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We report the first experimental evidence for the intimate connection between superconductivity and antiferromagnetism in Rb0.8Fe2Se2-xTex single crystal under negative chemical pressure by substituting Se with isovalent Te atoms.…

Superconductivity · Physics 2012-05-25 Dachun Gu , Liling Sun , Qi Wu , Chao Zhang , Jing Guo , Peiwen Gao , Yue Wu , Xiaoli Dong , Xi Dai , Zhongxian Zhao

We measure the resistivity and magnetic susceptibility in the temperature range from 5 K to 600 K for the single crystals $A$Fe$_{2-y}$Se$_2$ ($A$ = K$_{0.8}$, Rb$_{0.8}$, Cs$_{0.8}$, Tl$_{0.5}$K$_{0.3}$ and Tl$_{0.4}$Rb$_{0.4}$). A sharp…

Superconductivity · Physics 2015-05-27 R. H. Liu , X. G. Luo , M. Zhang , A. F. Wang , J. J. Ying , X. F. Wang , Y. J. Yan , Z. J. Xiang , P. Cheng , G. J. Ye , Z. Y. Li , X. H. Chen

The structural features and physical properties of the antiferromagnetic K0.8Fe1.6Se2 (so called K2Fe4Se5 phase) have been studied in the temperature range from 300K up to 600K. Resistivity measurements on both single crystal and…

Superconductivity · Physics 2015-05-28 Y. J. Song , Z. Wang , Z. W. Wang , H. L. Shi , Z. Chen , H. F. Tian , G. F. Chen , H. X. Yang , J. Q. Li

57Fe-M\"ossbauer studies of superconducting Rb0.8Fe1.6Se2.0 with TC = 32.4 K were performed on single-crystalline and polycrystalline samples in the temperature range 4.2 K to 295 K. They reveal the presence of 88% magnetic and 12%…

Superconductivity · Physics 2011-08-16 V. Ksenofontov , G. Wortmann , S. Medvedev , V. Tsurkan , J. Deisenhofer , A. Loidl , C. Felser

We report the crystal growth and structural, magnetic, conductivity, and specific heat investigations of Rb(1-x)Fe(2-y)Se2 single crystals with varying stoichiometry prepared by self-flux and Bridgman methods. The system exhibits a strongly…

Superconductivity · Physics 2011-11-01 V. Tsurkan , J. Deisenhofer , A. Günther , H. -A. Krug von Nidda , S. Widmann , A. Loidl

We report discovery of KFe$_{1.05}$Ag$_{0.88}$Te$_{2}$ single crystals with semiconducting spin glass ground state. Composition and structure analysis suggest nearly stoichiometric I4/mmm space group but allow for the existence of…

Strongly Correlated Electrons · Physics 2016-04-21 Hyejin Ryu , Hechang Lei , B. Klobes , J. B. Warren , R. P. Hermann , C. Petrovic

We have synthesized K0.95(1)Ni1.86(2)Se2 single crystals. The single crystals contain K and Ni deficiencies not observed in KNi2Se2 polycrystals. Unlike KNi2Se2 polycrystals, the superconductivity is absent in single crystals. The detailed…

Superconductivity · Physics 2012-11-07 Hechang Lei , Kefeng Wang , Hyejin Ryu , D. Graf , J. B. Warren , C. Petrovic

We have synthesized polycrystalline samples and single crystals of Fe(Te1-xSx)y, and characterized their properties. Our results show that the solid solution of S in this system is limited, < 30%. We observed superconductivity at ~ 9 K in…

Superconductivity · Physics 2008-11-24 M. H. Fang , B. Qian , H. M. Pham , J. H. Yang , T. J. Liu , E. K. Vehstedt , L. Spinu , Z. Q. Mao

We synthesized the new Fe-based superconductor K0.8Fe2Se2 single crystals. The obtained single crystal exhibited a sharp superconducting transition, and the onset and zero-resistivity temperature was estimated to be 33 and 31.8 K,…

We report on synthesis of single crystals of BaFe2Se3 and study of their crystal and magnetic structures by means of synchrotron single crystal X-ray and neutron powder diffraction. The crystal structure has orthorhombic symmetry and…

