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The ultrafast hole dynamics triggered by the photoexcitation of molecular targets is a highly correlated process even for those systems, like organic molecules, having a weakly correlated ground state. We here provide a unifying framework…

Chemical Physics · Physics 2021-07-21 Yaroslav Pavlyukh , Enrico Perfetto , Gianluca Stefanucci

In a recent series of scanning probe experiments, it became possible to visualize local electron flow in a two-dimensional electron gas. In this paper, a Green's function technique is presented that enables efficient calculation of the…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 G. Metalidis , P. Bruno

A few approximate schemes to solve the Hedin equations self-consistently introduced in (Phys. Rev. B 94, 155101 (2016)) are explored and tested for the 3D electron gas at metallic densities. We calculate one electron spectra, dielectric…

Strongly Correlated Electrons · Physics 2017-07-12 A. L. Kutepov , G. Kotliar

The magnon Hedin's equations are derived via the Schwinger functional derivative technique, and the resulting self-consistent Green's function method is used to calculate ground state spin patterns and magnetic structure factors for…

Strongly Correlated Electrons · Physics 2022-11-30 Zhen Zhao , Claudio Verdozzi , Ferdi Aryasetiawan

We present an approach for self-consistent calculations of the many-body Green function in transition metals. The distinguishing feature of our approach is the use of the one-site approximation and the self-consistent quasiparticle wave…

Strongly Correlated Electrons · Physics 2009-11-07 N. E. Zein , V. P. Antropov

Spectroscopic and optical properties of nanosystems and point defects are discussed within the framework of Green's function methods. We use an approach based on evaluating the self-energy in the so-called GW approximation and solving the…

Materials Science · Physics 2009-11-11 Murilo L. Tiago , James R. Chelikowsky

Over the years, Hedin's $GW$ self-energy has been proven to be a rather accurate and simple approximation to evaluate electronic quasiparticle energies in solids and in molecules. Attempts to improve over the simple $GW$ approximation, the…

Computational Physics · Physics 2024-01-24 Fabien Bruneval , Arno Förster

The $GW$ approximation has recently gained increasing attention as a viable method for the computation of deep core-level binding energies as measured by X-ray photoelectron spectroscopy (XPS). We present a comprehensive benchmark study of…

Chemical Physics · Physics 2022-06-14 Jiachen Li , Ye Jin , Patrick Rinke , Weitao Yang , Dorothea Golze

An accurate expression of the kinetic energy density of an electronic distribution in terms of the single particle reduced density matrix for atomic and molecular systems is a long-standing problem in electron structure theory. Existing…

Chemical Physics · Physics 2024-10-30 Priya , Mainak Sadhukhan

An efficient all-electron G$^0$W$^0$ method and a quasiparticle selfconsistent GW (QSGW) method for molecules are proposed in the molecular orbital space with the full random phase approximation. The convergence with basis set is examined.…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 San-Huang Ke

A nonequilibrium Green's functions (NEGF) approach for spatially inhomogeneous, strongly correlated artificial atoms is presented and applied to compute the time-dependent properties while starting from a (correlated) initial few-electron…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 K Balzer , M Bonitz

We derive a low-scaling $G_0W_0$ algorithm for molecules, using pair atomic density fitting (PADF) and an imaginary time representation of the Green's function and describe its implementation in the Slater type orbital (STO) based Amsterdam…

Chemical Physics · Physics 2020-11-13 Arno Förster , Lucas Visscher

The Green's function method has applications in several fields in Physics, from classical differential equations to quantum many-body problems. In the quantum context, Green's functions are correlation functions, from which it is possible…

Mesoscale and Nanoscale Physics · Physics 2016-10-14 Mariana M. Odashima , Beatriz G. Prado , E. Vernek

The GW approximation of many-body perturbation theory is an accurate method for computing electron addition and removal energies of molecules and solids. In a canonical implementation, however, its computational cost is $O(N^4)$ in the…

Chemical Physics · Physics 2021-04-21 Jan Wilhelm , Dorothea Golze , Leopold Talirz , Jürg Hutter , Carlo A. Pignedoli

Historically, the GW approach was put forward by Hedin as the simplest approximation to the so-called Hedin equations. In Section 2, we will derive these Hedin equations from a Feynman-diagrammatical point of view. Section 3.1 shows how GW…

Materials Science · Physics 2011-09-20 K. Held , C. Taranto , G. Rohringer , A. Toschi

We present a detailed account of the GW space-time method. The method increases the size of systems whose electronic structure can be studied with a computational implementation of Hedin's GW approximation. At the heart of the method is a…

Condensed Matter · Physics 2009-10-31 M. M. Rieger , L. Steinbeck , I. D. White , H. N. Rojas , R. W. Godby

Calculations of ground-state and excited-state properties of materials have been one of the major goals of condensed matter physics. Ground-state properties of solids have been extensively investigated for several decades within the…

Strongly Correlated Electrons · Physics 2009-10-30 F. Aryasetiawan , O. Gunnarsson

We combine the recently developed many-body Green's function theory for electrons and nuclei with the exact factorization of the wave function. The existing Born-Oppenheimer Green's functions are shown to be special cases of our exact…

Other Condensed Matter · Physics 2022-11-23 Ville J. Härkönen

In this article we derive the lattice Green Functions (GFs) of graphene using a Tight Binding Hamiltonian incorporating both first and second nearest neighbour hoppings and allowing for a non-orthogonal electron wavefunction overlap. It is…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 James A. Lawlor , Mauro S. Ferreira

We present a nontrivial model system of interacting electrons that can be solved analytically in the GW approximation. We obtain the particle number from the GW Green's function strictly analytically, and prove that there is a genuine…

Materials Science · Physics 2008-02-03 Arno Schindlmayr