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We present detailed electronic structure calculations for CaFe2As2. We investigate in particular the `collapsed' tetragonal and orthorhombic regions of the temperature-pressure phase diagram and find properties that distinguish CaFe2As2…

Strongly Correlated Electrons · Physics 2009-03-27 D. A. Tompsett , G. G. Lonzarich

With the proposed Hund's rule correlation picture, i.e. the fluctuating Fe local moments with the As-bridged antiferromagnetic superexchange interactions, the exceptional collapsed tetragonal phase and related phase transitions observed in…

Materials Science · Physics 2011-04-28 Wei Ji , Xun-Wang Yan , Zhong-Yi Lu

Compounds with a tetragonal ThCr$_{2}$Si$_{2}$-type structure are characterized by the possibility of the isostructural phase transition from the tetragonal phase to the collapsed tetragonal phase induced by the external pressure. An…

Superconductivity · Physics 2019-04-16 Andrzej Ptok , Małgorzata Sternik , Konrad Jerzy Kapcia , Przemysław Piekarz

The recent discovery and subsequent developments of FeAs-based superconductors have presented novel challenges and opportunities in the quest for superconducting mechanisms in correlated-electron systems. Central issues of ongoing studies…

Single crystals of SrFe2As2 grown using a self-flux solution method were characterized via x-ray, transport and magnetization studies, revealing a superconducting phase below T_c = 21 K characterized by a full electrical resistivity…

Superconductivity · Physics 2009-07-21 S. R. Saha , N. P. Butch , K. Kirshenbaum , J. Paglione

The recently discovered FeAs-based superconductors are a new, promising set of materials for both technological as well as basic research. They offer transition temperatures as high as 55 K as well as essentially isotropic and extremely…

Superconductivity · Physics 2015-05-18 Paul C. Canfield , Sergey L. Bud'ko

Single crystalline samples of Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ with $x < 0.12$ have been grown and characterized via microscopic, thermodynamic and transport measurements. With increasing Co substitution, the thermodynamic and transport…

Superconductivity · Physics 2009-11-13 N. Ni , M. E. Tillman , J. -Q. Yan , A. Kracher , S. T. Hannahs , S. L. Bud'ko , P. C. Canfield

We present heat capacity, c-axis thermal expansion and pressure dependent, low field, temperature dependent magnetization for pressures up to ~ 12 kbar, data for KFe2As2 single crystals. Tc decreases under pressure with dTc/dP ~ -0.10…

Superconductivity · Physics 2015-06-12 Sergey L. Bud'ko , Yong Liu , Thomas A. Lograsso , Paul C. Canfield

A brief overview of changes in the superconducting transition temperature under pressure and evolution of specific heat capacity jump at Tc for two related families of iron - based superconductors, Ba{1-x}KxFe2As2 (0.2 < x < 1.0) and…

Superconductivity · Physics 2015-02-23 Sergey L. Bud'ko

Temperature dependent high pressure electrical resistivity studies has been carried out on Ba(Fe_{1-x}Ru_{x})_{2}As_{2} single crystals with x = 0.12, 0.26 and 0.35, which correspond to under doped, optimally doped and over doped…

Superconductivity · Physics 2014-02-17 T. R. Devidas , Awadhesh Mani , Shilpam Sharma , K. Vinod , A. Bharathi , C. S. Sundar

Temperature dependent measurements of 57Fe Mossbauer spectra on CaFe2As2 single crystals in the tetragonal and collapsed tetragonal phases are reported. Clear features in the temperature dependencies of the isomer shift, relative spectra…

Materials Science · Physics 2016-01-27 Sergey L. Bud'ko , Xiaoming Ma , Milan Tomic , Sheng Ran , Roser Valenti , Paul C. Canfield

SrPt$_2$As$_2$ single crystals with CaBe$_2$Ge$_2$-type structure were synthesized by self-melting technique. X-ray diffraction, transmission electron microscopy, electrical resistivity, specific heat and optical spectroscopy measurements…

Superconductivity · Physics 2013-05-30 A. F. Fang , T. Dong , H. P. Wang , Z. G. Chen , B. Cheng , Y. G. Shi , P. Zheng , G. Xu , L. Wang , J. Q. Li , N. L. Wang

The iron-based pnictide LaFe2As2 is not superconducting as-synthesized, but it becomes such below Tc around 12 K upon annealing, as a consequence of a structural transition from a phase with collapsed tetragonal crystal structure to an…

We report a high-pressure study of simultaneous low-temperature electrical resistivity and Hall effect measurements on high quality single-crystalline KFe2As2 using designer diamond anvil cell techniques with applied pressures up to 33 GPa.…

We report the effect of applied pressures on magnetic and superconducting order in single crystals of the aliovalent La-doped iron pnictide material Ca$_{1-x}$La$_{x}$Fe$_{2}$As$_{2}$. Using electrical transport, elastic neutron scattering…

Applying an external pressure to indirectly electron-doped 122-type (Ba1-xLax)Fe2As2 epitaxial films enhances the superconducting critical temperature (Tc) up to 30.3 K. Different from the other family compounds, the Tc is enhanced not only…

Superconductivity · Physics 2013-10-16 Takayoshi Katase , Hikaru Sato , Hidenori Hiramatsu , Toshio Kamiya , Hideo Hosono

Recently, KFe$_2$As$_2$ was shown to exhibit a structural phase transition from a tetragonal to a collapsed tetragonal phase under applied pressure of about $15~\mathrm{GPa}$. Surprisingly, the collapsed tetragonal phase hosts a…

Superconductivity · Physics 2015-04-14 Daniel Guterding , Steffen Backes , Harald O. Jeschke , Roser Valenti

FeSe-derived superconductors show some unique behaviors relative to iron-pnictide superconductors, which are very helpful to understand the mechanism of superconductivity in high-Tc iron-based superconductors. The low-energy electronic…

Superconductivity · Physics 2014-12-17 X. F. Lu , N. Z. Wang , H. Wu , Y. P. Wu , D. Zhao , X. Z. Zeng , X. G. Luo , T. Wu , W. Bao , G. H. Zhang , F. Q. Huang , Q. Z. Huang , X. H. Chen

Quantum materials such as antiferromagnets or superconductors are complex in that chemical, electronic, and spin phenomena at atomic scales can manifest in their collective properties. Although there are some clues for designing such…

Superconductivity · Physics 2018-04-10 L. Li , Q. Zheng , Q. Zou , S. Rajput , A. O. Ijaduola , Z. Wu , X. P. Wang , H. B. Cao , M. Chi , Z. Gai , D. Parker , A. S. Sefat

The structural properties of the CaFe2As2 have been investigated by x-ray and neutron powder diffraction techniques as a function of temperature. Unambiguous experimental evidence is shown for coexistence of tetragonal and orthorhombic…

Superconductivity · Physics 2013-11-27 S. K. Mishra , R. Mittal , P. S. R. Krishna , P. U. Sastry , S. L. Chaplot , P. D. Babu , S. Matsuishi , H. Hosono