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Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain,…

Materials Science · Physics 2015-06-16 Andrea C. Ferrari , Denis M. Basko

Density functional theory (DFT), the most widely adopted method in modern computational chemistry, fails to describe accurately the electronic structure of strongly correlated systems. Here we show that DFT can be formally and practically…

Chemical Physics · Physics 2022-04-18 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

The unique properties of graphene offer immense opportunities for applications to many scientific fields, as well as societal needs, beyond our present imagination. One of the important features of graphene is the relatively simple…

Materials Science · Physics 2018-04-27 Otakar Frank , Mildred S. Dresselhaus , Martin Kalbac

We present the basic concepts and recent developments in the time-dependent density functional theory (TDDFT) for describing nuclear dynamics at low energy. The symmetry breaking is inherent in nuclear energy density functionals (EDFs),…

Nuclear Theory · Physics 2016-12-21 Takashi Nakatsukasa , Kenichi Matsuyanagi , Masayuki Matsuo , Kazuhiro Yabana

Time-dependent density functional theory (TDDFT) within the linear response regime provides a solid mathematical framework to capture excitations. The accuracy of the theory, however, largely depends on the approximations for the…

Strongly Correlated Electrons · Physics 2023-11-01 Aaron D. Kaplan , Adrienn Ruzsinszky

We calculate the phonon-dispersion relations of several two-dimensional materials and diamond using the density-functional based tight-binding approach (DFTB). Our goal is to verify if this numerically efficient method provides sufficiently…

Materials Science · Physics 2019-09-04 Thomas A. Niehaus , Sigismund T. A. G. Melissen , Balint Aradi , S. Mehdi Vaez Allaei

The ab initio simulation of charged interfaces in the framework of density functional theory (DFT) is heavily employed for the study of electrochemical energy conversion processes. The capacitance is the primary descriptor for the response…

Materials Science · Physics 2022-04-26 Tobias Binninger

The theory of optical effects in hydrogenated graphene (graphane) in terahertz and infrared range is developed, including the analysis of complex conductivity, reflection coefficient for graphane on a substrate and dispersion of surface…

Mesoscale and Nanoscale Physics · Physics 2022-10-19 E. I. Preobrazhensky , I. V. Oladyshkin , M. D. Tokman

To understand sparse systems we must account for both strong local atom bonds and weak nonlocal van der Waals forces between atoms separated by empty space. A fully nonlocal functional form [H. Rydberg, B.I. Lundqvist, D.C. Langreth, and M.…

Materials Science · Physics 2009-11-10 H. Rydberg , M. Dion , N. Jacobson , E. Schroder , P. Hyldgaard , S. I. Simak , D. C. Langreth , B. I. Lundqvist

An electrodynamic response of graphene to a strong electromagnetic radiation is considered. A hot electron model (HEM) is introduced and a corresponding system of nonlinear equations is formulated. Solutions of this system are found and…

Mesoscale and Nanoscale Physics · Physics 2019-09-18 S. A. Mikhailov

We derive the polarization tensor of graphene at nonzero temperature in (2+1)-dimensional space-time. The obtained tensor coincides with the previously known one at all Matsubara frequencies, but, in contrast to it, admits analytic…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 M. Bordag , G. L. Klimchitskaya , V. M. Mostepanenko , V. M. Petrov

Time-dependent density-functional theory (TDDFT) is a formally exact approach to the time-dependent electronic many-body problem which is widely used for calculating excitation energies. We present a survey of the fundamental framework,…

Materials Science · Physics 2014-01-29 Carsten A. Ullrich , Zeng-hui Yang

We propose a composite layered structure for tunable, low-loss plasmon resonances, which con- sists of a noble-metal thin film coated in graphene and supported on a hexagonal boron nitride (hBN) substrate. We calculate electron energy loss…

Mesoscale and Nanoscale Physics · Physics 2016-05-20 L. Rast , T. J. Sullivan , V. K. Tewary

In this article, we investigate the temperature and chemical potential dependence of the optical conductivity of graphene, within a field theoretical representation in the continuum approximation, arising from an underlying tight-binding…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Horacio Falomir , Enrique Muñoz , Marcelo Loewe , Renato Zamora

Electron energy loss spectroscopy (EELS) and Cathodoluminescence (CL) play a pivotal role in many of the cutting edge experiments in plasmonics. EELS and CL experiments are usually supported by numerical simulations, which, whilst accurate,…

Mesoscale and Nanoscale Physics · Physics 2016-07-18 Matthias Kraft , Yu Luo , J. B. Pendry

Intense ultrashort laser pulse irradiation of solid targets was systematically investigated at the first-principles level, both theoretically and computationally. In the method, the propagation of a pulsed light through a thin film is…

Optics · Physics 2024-01-25 Atsushi Yamada , Kazuhiro Yabana

Over the past twenty years, the field of plasmonics has been revolutionized with the isolation and utilization of two--dimensional materials, particularly graphene. Consequently there is significant interest in rapid, robust, and highly…

Numerical Analysis · Mathematics 2024-10-10 David Nicholls , Tianyu Zhu

The one-loop polarization function of graphene has been calculated at zero temperature for arbitrary wavevector, frequency, chemical potential (doping), and band gap. The result is expressed in terms of elementary functions and is used to…

Strongly Correlated Electrons · Physics 2008-12-12 P. K. Pyatkovskiy

Density functional theory (DFT) is the de facto approach for predicting self-consistent-field electronic structures of ground-state configurations of complex atoms, molecules, and solids and providing their property data for materials…

Materials Science · Physics 2024-01-30 Zi-Kui Liu

Recent progress has been made in capturing spectral features of electronic states of double-excitation character in time-dependent density functional theory (TDDFT) through a frequency-dependent kernel. While it might appear that this…

Chemical Physics · Physics 2026-05-04 Dhyey Ray , Anna Baranova , Davood B. Dar , Neepa T. Maitra