Crystals of SrMn2Sb2 and BaMn2Sb2 were grown using Sn flux and characterized by powder and single-crystal x-ray diffraction, respectively, and by single-crystal electrical resistivity rho, heat capacity Cp, and magnetic susceptibility chi…

Strongly Correlated Electrons · Physics 2018-01-10 N. S. Sangeetha , V. Smetana , A. -V. Mudring , D. C. Johnston

We successfully grew the high-quality single crystals of $A_{x}$Fe$_2$Se$_2$ ($A$ = K and Cs) by self-flux method. Sharp superconducting transition was observed for both types of crystals. The crystals show the onset superconducting…

Superconductivity · Physics 2011-07-07 J. J. Ying , X. F. Wang , X. G. Luo , A. F. Wang , M. Zhang , Y. J. Yan , Z. J. Xiang , R. H. Liu , P. Cheng , G. J. Ye , X. H. Chen

We report the synthesis and basic physical properties of single crystals of CaFe2As2, an isostructural compound to BaFe2As2 which has been recently doped to produce superconductivity. CaFe2As2 crystalizes in the ThCr2Si2 structure with…

Strongly Correlated Electrons · Physics 2008-07-10 F. Ronning , T. Klimczuk , E. D. Bauer , H. Volz , J. D. Thompson

By the first-principles electronic structure calculations, we find that the ground state of the Fe-vacancies ordered TlFe$_{1.5}$Se$_2$ is a quasi-two-dimensional collinear antiferromagnetic semiconductor with an energy gap of 94 meV, in…

Materials Science · Physics 2015-03-17 Xun-Wang Yan , Miao Gao , Zhong-Yi LU , Tao Xiang

We investigated the physical properties of $TlFe_{2-x}Se_2$ single crystals. The resistivity of $TlFe_{2-x}Se_2$ shows typical semiconductor behavior with an activation energy of 25 meV. DC susceptibility indicates an antiferromagnetic…

Strongly Correlated Electrons · Physics 2010-12-15 J. J. Ying , A. F. Wang , Z. J. Xiang , X. G. Luo , R. H. Liu , X. F. Wang , Y. J. Yan , M. Zhang , G. J. Ye , P. Cheng , X. H. Chen

Single crystals of Ce2PdIn8 were studied by means of magnetic susceptibility, electrical resistivity and specific heat measurements. The compound was found to be a heavy fermion clean-limit superconductor with Tc = 0.68 K. Most remarkably,…

Strongly Correlated Electrons · Physics 2009-07-13 D. Kaczorowski , A. P. Pikul , D. Gnida , V. H. Tran

High-quality single crystals of K0.8Fe2Se1.4S0.4 are successfully synthesized by self-flux method with the superconducting transition temperatures Tconset = 32.8 K and Tczero = 31.2 K. In contrast to external pressure effect on…

Superconductivity · Physics 2015-05-27 L. Li , Z. R. Yang , Z. T. Zhang , W. Tong , C. J. Zhang , S. Tan , Y. H. Zhang

The discovery of ThCr2Si2-type AxFe2-ySe2 (A = K, Rb, Cs and Tl) with Tc ~ 30K make much progress in iron-based superconducting field, but their multiple-phase separations are disadvantageous for understanding the origin. On the other hand,…

Superconductivity · Physics 2014-10-24 Jiangang Guo , Hechang Lei , Fumitaka Hayashi , Hideo hosono

Single crystal neutron diffraction study has been performed on new superconductor A2Fe4Se5, where A = Cs, K, (Tl,Rb) and (Tl,K), and the same Fe vacancy ordered crystal structure and the same block checkerboard antiferromagne tic order…

Superconductivity · Physics 2011-09-21 F. Ye , S. Chi , Wei Bao , X. F. Wang , J. J. Ying , X. H. Chen , H. D. Wang , C. H. Dong , Minghu Fang

The finding of superconductivity in Ba0.6K0.4Fe2As2 put the attention on the investigation of compounds that crystallize with ThCr2Si2 structure type such as AT2X2 (A = alkali/ alkaline earth/ rare earth element; T = transition metal and X…

Superconductivity · Physics 2012-12-10 Andrea V. Hoffmann , Viktor Hlukhyy , Thomas F. Fässler
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