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Related papers: A note about the ground state of the ${\rm H}_3^+$…

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Five physics mechanisms of interaction leading to the binding of the ${\rm H}_3^+$ molecular ion are identified. They are realized in a form of variational trial functions and their respective total energies are calculated. Each of them…

Chemical Physics · Physics 2015-06-12 A. V. Turbiner , J. C. Lopez Vieyra

A first detailed study of the ground state of the H$_3^+$ molecular ion in linear configuration, parallel to a magnetic field direction, and its low-lying $\Si,\Pi,\De$ states is carried out for magnetic fields $B=0-4.414 \times 10^{13} $G…

Atomic Physics · Physics 2009-11-11 A. V. Turbiner , N. L. Guevara , J. C. López Vieyra

A trial function is presented for the $H_2$ molecule which provides the most accurate (the lowest) Bohr-Oppenheimer ground state energy among few-parametric trial functions (with $\leq 14$ parameters). It includes the electronic correlation…

Atomic Physics · Physics 2007-05-23 A. V. Turbiner , N. L. Guevara

A detailed study of the low-lying electronic states ${}^1\Si,{}^3\Si,{}^3\Pi,{}^3\De$ of the $\rm{HeH}^+$ molecular ion in parallel to a magnetic field configuration (when $\al$-particle and proton are situated on the same magnetic line) is…

Atomic Physics · Physics 2009-11-13 A. V. Turbiner , N. L. Guevara

We demonstrate high accuracy calculations for the HeH$^+$ molecule using newly developed analytic formulas for two-center two-electron integrals with exponential functions. The Born-Oppenheimer potential for the ground electronic…

Chemical Physics · Physics 2015-06-04 Krzysztof Pachucki

Potential energy surfaces of the hydrogen molecular ion H$_2^+$ in the Born-Oppenheimer approximation are computed by means of the Riccati-Pad\'e method (RPM). The convergence properties of the method are analyzed for different states. The…

Chemical Physics · Physics 2022-10-25 Francisco Marcelo Fernández , Javier Garcia

A detailed quantitative analysis of the system $(ppe)$ placed in magnetic field ranging from $0 - 4.414 \times 10^{13} G$ is presented. The present study is focused on the question of the existence of the molecular ion $H_2^{+}$ in a…

Astrophysics · Physics 2008-11-26 J. C. Lopez Vieyra , A. V. Turbiner

The bound state in the system of three protons and an electron (pppe) under a homogeneous strong magnetic field where the protons are situated in the vertices of an equilateral triangle perpendicular to the magnetic field lines is found. It…

Astrophysics · Physics 2007-05-23 J. C. Lopez

We report on highly accurate calculations of Born-Oppenheimer potentials for excited $n\,\Sigma^{+}$ states of the hydrogen molecule for all possible combinations of singlet/triplet and gerade/ungerade symmetries up to $n=7$. A relative…

Atomic Physics · Physics 2023-02-28 Michał Siłkowski , Magdalena Zientkiewicz , Krzysztof Pachucki

We present high-precision non-relativistic variational calculations of bound vibrational-rotational state energies for the $H_2^+$ and $D_2^+$ molecular ions in each of the lowest electronic states of $\Sigma_g$, $\Sigma_u$, and $\Pi_u$…

Atomic Physics · Physics 2007-05-23 J. M. Taylor , Zong-Chao Yan , A. Dalgarno , J. F. Babb

The existence of the molecular ion $H_3^{++}$ in a magnetic field in a triangular configuration is revised. Variational method with an optimization of the form of the vector potential (gauge fixing) is used. It is shown that in the range of…

Astrophysics · Physics 2008-11-26 J. C. Lopez Vieyra , A. V. Turbiner

Matching for a wavefunction the WKB expansion at large distances and Taylor expansion at small distances leads to a compact, few-parametric uniform approximation found in {\it J. Phys. B44, 101002 (2011)}. The ten low-lying eigenstates of…

Quantum Physics · Physics 2019-08-13 Horacio Olivares-Pilón , Alexander V. Turbiner

A compact, few-parametric, physically adequate, 3-term variational trial function is used to calculate with high accuracy the energy of the ground state ${}^3\Pi_u$ of the hydrogen molecule ${\rm H}_2$ in strong magnetic field ${\bf B}$ in…

Atomic Physics · Physics 2021-08-04 D. J. Nader , A. V. Turbiner , J. C. López Vieyra

A detailed study of the ground state of the Coulomb system $(\al \al e e)$ which corresponds to the $He_2^{2+}$ molecular ion in a magnetic field $B=0-4.414 \times 10^{13} $ G in parallel configuration (infinitely massive $\al-$particles…

Astrophysics · Physics 2008-11-26 A. V. Turbiner , N. L. Guevara

The static dipole polarizabibility for the $1s\sigma$ electron state of the $\mathrm{H}_{2}^{+}$ hydrogen molecular ion is calculated within Born-Oppenheimer approximation. The variational expansion with randomly chosen exponents has been…

Atomic Physics · Physics 2010-07-27 Ts. Tsogbayar

Highly accurate variational calculations, based on a few-parameter, physically adequate trial function, are carried out for the hydrogen molecule \hh in inclined configuration, where the molecular axis forms an angle $\theta$ with respect…

Atomic Physics · Physics 2019-08-06 A. Alijah , J. C. López Vieyra , D. J. Nader , A. V. Turbiner , H. Medel Cobaxin

For rovibronic states corresponding to the $B$ and $B'\ ^1\Sigma_\text{u}^+$ electronic states of the hydrogen molecule, the pre-Born--Oppenheimer (four-particle) non-relativistic energy is converged to a 1-3 parts-per-billion relative…

Chemical Physics · Physics 2023-01-10 Eszter Saly , Dávid Ferenc , Edit Mátyus

Using a single trial function we perform an accurate calculation of the ground state $1\sigma_g$ of the hydrogenic molecular ion $H^+_2$ in a constant uniform magnetic field ranging $0-10^{13}$ G. We show that this trial function also makes…

Astrophysics · Physics 2009-10-30 J. C. Lopez , P. O. Hess , A. Turbiner

We report on accurate variational calculations of the Born-Oppenheimer potential for excited states of the hydrogen molecule with $\Pi$, $\Delta$, and $\Phi$ symmetries. The obtained potential energy curves reach the relative precision of…

Atomic Physics · Physics 2023-01-11 Michał Siłkowski , Krzysztof Pachucki

Accurate calculations for the ground state of the molecular ions He$_2^{3+}$ and HeH$^{2+}$ placed in a strong magnetic field $B\gtrsim 10^{2}$ a.u. ($\approx 2.35 \times 10^{11}$G) using the Lagrange-mesh method are presented. The…

High Energy Astrophysical Phenomena · Physics 2015-06-03 Horacio Olivares Pilón
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