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Spontaneous polarization is essential for ferroelectric functionality in non-centrosymmetric crystals. High-integration-density ferroelectric devices require the stabilization of ferroelectric polarization in small volumes. Here,…

Combining ferroelectricity with other properties such as visible light absorption or long-range magnetic order requires the discovery of new families of ferroelectric materials. Here, through the analysis of a high-throughput database of…

A detailed investigation of the out-of-plane electrical properties of charge-ordered alpha-(BEDT-TTF)2I3 provides clear evidence for ferroelectricity. Similar to multiferroic alpha-(BEDT-TTF)2Cu[N(CN)2]Cl, the polar order in this material…

Strongly Correlated Electrons · Physics 2015-06-22 P. Lunkenheimer , B. Hartmann , M. Lang , J. Müller , D. Schweitzer , S. Krohns , A. Loidl

Ferroelectricity has been believed unable to coexist with metallicity since the free carriers can screen the internal coulomb interactions of dipoles. Very recently, one kind of materials called as ferroelectric metal was reexamined. Here,…

Materials Science · Physics 2017-11-08 Jun-xing Gu , Kui-juan Jin , Chao Ma , Qing-hua Zhang , Lin Gu , Chen Ge , Jie-su Wang , Hai-zhong Guo , Guo-zhen Yang

We investigated the electrical properties of the liquid crystal compound, known as an RM734, exhibiting a ferroelectric nematic phase. The influence of alternating (AC) and direct (DC) current electric fields on the switching process of the…

Soft Condensed Matter · Physics 2025-03-04 Mateusz Mrukiewicz , Paweł Perkowski , Jakub Karcz , Przemysław Kula

Ferroelectricity and metallicity are usually believed not to coexist because conducting electrons would screen out static internal electric fields. In 1965, Anderson and Blount proposed the concept of 'ferroelectric metal', however, it is…

Materials Science · Physics 2020-09-22 Xing-Yu Ma , Hou-Yi Lyu , Kuan-Rong Hao , Yi-Ming Zhao , Xiaofeng Qian , Qing-Bo Yan , Gang Su

We report ferrielectricity in a single-phase crystal, TSCC -- tris-sarcosine calcium chloride [(CH3NHCH2COOH)3CaCl2]. Ferrielectricity is well known in smectic liquid crystals but almost unknown in true crystalline solids. Pulvari reported…

We report observation of magneto-electric and magneto-dielectric couplings in ceramic Co3TeO6. Temperature dependent DC magnetization and dielectric constant measurements together indicate coupling between magnetic order and electronic…

Materials Science · Physics 2013-09-26 Harishchandra Singh , Haranath Ghosh , A. K. Sinha , M. N. Singh , G. Sharma , S. Patnaik , S. K. Deb

Since conduction electrons of a metal screen effectively the local electric dipole moments, it was widely believed that the ferroelectric-like distortion cannot occur in metals. Recently, metallic LiOsO3, was discovered to be the first…

Materials Science · Physics 2014-10-01 Hongjun Xiang

The electronic polarization energies, P = (P+) + (P-), of a PTCDA (perylenetetracarboxylic acid dianhydride) cation and anion in a crystalline thin film on a metallic substrate are computed and compared with measurements of the PTCDA…

Condensed Matter · Physics 2009-11-07 E. V. Tsiper , Z. G. Soos , W. Gao , A. Kahn

Dabconium hybrid perovskites include a number of recently-discovered ferroelectric phases with large spontaneous polarisations. The origin of ferroelectric response has been rationalised in general terms in the context of hydrogen bonding,…

Materials Science · Physics 2020-06-11 Dominic J. W. Allen , Nicholas C. Bristowe , Andrew L. Goodwin , Hamish H. -M. Yeung

Measurements of ferroelectric polarization and dielectric constant were done on $R$Mn$_2$O$_5$ ($R$=Tb, Dy, and Ho) with applied hydrostatic pressures of up to 18 kbar. At ambient pressure, distinctive anomalies were observed in the…

Strongly Correlated Electrons · Physics 2009-11-13 C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Wang , S. Park , S-W. Cheong , M. M. Gospodinov , C. W. Chu

The ferroelectric nematic phase (N$_{\text{F}}$) has quickly become the most studied system in liquid crystal research. In this work, we investigate the origin of such polar structure by studying a compound for which the N$_{\text{F}}$…

Soft Condensed Matter · Physics 2024-11-14 Aitor Erkoreka , Nerea Sebastián , Alenka Mertelj , Josu Martinez-Perdiguero

There is great interest in hybrid organic-inorganic materials such as metal-organic frameworks (MOFs). The compounds [C(NH$_{2}$)$_{3}$]M(HCOO)$_{3}$, where M=Cu$^{2+}$ or Cr$^{2+}$ are Jahn-Teller (JT) active ions, are MOF with perovskite…

Materials Science · Physics 2014-03-27 Alessandro Stroppa , Paolo Barone , Prashant Jain , Jean Manuel Perez-Mato , Silvia Picozzi

We present a computational investigation, in conjunction with synthesis and experimental characterization, into the structural, electronic, and optical properties of layered 2D organic lead bromide perovskites. We contrast materials based…

Materials Science · Physics 2025-10-29 Md Mehdi Masud , Jarek Viera , Azza Ben-Akacha , Biwu Ma , David A. Strubbe

Materials with reduced dimensions have been shown to host a wide variety of exotic properties and novel quantum states that often defy textbook wisdom1-5. Ferroelectric polarization and metallicity are well-known examples of mutually…

Using first-principles density functional calculations, we study the interplay of ferroelectricity and polar discontinuities in a range of 1-1 oxide superlattices, built out of ferroelectric and paraelectric components. Studies have been…

Computational Physics · Physics 2015-05-18 Hena Das , Nicola A. Spaldin , Umesh V. Waghmare , T. Saha-Dasgupta

The electric polarization hysteresis loops and remanent polarization were revealed in multiferroics RMn$_2$O$_5$ with $R = Gd$ and $Bi$ at wide temperature interval from 5 K up to 330 K. Until recently, the long-range ferroelectric order…

Materials Science · Physics 2016-10-21 B. Kh. Khannanov , V. A. Sanina , E. I. Golovenchits , M. P. Scheglov

Sliding ferroelectricity is a recently observed polarity existing in two-dimensional materials. However, due to their weak polarization and poor electrical insulation in these materials, all available experimental evidence till now are…

Materials Science · Physics 2023-05-22 Le-Ping Miao , Ning Ding , Na Wang , Chao Shi , Heng-Yun Ye , Linglong Li , Ye-Feng Yao , Shuai Dong , Yi Zhang

Li et al. (Science Advances, 29 January, p. eabe3068) claim the discovery of two improper ferroelectrics, dabcoHClO4 and dabcoHBF4 (dabco = 1,4-diazabicyclo[2.2.2]octane), and that these materials exhibit superior pyroelectric figures of…

Materials Science · Physics 2021-07-02 Marek Szafrański , Andrzej Katrusiak