ruban , Oleg E. Peil

Revealing statistics of H-defect interactions provides insights into significant ductility loss due to the particular strain partitioning in H-charged structural alloys. Experimental investigation of these interactions is extremely…

Materials Science · Physics 2025-01-22 Matthew J. Melfi , S. Mohadeseh Taheri-Mousavi
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