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Using molecular dynamics simulation, we have calculated the pressure dependence of the diffusion constant in a binary Lennard-Jones Glass. We observe four temperature regimes. The apparent activation volume drops from high values in the hot…

Disordered Systems and Neural Networks · Physics 2009-11-07 H. R. Schober

The phase diagram of the prototypical two-dimensional Lennard-Jones system, while extensively investigated, is still debated. In particular, there are controversial results in the literature as concern the existence of the hexatic phase and…

Statistical Mechanics · Physics 2020-12-08 Yan-Wei Li , Massimo Pica Ciamarra

The optimal conversion of a continuous inter-particle potential to a discrete equivalent is considered here. Existing and novel algorithms are evaluated to determine the best technique for creating accurate discrete forms using the minimum…

Soft Condensed Matter · Physics 2014-02-13 Chris Thomson , Leo Lue , Marcus N. Bannerman

We prepare metastable glassy states in a model glass-former made of Lennard-Jones particles by sampling biased ensembles of trajectories with low dynamical activity. These trajectories form an inactive dynamical phase whose `fast'…

Statistical Mechanics · Physics 2011-12-30 Robert L. Jack , Lester O. Hedges , Juan P. Garrahan , David Chandler

Melt supercooling leads to glass formation. Liquid-to-liquid phase transitions are observed depending on thermal paths. Viscosity, density and surface tension thermal dependences measured at heating and subsequent cooling show hysteresis…

Materials Science · Physics 2016-12-21 Robert F. Tournier

We compare vibrational dynamics in two structurally distinct, simple monatomic model glasses simulated by molecular dynamics: the Lennard-Jones glass with an fcc-related structure and a glass with predominantly icosahedral short-range…

Disordered Systems and Neural Networks · Physics 2009-10-31 S. I. Simdyankin , M. Dzugutov , S. N. Taraskin , S. R. Elliott

The Lennard-Jones potential is perhaps one of the most widely-used models for the interaction of uncharged particles, such as noble gas solids. The phase diagram of the classical LJ solid is known to exhibit transitions between hcp and fcc…

Materials Science · Physics 2020-06-16 Heather Wiebe , Tom L. Underwood , Graeme J. Ackland

The transparence of a laser-driven optical resonator containing an ensemble of cold atoms can have two distinct, robust states. Atoms in their initially prepared pure state blockade the transmission by detuning the cavity mode from the…

Quantum Physics · Physics 2022-06-29 T. W. Clark , A. Dombi , F. I. B. Williams , Á. Kurkó , J. Fortágh , D. Nagy , A. Vukics , P. Domokos

We present the results of molecular dynamics simulations of the Gay-Berne model of liquid crystals, supercooled from the nematic phase. We find a glass transition to a metastable phase with nematic order and frozen translational and…

Condensed Matter · Physics 2007-05-23 A. M. Smondyrev , Robert A. Pelcovits

We consider thermodynamic and dynamic phase transitions in plaquette spin models of glasses. The thermodynamic transitions involve coupled (annealed) replicas of the model. We map these coupled-replica systems to a single replica in a…

Statistical Mechanics · Physics 2015-08-19 Robert M. Turner , Robert L. Jack , Juan P. Garrahan

On the basis of microscopic statistical mechanics of simple liquids the orientational interaction between clusters consisting of a particle and its nearest neighbors is estimated. It is shown that there are ranges of density and temperature…

Disordered Systems and Neural Networks · Physics 2009-11-10 N. M. Chtchelkatchev , V. N. Ryzhov , T. I. Schelkacheva , E. E. Tareyeva

A molecular dynamics study of a two dimensional system of particles interacting through a Lennard-Jones pairwise potential is performed at fixed temperature and vanishing external pressure. As the temperature is increased, a solid-to-liquid…

Statistical Mechanics · Physics 2015-05-27 Daniel Asenjo , Fernando Lund , Simón Poblete , Rodrigo Soto , Marcos Sotomayor

First-order phase transition in a highly correlated electron system can manifest as a dynamic phenomenon. The presence of multiple domains of the coexisting phases average out the dynamical effects making it nearly impossible to predict the…

Mesoscale and Nanoscale Physics · Physics 2014-09-17 Devendra Kumar , K. P. Rajeev , J. A. Alonso , M. J. Martínez-Lope

Using the crystallization transition in a Lennard-Jones fluid as example, we show that mean first-passage time based methods may underestimate the reaction rates. We trace the reason of this deficiency back to the non-Markovian character of…

Soft Condensed Matter · Physics 2017-10-06 S. Jungblut , C. Dellago

We show that a fluid under strong spatially periodic confinement displays a glass transition within mode-coupling theory (MCT) at a much lower density than the corresponding bulk system. We use fluctuating hydrodynamics, with confinement…

Soft Condensed Matter · Physics 2013-03-14 Saroj Kumar Nandi , Sarika Maitra Bhattacharyya , Sriram Ramaswamy

A method is proposed to compute the interfacial free energy of a Lennard-Jones system in contact with a structured wall by molecular dynamics simulation. Both the bulk liquid and bulk face-centered-cubic crystal phase along the (111)…

Statistical Mechanics · Physics 2015-06-04 Ronald Benjamin , Jürgen Horbach

Wetting and drying of a rigid substrate by a Lennard-Jones fluid in molecular dynamics simulations is reported. The size of the substrate particles, being smaller than the fluid particles in former simulations, is now taken to be equal to,…

Soft Condensed Matter · Physics 2015-06-25 C. Bruin

We formulate and solve a model of dynamical arrest in colloids. A particle is coupled to the bath of statistically identical particles. The dynamics is described by Langevin equation with stochastic external force described by telegraphic…

Statistical Mechanics · Physics 2007-05-23 Frantisek Slanina , Petr Chvosta

The classic Kob-Andersen (KA) binary Lennard-Jones mixtures which are designed to prevent crystallization has been extensively studied in simulation of slow dynamics. Although crystallization can occur if a liquid system is cooled slowly,…

Soft Condensed Matter · Physics 2017-03-10 Penghui Cao

The physical behavior of glass-forming liquids presents complex features of both dynamic and thermodynamic nature. Some studies indicate the presence of thermodynamic anomalies and of crossovers in the dynamic properties, but their origin…

Statistical Mechanics · Physics 2018-06-08 Daniele Coslovich , Misaki Ozawa , Walter Kob