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A phase-field formulation is introduced to simulate quantitatively microstructural pattern formation in alloys. The thin-interface limit of this formulation yields a much less stringent restriction on the choice of interface thickness than…

Materials Science · Physics 2016-08-31 Alain Karma

We further develop a recently introduced phase-field model of rapid alloy solidification [Ji et al., PRL 2023]. This model utilizes enhanced solute diffusivity within the spatially diffuse interface region to quantitatively capture solute…

Materials Science · Physics 2025-08-11 Kaihua Ji , Mingwang Zhong , Alain Karma

A new diffuse interface model has been proposed in this study for simulating binary alloy solidification under universal cooling conditions, involving both equilibrium and non-equilibrium solute partitioning. Starting from the Gibbs-Thomson…

Materials Science · Physics 2023-09-22 Chuanqi Zhu , Yusuke Seguchi , Masayuki Okugawa , Yuichiro Koizumi

We study initial transient stages in directional solidification by means of a non-variational phase field model with fluctuations. This model applies for the symmetric solidification of dilute binary solutions and does not invoke…

Materials Science · Physics 2016-08-16 R. Benítez , L. Ramírez-Piscina

A phase-field model that allows for quantitative simulations of low-speed eutectic and peritectic solidification under typical experimental conditions is developed. Its cornerstone is a smooth free-energy functional, designed so that the…

Materials Science · Physics 2009-11-11 R. Folch , M. Plapp

The phase-field method is reviewed from the general perspective of converting a free boundary problem into a set of coupled partial differential equations. Its main advantage is that it avoids front tracking by using phase fields to locate…

We present a detailed derivation and thin interface analysis of a phase-field model that can accurately simulate microstructural pattern formation for low-speed directional solidification of a dilute binary alloy. This advance with respect…

Materials Science · Physics 2009-11-10 Blas Echebarria , Roger Folch , Alain Karma , Mathis Plapp

The effect of nonequilibrium solute trapping by a growing solid under rapid solidification conditions is studied using a phase-field model. Considering a continuous steady-state concentration profile across the diffuse solid-liquid…

Materials Science · Physics 2007-05-23 Denis Danilov , Britta Nestler

We present a new phase-field model of solidification which allows efficient computations in the regime when interface kinetic effects dominate over capillary effects. The asymptotic analysis required to relate the parameters in the…

Condensed Matter · Physics 2007-05-23 Kalin Vetsigian , Nigel Goldenfeld

The kinetics of interfaces in alloy solidification pose a classic free boundary problem. This paper introduces an approach that amalgamates the distinctive characteristics of sharp and diffuse interface models. The motion of the diffuse…

Materials Science · Physics 2024-05-31 Chuanqi Zhu , Yuichiro Koizumi

A phase-field approach to the dynamics of liquid-solid interfaces that evolve due to precipitation and/or dissolution is presented. For the purpose of illustration and comparison with other methods, phase field simulations were carried out…

Computational Physics · Physics 2018-07-04 Zhijie Xu , Paul Meakin

Directional solidification of water-based solutions has emerged as a versatile technique for templating hierarchical porous materials. However, the underlying mechanisms of pattern formation remain incompletely understood. In this work, we…

Materials Science · Physics 2026-03-20 Kaihua Ji , Alain Karma

The near-rapid solidification conditions during additive manufacturing can lead to selection of non-equilibrium phases. Sharp interface models via interface response functions have been used earlier to explain the microstructure selection…

Materials Science · Physics 2023-03-15 V. S. Hariharan , B. S. Murty , Gandham Phanikumar

Phase field models for two-phase flow with a surfactant soluble in possibly both fluids are derived from balance equations and an energy inequality so that thermodynamic consistency is guaranteed. Via a formal asymptotic analysis, they are…

Fluid Dynamics · Physics 2013-03-12 Harald Garcke , Kei Fong Lam , Björn Stinner

In alloy solidification, the transport processes of heat and solute result in morphological instability of the interface, forming different patterns of solidification structure and determining the mechanical properties of components. As the…

Materials Science · Physics 2023-04-05 Fengyi Yu

Phase-field models of microstructural pattern formation during alloy solidification are commonly solved numerically using the finite-difference method, which is ideally suited to carry out computationally efficient simulations on massively…

Materials Science · Physics 2022-02-17 Kaihua Ji , Amirhossein Molavi Tabrizi , Alain Karma

From a simple bulk model for the one-dimensional steady-state solidification of a dilute binary alloy we derive an interface description, allowing arbitrary values of the growth velocity. Our derivation leads to exact expressions for the…

Materials Science · Physics 2015-06-05 Alexander L. Korzhenevskii , Richard Bausch , Rudi Schmitz

The existing theoretical analyses of solidification dynamics lack the insights of historical relevance and transport processes in the whole system. Through the phase-field model, this paper investigates the evolution in the whole domain…

Materials Science · Physics 2023-09-06 Fengyi Yu

We introduce a new phase-field formulation of rapid alloy solidification that quantitatively incorporates nonequilibrium effects at the solid-liquid interface over a very wide range of interface velocities. Simulations identify a new…

Materials Science · Physics 2023-01-16 Kaihua Ji , Elaheh Dorari , Amy J. Clarke , Alain Karma

In this paper the development of a physically consistent phase-field theory of solidification shrinkage is presented. The coarse-grained hydrodynamic equations are derived directly from the N-body Hamiltonian equations in the framework of…

Materials Science · Physics 2020-02-28 Gyula I. Toth , Wenyue Ma
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