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The recent observation of a ferroelectric-like structural transition in metallic LiOsO$_3$ has generated a flurry of interest in the properties of polar metals. Such materials are thought to be rare because free electrons screen out the…

Materials Science · Physics 2016-02-29 Nicole A. Benedek , Turan Birol

Using first-principles calculations, we predict a lightweight room-temperature ferroelectric carbon-boron framework in a host/guest clathrate structure. This ferroelectric clathrate, with composition ScB$_3$C$_3$, exhibits high polarization…

Materials Science · Physics 2020-09-18 Li Zhu , Timothy A. Strobel , R. E. Cohen

Ferroelectricity in perovskites is known to be suppressed by a moderate hydrostatic pressure. The notion that a polar instability should reappear in a higher pressure regime is well accepted theoretically but experiments have failed so far…

Magnetic dc susceptibility between 1.5 and 800 K, ac susceptibility and magnetization, thermodynamic properties, temperature dependence of radio and audio-wave dielectric constants and conductivity, contact-free dielectric constants at…

Materials Science · Physics 2010-07-22 Jun Lu , A. Günther , F. Schrettle , F. Mayr , S. Krohns , P. Lunkenheimer , A. Pimenov , V. D. Travkin , A. A. Mukhin , A. Loidl

Against expectations, robust switchable ferroelectricity has been recently observed in ultrathin (1 nm) ferroelectric films exposed to air [V. Garcia $et$ $al.$, Nature {\bf 460}, 81 (2009)]. Based on first-principles calculations, we show…

Mesoscale and Nanoscale Physics · Physics 2012-01-10 N. C. Bristowe , Massimiliano Stengel , P. B. Littlewood , J. M. Pruneda , Emilio Artacho

A wide variety of applications has inspired great interest in designing new materials and investigating fundamental physics in the ferroelectric field. In the concept of ferroelectricity, the spontaneous polarization is traditionally…

Materials Science · Physics 2025-03-18 Zengqian Wang , Yuanfang Yue , Z. Y. Xie , Fengjie Ma , Xun-Wang Yan

Persistent electrical polarized states are fundamentally important to the electric industry as they can be used in the non-volatile memory, the artificial neuromorphic network, and negative capacitors, making ultralow energy consumption…

Mesoscale and Nanoscale Physics · Physics 2020-01-10 Chengcheng Xiao , Zhu-An Xu , Xin Luo , Yunhao Lu

A significant effort in condensed matter physics is dedicated to the search for exotic arrangements of electric dipoles in crystals. Non-collinear dipolar arrangements mimicking magnetic spin textures, such as polar vortices and skyrmions,…

Mesoscale and Nanoscale Physics · Physics 2025-10-02 Yang Zhang , Mingyu Xu , Jie Li , Suk Hyun Sung , Sang-Wook Cheong , Weiwei Xie , Ismail El Baggari

We report nearly single phase Pb(Zr0.14Ti0.56Ni0.30)O3-delta(PZTNi30) ferroelectric having large remanent polarization (15-30 {\mu}C/cm2), 0.3-0.4 V open circuit voltage (VOC), reduced band gap (direct 3.4 eV, and indirect 2.9 eV), large ON…

Materials Science · Physics 2014-03-04 Shalini Kumari , Nora Ortega , Ashok Kumar , J. F. Scott , R. S. Katiyar

Relaxor ferroelectrics, which can exhibit exceptional electromechanical coupling are some of the most important functional materials with applications ranging from ultrasound imaging to actuators and sensors in microelectromechanical…

The discovery of ferroelectric polarization in HfO2-based ultrathin films has spawned a lot of interest due to their potential applications in data storage. Recently, a new R3m rhombohedral phase was proposed to be responsible for the…

Materials Science · Physics 2020-07-29 Yuke Zhang , Qiong Yang , Lingling Tao , Evgeny Y. Tsymbal , Vitaly Alexandrov

Electric polarization in ErCrO3 single crystals has been investigated in the temperature range of 5_370 K. Ferroelectric ordering has not been found in any of the directions. However, electric polarization induced by restricted polar…

Materials Science · Physics 2019-05-03 V. A. Sanina , B. Kh. Khannanov , E. I. Golovenchits , M. P. Shcheglov

Based on density functional theory calculations and group theoretical analysis, we have studied NaLaMnWO$_{6}$ compound which has been recently synthesized [Phys. Rev. B 79, 224428 (2009)] and belongs to the $AA'BB'{\rm O}_{6}$ family of…

Materials Science · Physics 2017-09-13 T. Fukushima , A. Stroppa , S. Picozzi , J. M. Perez-Mato

Observation of ferroelectricity among non-d0 systems, which was believed for a long time an unrealistic concept, led to various proposals for the mechanisms to explain the same (i.e. magnetically induced ferroelectricity) during last…

The origin of magnetic frustration was stated and the ions whose shift is accompanied by emerging magnetic ordering and ferroelectricity in TbMn2O5 and BiMn2O5 were determined on the basis of calculation of magnetic coupling parameters by…

Materials Science · Physics 2008-12-03 L. M. Volkova , D. V. Marinin

Born effective charge (BEC), a fundamental quantity in lattice dynamics and ferroelectric theory, provides a quantitative measure of linear polarization response to ionic displacements. However, it does not account for higher-order effects,…

Materials Science · Physics 2025-12-02 Seongjoo Jung , Turan Birol

Deterministic polarization reversal in ferroelectric and multiferroic films is critical for their exploitation in nanoelectronic devices. While ferroelectricity has been studied for nearly a century, major discrepancies in the reported…

Motivated by recent experimental suggestions of charge-order-driven ferroelectricity in organic charge-transfer salts, such as $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Cl, we investigate magnetic and charge-ordered phases that emerge in an…

Strongly Correlated Electrons · Physics 2017-10-30 Ryui Kaneko , Luca F. Tocchio , Roser Valentí , Federico Becca

Double-perovskite A2BB'O6 oxides with magnetic B and B' ions and E*-type antiferromagnetic order (E*-AFM, i.e. the ++-- structure) are believed to exhibit promising multiferroic properties, and Y2CoMnO6 (YCMO) is one candidate in this…

Materials Science · Physics 2015-10-28 C. Y. Ma , S. Dong , P. X. Zhou , Z. Z. Du , M. F. Liu , H. M. Liu , Z. B. Yan , J. M. Liu

HfO2, a simple binary oxide, holds ultra-scalable ferroelectricity integrable into silicon technology. Polar orthorhombic (Pbc21) form in ultra-thin-films ascribes as the plausible root-cause of the astonishing ferroelectricity, which has…

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