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The set of solutions inferred by the generic maximum entropy (MaxEnt) or maximum relative entropy (MaxREnt) principles of Jaynes - considered as a function of the moment constraints or their conjugate Lagrangian multipliers - is endowed…

Statistical Mechanics · Physics 2017-08-23 Robert K. Niven , Bjarne Andresen

We introduce an axiomatic approach to entropies and relative entropies that relies only on minimal information-theoretic axioms, namely monotonicity under mixing and data-processing as well as additivity for product distributions. We find…

Information Theory · Computer Science 2021-09-22 Gilad Gour , Marco Tomamichel

Perturbation theory is used to investigate the evolution of the von Neumann entropy of a subsystem of a bipartite quantum system under the action of a unitary matrix, in the limit where that matrix is close to the unit matrix. The physical…

Quantum Physics · Physics 2025-09-08 Duncan MacIntyre , Gordon W. Semenoff

The formal consideration of the concept of interaction in thermodynamic analysis makes it possible to deduce, in the broadest terms, new results related to the coevolution of interacting systems, irrespective of their distance from…

Populations and Evolution · Quantitative Biology 2008-05-04 Antonio Leon

Active systems are characterized by a continuous production of entropy at steady state. We study the statistics of entropy production within a lattice-based model of interacting active particles that is capable of motility-induced phase…

Statistical Mechanics · Physics 2022-12-21 Tal Agranov , Michael E. Cates , Robert L. Jack

The concept of limiting step gives the limit simplification: the whole network behaves as a single step. However, in its simplest form this idea is applicable only to the simplest linear cycles in steady states. For such the simplest cycles…

Chemical Physics · Physics 2008-06-23 A. N. Gorban , O. Radulescu

Entropy production for a system not in the thermodynamic limit is formulated using Hill's nanothermodynamics, in which a macroscopic ensemble of such systems is considered. External influence of the environment on the average nanosystem is…

Statistical Mechanics · Physics 2011-03-21 J. Carrete , L. M. Varela , L. J. Gallego

By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/\tau+\sigma={\it maximum}$, where $S_S$ is system entropy, $\sigma$ is entropy production and $\tau$ is…

Statistical Mechanics · Physics 2016-07-26 Yong-Jun Zhang

We extend the Gibbs conditioning principle to an abstract setting combining infinitely many linear equality constraints and non-linear inequality constraints, which need not be convex. A conditional large large deviation principle (LDP) is…

Functional Analysis · Mathematics 2024-10-29 Louis-Pierre Chaintron , Giovanni Conforti , Julien Reygner

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

We address the emergence of entropy production in the non-equilibrium process of an open quantum system from the viewpoint of the environment. By making use of a dilation-based approach akin to Stinespring theorem, we derive an expression…

The entropy production rate is a key quantity in irreversible thermodynamics. In this work, we concentrate on the realization of entropy production rate in chemical reaction systems in terms of the experimentally measurable reaction rate.…

Chemical Physics · Physics 2019-11-14 Kinshuk Banerjee , Kamal Bhattacharyya

In a glassy system different degrees of freedom have well-separated characteristic times, and are described by different temperatures. The stationary state is essentially non-equilibrium. A generalized statistical thermodynamics is…

Disordered Systems and Neural Networks · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

Nonequilibrium processes break time-reversal symmetry and generate entropy. Living systems are driven out-of-equilibrium at the microscopic level of molecular motors that exploit chemical potential gradients to transduce free energy to…

Statistical Mechanics · Physics 2022-12-06 Eden Nitzan , Aishani Ghosal , Gili Bisker

We derive an exact (classical and quantum) expression for the entropy production of a finite system placed in contact with one or several finite reservoirs each of which is initially described by a canonical equilibrium distribution.…

Statistical Mechanics · Physics 2015-05-13 Massimiliano Esposito , Katja Lindenberg , Christian Van den Broeck

The maximum entropy principle, as applied to quantum systems, is a fundamental prescript positing that for a quantum system for which we only have partial knowledge, the maximum entropy state consistent with the partial knowledge is a…

Quantum Physics · Physics 2025-07-24 Siddhartha Das , Ujjwal Sen

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner

Statistical properties of coupled dynamic-stochastic systems are studied within a combination of the maximum information principle and the superstatistical approach. The conditions at which the Shannon entropy functional leads to a…

Statistical Mechanics · Physics 2009-11-11 E. V. Vakarin , J. P. Badiali

The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…

Statistical Mechanics · Physics 2018-11-14 Dragos-Victor Anghel , Alexandru S. Parvan

Non-reciprocal interactions are present in many systems out of equilibrium. The rate of entropy production is a measure that quantifies the time irreversibility of a system, and thus how far it is from equilibrium. In this work, we…

Statistical Mechanics · Physics 2022-11-28 Ziluo Zhang , Rosalba Garcia-Millan
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