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A simple approximation which captures some non-perturbative aspects of the one electron Green function of strongly interacting Fermion systems is developed. It provides a way to go one step beyond the usual dilute limit since…

Condensed Matter · Physics 2016-08-31 Ted Hsu , Benoit Doucot

In this paper, we propose a generic and systematic approach for study of the electronic structure for atoms or molecules. In particular, we address the issue of single particle states, or orbitals, which should be one of the most important…

Chemical Physics · Physics 2007-05-23 Liqiang Wei

We present a new, highly efficient yet accurate approximation for the Green's functions of dressed particles, using the Holstein polaron as an example. Instead of summing a subclass of diagrams (e.g. the non-crossed ones, in the…

Other Condensed Matter · Physics 2009-11-11 Mona Berciu

A modified $GW$ approximation to many - body systems is developed. The approximation has the same computational complexity as the traditional $GW$ approach, but uses a different truncation scheme. This scheme neglects high order connected…

Strongly Correlated Electrons · Physics 2021-09-29 Zhipeng Sun , Zhenhao Fan , Hui Li , Dingping Li , Baruch Rostenstein

We lay down the {\em ab initio} many-body quantum theory of electrons and phonons in- and out-of-equilibrium at any temperature. We begin by addressing a fundamental issue concerning the {\em ab initio} Hamiltonian in the harmonic…

Materials Science · Physics 2024-02-19 Gianluca Stefanucci , Robert van Leeuwen , Enrico Perfetto

This article presents an overview on recent progress in the theory of nonequilibrium Green functions (NEGF). NEGF, presently, are the only \textit{ab-initio} quantum approach that is able to study the dynamics of correlations for long times…

Strongly Correlated Electrons · Physics 2019-12-20 N. Schluenzen , S. Hermanns , M. Scharnke , M. Bonitz

We propose a scheme for the construction of one-particle Green's function (GF) of an interacting electronic system via statistical sampling on a quantum computer. Although the non-unitarity of creation and annihilation operators for the…

Quantum Physics · Physics 2020-02-19 Taichi Kosugi , Yu-ichiro Matsushita

We present a many-body $GW$ formalism for quantum subsystems embedded in discrete polarizable environments containing up to several hundred thousand atoms described at a fully ab initio random phase approximation level. Our approach is…

Chemical Physics · Physics 2024-01-26 David Amblard , Xavier Blase , Ivan Duchemin

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

Methods for electronic structure based on Gaussian and molecular orbital discretizations offer a well established, compact representation that forms much of the foundation of correlated quantum chemistry calculations on both classical and…

In this work we explore the performance of approximations to electron correlation in reduced density-matrix functional theory (RDMFT) and of approximations to the observables calculated within this theory. Our analysis focuses on the…

Strongly Correlated Electrons · Physics 2015-02-26 Stefano Di Sabatino , Jan A. Berger , Lucia Reining , Pina Romaniello

We report an implementation of self-consistent Green's function many-body theory within a second-order approximation (GF2) for application with molecular systems. This is done by iterative solution of the Dyson equation expressed in matrix…

Chemical Physics · Physics 2016-11-15 Jordan J. Phillips , Dominika Zgid

Computationally inexpensive approximations describing electron-phonon scattering in molecular-scale conductors are derived from the non-equilibrium Green's function method. The accuracy is demonstrated with a first principles calculation on…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Magnus Paulsson , Thomas Frederiksen , Mads Brandbyge

Recent high resolution Compton scattering experiments clearly reveal that there are fundamental limitations to the conventional local density approximation (LDA) based description of the ground state electron momentum density (EMD) in…

Strongly Correlated Electrons · Physics 2007-10-11 B. Barbiellini , A. Bansil

We introduce diagrammatic technique for Hubbard nonequilibrium Green functions (NEGF). The formulation is an extension of equilibrium considerations for strongly correlated lattice models to description of current carrying molecular…

Mesoscale and Nanoscale Physics · Physics 2016-11-04 Feng Chen , Maicol A. Ochoa , Michael Galperin

Representing spectral densities, real-frequency, and real-time Green's functions of continuous systems by a small discrete set of complex poles is an ubiquitous problem in condensed matter physics, with applications ranging from quantum…

Strongly Correlated Electrons · Physics 2025-06-04 Lei Zhang , André Erpenbeck , Yang Yu , Emanuel Gull

In this paper, we present a mathematical analysis of time-dependent $N$-body electronic systems and establish mixed regularity for the corresponding wavefunctions. Based on this, we develop sparse grid approximations to reduce computational…

Numerical Analysis · Mathematics 2025-09-16 Long Meng , Dexuan Zhou

A well-established method to deal with highly correlated systems is based on the expansion of the Green's function in terms of spectral moments. In the context of the Composite Operator Method one approximation is proposed: a set of n…

Strongly Correlated Electrons · Physics 2007-05-23 F. Mancini

In this work, we propose an efficient computational scheme for first-principle quantum transport simulations to evaluate the open-boundary conditions. Its partitioning differentiates from conventional methods in that the contact self-energy…

Materials Science · Physics 2021-01-01 Guido Gandus , Youseung Lee , Daniele Passerone , Mathieu Luisier

Using the finite-element discrete variable representation of the nonequilibrium Green's function (NEGF) we extend previous work [K.~Balzer et al., Phys. Rev. A \textbf{81}, 022510 (2010)] to nonequilibrium situations and compute---from the…

Atomic Physics · Physics 2010-11-29 K. Balzer , S. Bauch , M. Bonitz